Composition and electronic structure of SiOx/TiOy/Al passivating carrier selective contacts on n-type silicon solar cells

Carrier-selective and passivating SiOx/TiOy heterocontacts are an attractive alternative to conventional contacts due to their high efficiency potentials combined with relatively simple processing schemes. It is widely accepted that post deposition annealing is necessary to obtain high photovoltaic efficiencies, especially for full area aluminum metallized contacts. Despite some previous high-level electron microscopy studies, the picture of atomic-scale processes underlying this improvement seems to be incomplete. In this work, we apply nanoscale electron microscopy techniques to macroscopically well-characterized solar cells with SiOx/TiOy/Al rear contacts on n-type silicon. Macroscopically, annealed solar cells show a tremendous decrease of series resistance and improved interface passivation. Analyzing the microscopic composition and electronic structure of the contacts, we find that partial intermixing of the SiOx and TiOy layers occurs due to annealing, leading to an apparent thickness reduction of the passivating SiOx. However, the electronic structure of the layers remains clearly distinct. Hence, we conclude that the key to obtain highly efficient SiOx/TiOy/Al contacts is to tailor the processing such that the excellent chemical interface passivation of a SiOx layer is achieved for a layer thin enough to allow efficient tunneling through the layer. Furthermore, we discuss the impact of aluminum metallization on the above mentioned processes

Translational and Rotational Energy Distributions of NO Photodesorbed from Au(100)

We report velocity and internal state distributions of nitric oxide photodesorbed from an Au(100) single crystal using 355 and 266 nm photons. The velocity distributions were measured in all three dimensions independently using our novel 3D-velocity map imaging setup. Combined with the internal energy distributions we reveal two distinct desorption mechanisms for the photodesorption of NO from gold dependent on the photon wavelength. The 355 nm desorption is dominated by a nonthermal mechanism due to excitation of an electron from the gold substrate to the adsorbed NO; this leads to a superthermal and noticeably narrow velocity distribution and a rotational state distribution that positively correlates with the velocity distribution and can be described by a rotational temperature appreciably above the surface temperature. Desorption with 266 nm photons leads to a slower average speed and wider angular distribution and rotational temperatures not too far off the surface temperature. We conclude that in the absence of occupied orbitals in the substrate and unoccupied orbitals on the adsorbed NO separated by 4.7 eV, corresponding to 266 nm; the shorter wavelength desorption is dominated by a thermally activated mechanism