Multilayer WO3/BiVO4 Photoanodes for Solar-Driven Water Splitting Prepared by RF-Plasma Sputtering

A series of WO3, BiVO4 and WO3/BiVO4 heterojunction coatings were deposited on fluorine-doped tin oxide (FTO), by means of reactive radio frequency (RF) plasma (co)sputtering, and tested as photoanodes for water splitting under simulatedAM1.5 G solar light in a three-electrode photoelectrochemical (PEC) cell in a 0.5 M NaSO4 electrolyte solution. The PEC performance and time stability of the heterojunction increases with an increase of the WO3 innermost layer up to 1000 nm. A two-step calcination treatment (600 \ub0C after WO3 deposition followed by 400 \ub0C after BiVO4 deposition) led to a most performing photoanode under back-side irradiation, generating a photocurrent density of 1.7 mA cm-2 at 1.4 V vs. SCE (i.e., two-fold and five-fold higher than that generated by individual WO3 and BiVO4 photoanodes, respectively). The incident photon to current efficiency (IPCE) measurements reveal the presence of two activity regions over the heterojunction with respect to WO3 alone: The PEC efficiency increases due to improved charge carrier separation above 450 nm (i.e., below the WO3 excitation energy), while it decreases below 450 nm (i.e., when both semiconductors are excited) due to electron\u2013hole recombination at the interface of the two semiconductors

Low temperature/uv-assisted composites as gas sensors for medical applications

The sensing of gas molecules is of fundamental importance for environmental monitoring, control of chemical processes, medical applications, and so on [1]. Furthermore, recent success in non-invasive medical diagnostics, based on human breath analysis, is pushing forward the development of extremely sensitive gas sensors for ppb detection of specific analytes (e.g. acetone) in a complex gas mixture [1,2]. In recent years, graphene-based gas sensors have attracted much attention and different structures have been developed showing high sensing performances and room temperature working conditions [2]. However, they still suffer from several problems, which could be overcome by covering the graphene surface with metal oxide semiconductors. Furthermore, studies regarding the detection of Volatile Organic Compounds (VOCs) are still at the beginning [3]. Hence, the present work will be aimed at: i) optimizing the synthetic routes of ad hoc composite VOCs sensing materials (based on graphene oxide/SnO2 hybrids); ii) engineering the gas sensor device; and iii) evaluating the sensing performances at both high and mild temperatures (also exploiting the UV light) towards gaseous ethanol, acetone and ethylbenzene. Starting from pure graphite, graphene oxide (GO) powder was synthesized by adopting the Hummer\u2019s modified method, in which the synthetic route was deeply investigated, and several parameters (such as H2O2 concentration) were modulated. Once optimized this step, SnO2 were grown on its surface by hydrothermal method, varying the starting salt precursor/GO weight ratio between 4 and 32. For comparison, pure commercial and home-made SnO2 were also tested. Several physico-chemical analyses were performed to characterize all the as-prepared nanopowders. Subsequently, a homogeneous film was deposited by spraying technique onto Pt-Interdigitated Electrodes (Pt-IDEs). Then, gaseous ethanol (Figure 1) and acetone were sensed, obtaining very promising results for both pure and hybrid materials at 350\ub0C, and at lower temperatures (150\ub0C to 30\ub0C, by exploiting the UV light) for the graphene-based samples

Effect of titanium dioxide crystalline structure on the photocatalytic production of hydrogen

The effect of the crystalline phase of TiO 2 (anatase, rutile and brookite) on its photocatalytic activity in hydrogen production from methanol-water vapours has been investigated by testing a series of both home-made and commercial TiO 2 photocatalysts, either bare or surface-modified by deposition of a fixed amount, i.e. 1 wt%, of platinum as co-catalyst. For all of the TiO 2 samples the rate of hydrogen production increased by one order of magnitude upon Pt deposition, because of the ability of Pt to enhance the separation of photoproduced electron-hole pairs. Under irradiation in the 350-450 nm wavelength range, brookite and anatase showed similar photoactivities, both superior to that of rutile. By contrast, rutile, possessing a narrower band gap, was active also under visible light (λ > 400 nm), whereas no hydrogen evolution was observed with anatase and brookite under such conditions. Surface area proved to be a key parameter, strongly influencing photoactivity. However, as the particle size became ultra-small, the semiconductor absorption edge was blue-shifted because of size quantisation effects, with a consequent decrease in hydrogen production rate due to the smaller portion of incident photons absorbed by the photocatalyst. © The Royal Society of Chemistry and Owner Societies 2011

Avaliação dos danos de Sibinia spp. (Coleoptera: Curculionidae) em sementes de Bracatinga (Mimosa scabrella Benth.) de três procedências.

bitstream/item/101248/1/PA-1983-Iede-AvaliacaoDanos.pd

Contribuição à biologia larval de Hylesia sp. (Lepidoptera: Hemileucidae) em Bracatinga (Mimosa scabrella Benth.).

bitstream/item/101249/1/PA-1983-Iede-ContribuicaoBiologia.pd

Study of the Fabrication Process for a Dual Mass Tuning Fork Gyro

AbstractThe fabrication process of a dual mass tuning for gyroscope presents many different challenges: the aspect ratio of the sidewalls, the Aspect Ratio Dependent Etch (ARDE) which causes different gaps to be etched in different etching time [1], the stiction during the release of the free structures, the notching effect that occurs with a dielectric etch stop layer [2], the thermal contact during the etch process. In this paper are presented different processes and studies of the etching characteristics in order to avoid or minimize these problems

Pré-otimização do pré-tratamento por explosão a vapor de Eucalyptus urograndis visando maior susceptibilidade na hidrólise enzimática.

21-SBQSul. Poster

Venous Pulse Wave Velocity variation in response to a simulated fluid challenge in healthy subjects

Purpose: The evaluation of a mini or simulated fluid challenge is still a complex and open issue in the clinical setting and it is of paramount significance for the fluid therapy optimization. We here investigated the capacity of a new hemodynamic parameter, the venous Pulse Wave Velocity (vPWV), to detect the effect of passive leg raising (PLR). Materials and methods: In 15 healthy volunteers (7 M, 8 F, age 26 ± 3) venous pressure pulses were elicited by pneumatic compressions of the left hand and proximally detected by ultrasound for calculation of the vPWV. We also non-invasively measured the basilic vein (BV) cross-sectional perimeter, and peripheral venous pressure (PVP). The PLR manoeuvre was performed twice to evaluate reliability of the assessment. Results: The PLR had an overall statistically significant effect on the entire set of variables (MANOVA, p < 0.05): vPWV increased from 2.11 ± 0.46 to 2.30 ± 0.47 m/s (p = 0.01; average increase: 10%). This effect was transient and dropped below 5% after about 3 min. A significant increase was also exhibited by BV size and PVP. In consecutive measurements vPWV showed little intra-subject variability (CoV = 8%) and good reliability (ICC = 0.87). Finally, the vPWV responses to the two PLRs exhibited good agreement (paired T-test: p = 0.96), and moderate reliability (ICC = 0.57). Conclusion: These results demonstrated that vPWV can be non-invasively, objectively and reliably measured in healthy subjects and that it is adequate to detect small pressure/volume variations, as induced by PLR-from-supine. These characteristics make it suitable for clinical applications