1 research outputs found
Impact of Ni–Mn–Co–Al-Based Cathode Material Composition on the Sintering with Garnet Solid Electrolytes for All-Solid-State Batteries
A systematic and
comprehensive study of the thermal stability
of
the cathode active materials LiNi1/3Mn1/3Co1/3O2 (NMC111), LiNi0.6Mn0.2Co0.2O2 (NMC622), LiNi0.8Mn0.1Co0.1O2 (NMC811), and LiNi0.8Co0.15Al0.05O2 (NCA) in combination
with the garnet solid electrolyte Li6.45La3Zr1.6Ta0.4Al0.05O12 was performed,
and the respective thermal stability limits in air were assessed.
Compared to prior studies on such material mixtures, additional Zr-containing
secondary phases were detected, which had not been taken into consideration
in a previously published work. Here, these phases were successfully
identified for the first time by a combination of X-ray diffraction,
Raman spectroscopy, and microstructural analysis