5 research outputs found
Orbiton-mediated multi-phonon scattering in LaSrMnO
We report on Raman scattering measurements of single crystalline
LaSrMnO (=0, 0.06, 0.09 and 0.125), focusing on the high
frequency regime. We observe multi-phonon scattering processes up to
fourth-order which show distinct features: (i) anomalies in peak energy and its
relative intensity and (ii) a pronounced temperature-, polarization-, and
doping-dependence. These features suggest a mixed orbiton-phonon nature of the
observed multi-phonon Raman spectra.Comment: 6pages, 6figures, submitted to PR
Existence of orbital polarons in ferromagnetic insulating LaSrMnO (0.110.14) evidenced by giant phonon softening
We present an inelastic light scattering study of single crystalline
(LaPr)SrMnO (, and
,). A giant softening up to 20 - 30 cm of the
Mn-O breathing mode has been observed only for the ferromagnetic insulating
(FMI) samples () upon cooling below the Curie
temperature. With increasing Pr-doping the giant softening is gradually
suppressed. This is attributed to a coupling of the breathing mode to orbital
polarons which are present in the FMI phase.Comment: 4 pages, 5 figure
Existence of orbital polarons in ferromagnetic insulating La1-xSrMnO3 (0.11≤x≤0.14) revealed by giant phonon softening
Optical study of orbital excitations in transition-metal oxides
The orbital excitations of a series of transition-metal compounds are studied
by means of optical spectroscopy. Our aim was to identify signatures of
collective orbital excitations by comparison with experimental and theoretical
results for predominantly local crystal-field excitations. To this end, we have
studied TiOCl, RTiO3 (R=La, Sm, Y), LaMnO3, Y2BaNiO5, CaCu2O3, and K4Cu4OCl10,
ranging from early to late transition-metal ions, from t_2g to e_g systems, and
including systems in which the exchange coupling is predominantly
three-dimensional, one-dimensional or zero-dimensional. With the exception of
LaMnO3, we find orbital excitations in all compounds. We discuss the
competition between orbital fluctuations (for dominant exchange coupling) and
crystal-field splitting (for dominant coupling to the lattice). Comparison of
our experimental results with configuration-interaction cluster calculations in
general yield good agreement, demonstrating that the coupling to the lattice is
important for a quantitative description of the orbital excitations in these
compounds. However, detailed theoretical predictions for the contribution of
collective orbital modes to the optical conductivity (e.g., the line shape or
the polarization dependence) are required to decide on a possible contribution
of orbital fluctuations at low energies, in particular in case of the orbital
excitations at about 0.25 eV in RTiO3. Further calculations are called for
which take into account the exchange interactions between the orbitals and the
coupling to the lattice on an equal footing.Comment: published version, discussion of TiOCl extended to low T, improved
calculation of orbital excitation energies in TiOCl, figure 16 improved,
references updated, 33 pages, 20 figure