2,101 research outputs found
Probability distributions of smeared quantum stress tensors
We obtain in closed form the probability distribution for individual
measurements of the stress-energy tensor of two-dimensional conformal field
theory in the vacuum state, smeared in time against a Gaussian test function.
The result is a shifted Gamma distribution with the shift given by the
previously known optimal quantum inequality bound. For small values of the
central charge it is overwhelmingly likely that individual measurements of the
sampled energy density in the vacuum give negative results. For the case of a
single massless scalar field, the probability of finding a negative value is
84%. We also report on computations for four-dimensional massless scalar fields
showing that the probability distribution of the smeared square field is also a
shifted Gamma distribution, but that the distribution of the energy density is
not.Comment: 9 pages, 1 figure. Minor edits implemente
Puttingtert-Butyl Cation in a Bottle
Usually viewed as intermediates that become long-lived at low temperatures in superacidic media, simple alkyl carbocations such as the tert-butyl cation can be isolated as stable salts at room temperature when partnered with inert carborane anions. The X-ray crystal structures of tert-butyl (depicted), tert-pentyl, and methyl-cyclopentyl cations have been determined with CHB 11Me5X6- counterions (X= Br or Cl). C blue; H white; B yellow; X green
Fullerene—Porphyrin Constructs
Porphyrins and fullerenes are spontaneously attracted to each other. This new supramolecular recognition element can be used to construct discrete host-guest complexes, as well as ordered arrays of interleaved porphyrins and fullerenes. The fullerene-porphyrin interaction underlies successful chromatographic separations of fullerenes, and there are promising applications in the areas of porous framework solids and photovoltaic devices
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