439 research outputs found
Revealing three-dimensional structure of individual colloidal crystal grain by coherent x-ray diffractive imaging
We present results of a coherent x-ray diffractive imaging experiment
performed on a single colloidal crystal grain. The full three-dimensional (3D)
reciprocal space map measured by an azimuthal rotational scan contained several
orders of Bragg reflections together with the coherent interference signal
between them. Applying the iterative phase retrieval approach, the 3D structure
of the crystal grain was reconstructed and positions of individual colloidal
particles were resolved. As a result, an exact stacking sequence of hexagonal
close-packed layers including planar and linear defects were identified.Comment: 8 pages, 5 figure
Nanoassembly of Polydisperse Photonic Crystals Based on Binary and Ternary Polymer Opal Alloys
Ordered binary and ternary photonic crystals, composed of different sized
polymer-composite spheres with diameter ratios up to 120%, are generated using
bending induced oscillatory shearing (BIOS). This viscoelastic system creates
polydisperse equilibrium structures, producing mixed opaline colored films with
greatly reduced requirements for particle monodispersity, and very different
sphere size ratios, compared to other methods of nano-assembly
Large-scale ordering of nanoparticles using viscoelastic shear processing
This is the author accepted manuscript. It is currently under an indefinite embargo pending publication by Nature Publishing Group.Despite the availability of elaborate varieties of nanoparticles, their assembly into regular superstructures and photonic materials remains challenging. Here we show how flexible films of stacked polymer nanoparticles can be directly assembled in a roll-to-roll process using a bending-induced oscillatory shear (BIOS) technique. For sub-micron spherical nanoparticles, this gives elastomeric photonic crystals termed polymer opals showing extremely strong structural colour. With oscillatory strain amplitudes of 300%, crystallisation initiates at the wall and develops quickly across the bulk within only 5 oscillations yielding sharp intense reflectance peaks of tunable colour. The resulting structure of randomly stacked hexagonal close-packed layers parallel to the shear plane, is improved by shearing bidirectionally, alternating between two in-plane directions. Our theoretical framework indicates how the reduction in shear viscosity with increasing order of each layer accounts for these results, even when diffusion is totally absent. This general principle of shear ordering in viscoelastic media opens the way to manufacturable photonics materials, and forms a generic tool for ordering nanoparticles.We acknowledge EPSRC grants EP/G060649/1, EP/H027130/1, EP/E040241, EP/L027151/1 and EU ERC grants LINASS 320503 and FP7 291522-3DIMAGE
Synthesis and Polyelectrolyte Functionalization of Hollow Fiber Membranes Formed by Solvent Transfer Induced Phase Separation
Ultrafiltration membranes are important porous materials to produce freshwater in an increasingly water-scarce world. A recent approach to generate porous membranes is solvent transfer induced phase separation (STrIPS). During STrIPS, the interplay of liquid-liquid phase separation and nanoparticle self-assembly results in hollow fibers with small surface pores, ideal structures for applications as filtration membranes. However, the underlying mechanisms of the membrane formation are still poorly understood, limiting the control over structure and properties. To address this knowledge gap, we study the nonequilibrium dynamics of hollow fiber structure evolution. Confocal microscopy reveals the distribution of nanoparticles and monomers during STrIPS. Diffusion simulations are combined with measurements of the interfacial elasticity to investigate the effect of the solvent concentration on nanoparticle stabilization. Furthermore, we demonstrate the separation performance of the membrane during ultrafiltration. To this end, polyelectrolyte multilayers are deposited on the membrane, leading to tunable pores that enable the removal of dextran molecules of different molecular weights (>360 kDa, >60 kDa, >18 kDa) from a feed water stream. The resulting understanding of STrIPS and the simplicity of the synthesis process open avenues to design novel membranes for advanced separation applications
Organic Reference Materials for Hydrogen, Carbon, And Nitrogen Stable Isotope-Ratio Measurements: Caffeines, n-Alkanes, Fatty Acid Methyl Esters, Glycines, l-Valines, Polyethylenes, and Oils
Deuterium exchange of organic and organosilicon compounds on group VIII transition metals
- …