Tunable solid-state fluorescent materials for supramolecular encryption

Tunable solid-state fluorescent materials are ideal for applications in security printing technologies. A document possesses a high level of security if its encrypted information can be authenticated without being decoded, while also being resistant to counterfeiting. Herein, we describe a heterorotaxane with tunable solid-state fluorescent emissions enabled through reversible manipulation of its aggregation by supramolecular encapsulation. The dynamic nature of this fluorescent material is based on a complex set of equilibria, whose fluorescence output depends non-linearly on the chemical inputs and the composition of the paper. By applying this system in fluorescent security inks, the information encoded in polychromic images can be protected in such a way that it is close to impossible to reverse engineer, as well as being easy to verify. This system constitutes a unique application of responsive complex equilibria in the form of a cryptographic algorithm that protects valuable information printed using tunable solid-state fluorescent materials

Study of Quenching and Partitioning (Q&P) and Ultrasonic Surface Rolling (USR) Process on Microstructure and Mechanical Property of a High-Strength Martensitic Steel

Steel with a combination of strength and plasticity is prevalently demanded for lightweight design and emission reductions in manufacturing. In this study, a high-strength Cr-Ni-Mo martensitic steel treated by quenching and partitioning (Q&P) and ultrasonic surface rolling (USR) processes was studied for both strength and plasticity enhancement. Specimens were austenitized at 850 °C and then quenched to 240 °C via cooling by water, oil, and normalization in quenching. This was followed by partitioning, in which two groups of specimens were heated to 370 °C and 350 °C for 45 min, respectively. At last, all the specimens were quenched to room temperature with the same methods of quenching. The highest tensile strength increased from 681.73 MPa to 1389.76 MPa when compared to as-received (AR) steel after the Q&P process. The USR process with a static force of 800 N further improved the tensile strength of specimens with high tensile strength after the Q&P process, which improved from 1389.76 MPa to 1586.62 MPa and the product’s strength and elongation (PSE) increased from 15.76 GPa% to 15.9 GPa%, while the total elongation showed a mitigatory decrease from 11.34% to 10.02%. Tensile fractures were also studied and verified using a combination of strength and plasticity after a combined process of Q&P and USR

A Mathematical Model of Neutral Lipid Content in terms of Initial Nitrogen Concentration and Validation in Coelastrum sp. HA-1 and Application in Chlorella sorokiniana

Microalgae are considered to be a potential major biomass feedstock for biofuel due to their high lipid content. However, no correlation equations as a function of initial nitrogen concentration for lipid accumulation have been developed for simplicity to predict lipid production and optimize the lipid production process. In this study, a lipid accumulation model was developed with simple parameters based on the assumption protein synthesis shift to lipid synthesis by a linear function of nitrogen quota. The model predictions fitted well for the growth, lipid content, and nitrogen consumption of Coelastrum sp. HA-1 under various initial nitrogen concentrations. Then the model was applied successfully in Chlorella sorokiniana to predict the lipid content with different light intensities. The quantitative relationship between initial nitrogen concentrations and the final lipid content with sensitivity analysis of the model were also discussed. Based on the model results, the conversion efficiency from protein synthesis to lipid synthesis is higher and higher in microalgae metabolism process as nitrogen decreases; however, the carbohydrate composition content remains basically unchanged neither in HA-1 nor in C. sorokiniana

Isolation and Characterization of a Marine Microalga for Biofuel Production with Astaxanthin as a Co-Product

energie

Enhanced evapotranspiration induced by vegetation restoration may pose water resource risks under climate change in the Yellow River Basin

Quantifying the impacts of climate change, vegetation greening and human activities (CVH) on evapotranspiration (ET), surface drought intensity (ET divided by precipitation, SDI), and vegetation available water (precipitation minus ET, VAW) would improve our understanding of water cycle processes. The Yellow River Basin (YRB) is a significant climate-sensitive region in China, resulting in an obvious spatiotemporal heterogeneity of ET, SDI, and VAW in response to driving variables. In this study, we analysed the spatiotemporal variation characteristics of ET, SDI, and VAW in the YRB from 1984 to 2018. We also quantified the direct and indirect contributions of the CVH to the changes in ET, SDI, and VAW, and revealed the influence mechanism of each link. Finally, water resource risks were assessed from a probabilistic perspective. The results indicated that vegetation greening was the primary driver of ET with an increase rate of 1.60 mm/a, which was also the most important influencing factor of SDI increase and VAW decrease. Leaf area index (LAI) and relative humidity (RH) jointly dominated the ET changes in 66 % of the YRB, temperature (Temp) dominated the SDI changes in nearly half of the basin, precipitation (Pre) and LAI jointly dominated the VAW changes in 66 % of the YRB. Temp indirectly influenced ET primarily through LAI, whereas LAI primarily influenced ET directly. Temp had a significant direct impact on SDI, while LAI mainly influenced SDI through RH and wind speed (WS). Temp exhibited the most substantial negative influence on VAW. LAI was identified as the primary factor contributing to water resource risks, with a probability reaching 0.8, while the probabilities associated with other factors inducing such risks were similar at the basin level, but disparities existed among different land use types. The findings of the study significantly enhanced our understanding of the role that the CVH played in hydrological processes, serving as a crucial foundation for achieving a balance between ecological restoration and socio-economic development in the YRB