Positron Induced Electron Emission from Graphite

In this paper, we present and analyze measurements of the positron induced electron spectra (PIES) from highly oriented pyrolytic graphite (HOPG). The spectra were obtained using a time of flight spectrometer attached to a variable energy positron beam. In the first measurements presented, the system was configured to obtain high resolution data from the annihilation induced KVV Auger transition of carbon. In the second set of data presented, PIES spectra were obtained for 3 different positron beam energies (1.25 eV, 3.5 eV and 4.5 eV). The resulting time of flight (ToF)-PIES exhibit contributions arising from either positron annihilation induced Auger processes (PAES), Auger mediated positron sticking (AMPS), or secondary electron emission. Our analysis indicates that for incident positron energies 3.5 eV and less, the ToF-PIES can be accounted for considering only two mechanisms: positron annihilation induced Auger processes or positron sticking.Comment: Presented at 18th International Conference on Positron Annihilation, August 19-24, 2018 | Orlando, USA. The following article has been accepted by AIP Conference Proceedings. After it is published, it will be found at this https://aip.scitation.org/journal/ap

Positronium formation in graphene and graphite

Positronium (Ps) formation on the surface of clean polycrystalline copper (Cu), highly oriented pyrolytic graphite (HOPG) and multi layer graphene (MLG) grown on a polycrystalline copper substrate has been investigated as a function of incident positron kinetic energy (1.5eV to 1keV). Measurments on Cu indicate that as the kinetic energy of the incident positrons increases from 1.5eV to 900eV, the fraction of positrons that form Ps ($f_{Ps}$) decreases from ~0.5 to ~0.3. However, in HOPG and MLG, instead of a monotonic decrease of $f_{Ps}$ with positron kinetic energy, a sharp peak is observed at ~ 5eV and above ~200eV,remains nearly constant in HOPG and MLG. We propose that in HOPG and MLG, at low incident positron energies the Ps formation is dominated either by a surface Plasmon assisted electron pick up process or by an energy dependent back scattering process. Both these processes can explain the peak observed and the present data can help to augment the understanding of Ps formation from layered materials.Comment: Presented at 18th International Conference on Positron Annihilation, August 19-24, 2018 | Orlando, USA. The following article has been accepted by AIP Conference Proceedings. After it is published, it will be found at https://aip.scitation.org/journal/ap

Coincident Measurement of the Energy Spectra of Doppler-Shifted Annihilation Gamma Quanta and Positron-Induced Secondary Electrons

Preliminary results are presented from a new positron beam system currently under development at the University of Texas at Arlington for the coincident energy measurement of Doppler-shifted annihilation quanta and positron-induced Auger electrons. We report data based on an analysis of the pulses resulting from the detection of positron induced secondary electrons by a micro-channel plate detector in coincidence with the pulses resulting from the detection of associated annihilation gamma rays in a NaI(Tl) gamma detector.Comment: Presented at 18th International Conference on Positron Annihilation, August 19-24, 2018 | Orlando, USA. The following article has been accepted by AIP Conference Proceedings. After it is published, it will be found at https://aip.scitation.org/journal/ap

Using Remotely Piloted Aircraft and Onboard Processing to Optimize and Expand Data Collection

Remotely piloted aircraft (RPA) have the potential to revolutionize local to regional data collection for geophysicists as platform and payload size decrease while aircraft capabilities increase. In particular, data from RPAs combine high-resolution imagery available from low flight elevations with comprehensive areal coverage, unattainable from ground investigations and difficult to acquire from manned aircraft due to budgetary and logistical costs. Low flight elevations are particularly important for detecting signals that decay exponentially with distance, such as electromagnetic fields. Onboard data processing coupled with high-bandwidth telemetry open up opportunities for real-time and near real-time data processing, producing more efficient flight plans through the use of payload-directed flight, machine learning and autonomous systems. Such applications not only strive to enhance data collection, but also enable novel sensing modalities and temporal resolution. NASAs Airborne Science Program has been refining the capabilities and applications of RPA in support of satellite calibration and data product validation for several decades. In this paper, we describe current platforms, payloads, and onboard data systems available to the research community. Case studies include Fluid Lensing for littoral zone 3D mapping, structure from motion for terrestrial 3D multispectral imaging, and airborne magnetometry on medium and small RPAs

Application of Doppler Broadened Gamma Spectroscopy to Study the Surface of Graphene

We present Doppler broadened gamma spectra, obtained using the newly developed advanced positron beam at the University of Texas at Arlington, from a sample consisting of 6 to 8 layers of graphene (MLG) on polycrystalline Cu. The kinetic energy of the positron beam was varied form 2 eV to 20 keV allowing for a depth resolved measurement. The ratio curves formed by dividing the measured Doppler broadened gamma spectra obtained at low positron kinetic energies (~2eV) to the gamma spectra obtained at 20 keV were compared to ratio curves found by dividing the calculated spectra of bulk graphite to bulk Cu. The ratio curves obtained from the measured results show qualitative agreement with those obtained from the calculated spectra. In particular, both sets of curves indicate a much reduced intensity at high momentum. The agreement between the measured and calculated curves is consistent with the hypothesis that the 2eV spectra correspond to the Doppler broadened spectra from the thin overlayer of Graphene (which we anticipate should be similar to the spectra obtained from bulk graphite) and that the spectra taken at 20 keV corresponds to bulk Cu due to the fact that most of the positrons implanted at this energy annihilate in the Cu substrate. The results taken at 2 eV provide evidence that it is possible to obtain chemically sensitive information from the top atomic layers of surfaces (both internal and external) from an analysis of the high momentum tail of the Doppler broadened gamma spectra obtained from the annihilation of positrons at the surface.Comment: Presented at 18th International Conference on Positron Annihilation, August 19-24, 2018 | Orlando, USA. The following article has been accepted by AIP Conference Proceedings. After it is published, it will be found at https://aip.scitation.org/journal/ap

Monte Carlo analysis of the contributions of long-lived positronium to the spectra of positron-impact-induced secondary electrons measured using an annihilation-gamma-triggered time-of-flight spectrometer

Magnetic bottle Time-of-Flight (ToF) spectrometers can measure the energy spectra of all electrons emitted into a 2$\pi$ sr solid angle simultaneously, greatly reducing data collection time. When the detection of the annihilation gamma ($\gamma$) and the detection of the electron (e) are used as timing signals for ToF spectrometers, the e-$\gamma$ time difference spectra (e-$\gamma$ TDS) are reflective of the positron-induced electron energy distributions provided the times between the impact of the positrons and the emission of the annihilation gammas are short compared to the flight times of the electrons. This is typically the case since positrons have short lifetime in solids ($\sim$ 100 - 500 ps) compared to the flight times of the secondary electrons ($10^2$ ns to $10^3$ ns). However, if the positron leaves the surface as a positronium atom (a bound electron-positron state), the annihilation gamma photons can be appreciably delayed due to the longer ortho-positronium (o-Ps) lifetime. This can result in an e-$\gamma$ TDS having an exponential tail with a decay constant related to the o-Ps lifetime. Here, we present an analysis of the e-$\gamma$ TDS using a Monte Carlo model which estimates the spectral contributions resulting from o-Ps annihilations. By removing the contributions from the delayed gamma signal, the energy spectrum of Positron Impact-Induced Secondary electrons (PIISE) can be isolated. Furthermore, our analysis allows an estimation of the intensity of the exponential tail in the e-$\gamma$ TDS providing a method to measure the fraction of positrons that form Ps at solid surfaces without relying on assumed 100% Ps emitting surfaces for calibration

Measurement and analysis of the Doppler broadened energy spectra of annihilation gamma radiation originating from clean and adsorbate-covered surfaces

We present measurements and theoretical modeling demonstrating the capability of Doppler Broadened annihilation gamma Spectroscopy (DBS) to provide element-specific information from the topmost atomic layer of surfaces that are either clean or covered with adsorbates or thin films. Our measurements show that the energy spectra of Doppler-shifted annihilation gamma photons emitted following the annihilation of positrons from the topmost atomic layers of clean gold (Au) and copper (Cu) differ significantly. With the aid of the positron annihilation-induced Auger electron spectroscopy (PAES) performed simultaneously with DBS, we show that measurable differences between the Doppler broadened gamma spectra from Au and Cu surfaces in the high energy region of the gamma spectra can be used for the quantification of surface chemical composition. Modeling the measured Doppler spectra from clean Au and Cu surfaces using gamma spectra obtained from ab initio calculations after considering the detector energy resolution and surface positronium formation pointed to an increase in the relative contribution of gamma from positron annihilation with valence shell electrons. The fit result also suggests that the surface-trapped positrons predominantly annihilated with the delocalized valence shell (s and p) electrons that extended into the vacuum as compared to the highly localized d electrons. Simultaneous DBS and PAES measurements from adsorbate (sulfur, oxygen, carbon) or thin film (selenium (Se), graphene) covered Cu surface showed that it is possible to distinguish and quantify the surface adsorbate and thin-film composition just based on DBS. DBS of elemental surfaces presents a promising avenue for developing a characterization tool that can be used to probe external and internal surfaces that are inaccessible by conventional surface science techniques