67 research outputs found
Time-dependent efficiency measurements of polymer solar cells with dye additives: unexpected initial increase of efficiency
We report the effects of the addition of two azo-dye additives on the time-dependent efficiency of polymer solar cells. Although the maximum efficiencies of devices containing different amounts of dye do not vary greatly over the selected concentration range, the time dependence results reveal a surprising initial increase in efficiency in some samples. We observe this effect to be correlated with a leakage current, although a specific mechanism is not yet identified. We also present the measured lifetimes of these solar cells, and find that variations in dye concentrations produce a small effect at most. Characterization of the bulk heterojunction layer (active layer) morphology using atomic-force microscope (AFM) imaging reveals reordering patterns which suggest that the primary effects of the dyes arise via structural, not absorptive, characteristics
Structure–function relationships of fullerene esters in polymer solar cells: unexpected structural effects on lifetime and efficiency
We report both transport measurements and spectroscopic data of polymer/fullerene blend photovoltaics using a small library of fullerene esters to correlate device properties with a range of functionality and structural diversity of the ester substituent. We observe that minor structural changes can lead to significant and surprising differences in device efficiency and lifetime. For example we have found that isomeric R-groups in the fullerene ester-based devices we have studied have dramatically different efficiencies. The characteristic lifetimes derived from both transport and spectroscopic measurements are generally comparable; however, some more rapid effects in specific fullerene esters are not observed spectroscopically. It is apparent from our results that each fullerene derivative requires re-optimization to reveal the best device performance. Furthermore we conclude that a library approach is essential for evaluating the effects of structural differences in the constituent molecules and serves as important device optimization method that is not being currently employed in photovoltaic investigations
The Simons Observatory: Characterizing the Large Aperture Telescope Receiver with Radio Holography
We present near-field radio holography measurements of the Simons Observatory
Large Aperture Telescope Receiver optics. These measurements demonstrate that
radio holography of complex millimeter-wave optical systems comprising
cryogenic lenses, filters, and feed horns can provide detailed characterization
of wave propagation before deployment. We used the measured amplitude and
phase, at 4K, of the receiver near-field beam pattern to predict two key
performance parameters: 1) the amount of scattered light that will spill past
the telescope to 300K and 2) the beam pattern expected from the receiver when
fielded on the telescope. These cryogenic measurements informed the removal of
a filter, which led to improved optical efficiency and reduced side-lobes at
the exit of the receiver. Holography measurements of this system suggest that
the spilled power past the telescope mirrors will be less than 1% and the main
beam with its near side-lobes are consistent with the nominal telescope design.
This is the first time such parameters have been confirmed in the lab prior to
deployment of a new receiver. This approach is broadly applicable to millimeter
and sub-millimeter instruments.Comment: in proces
The Simons Observatory: Beam characterization for the Small Aperture Telescopes
We use time-domain simulations of Jupiter observations to test and develop a
beam reconstruction pipeline for the Simons Observatory Small Aperture
Telescopes. The method relies on a map maker that estimates and subtracts
correlated atmospheric noise and a beam fitting code designed to compensate for
the bias caused by the map maker. We test our reconstruction performance for
four different frequency bands against various algorithmic parameters,
atmospheric conditions and input beams. We additionally show the reconstruction
quality as function of the number of available observations and investigate how
different calibration strategies affect the beam uncertainty. For all of the
cases considered, we find good agreement between the fitted results and the
input beam model within a ~1.5% error for a multipole range l = 30 - 700.Comment: 22 pages, 21 figures, to be submitted to Ap
The Simons Observatory: Beam characterization for the small aperture telescopes
We use time-domain simulations of Jupiter observations to test and develop a beam reconstruction pipeline for the Simons Observatory Small Aperture Telescopes. The method relies on a mapmaker that estimates and subtracts correlated atmospheric noise and a beam fitting code designed to compensate for the bias caused by the mapmaker. We test our reconstruction performance for four different frequency bands against various algorithmic parameters, atmospheric conditions, and input beams. We additionally show the reconstruction quality as a function of the number of available observations and investigate how different calibration strategies affect the beam uncertainty. For all of the cases considered, we find good agreement between the fitted results and the input beam model within an ∼1.5% error for a multipole range ℓ = 30–700 and an ∼0.5% error for a multipole range ℓ = 50–200. We conclude by using a harmonic-domain component separation algorithm to verify that the beam reconstruction errors and biases observed in our analysis do not significantly bias the Simons Observatory r-measuremen
The Simons Observatory Large Aperture Telescope Receiver
The Simons Observatory (SO) Large Aperture Telescope Receiver (LATR) will be
coupled to the Large Aperture Telescope located at an elevation of 5,200 m on
Cerro Toco in Chile. The resulting instrument will produce arcminute-resolution
millimeter-wave maps of half the sky with unprecedented precision. The LATR is
the largest cryogenic millimeter-wave camera built to date with a diameter of
2.4 m and a length of 2.6 m. It cools 1200 kg of material to 4 K and 200 kg to
100 mk, the operating temperature of the bolometric detectors with bands
centered around 27, 39, 93, 145, 225, and 280 GHz. Ultimately, the LATR will
accommodate 13 40 cm diameter optics tubes, each with three detector wafers and
a total of 62,000 detectors. The LATR design must simultaneously maintain the
optical alignment of the system, control stray light, provide cryogenic
isolation, limit thermal gradients, and minimize the time to cool the system
from room temperature to 100 mK. The interplay between these competing factors
poses unique challenges. We discuss the trade studies involved with the design,
the final optimization, the construction, and ultimate performance of the
system
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