Statistical-mechanical theory of ultrasonic absorption in molecular liquids

We present results of theoretical description of ultrasonic phenomena in molecular liquids. In particular, we are interested in the development of microscopical, i.e., statistical-mechanical framework capable to explain the long living puzzle of the excess ultrasonic absorption in liquids. Typically, ultrasonic wave in a liquid can be generated by applying the periodically alternating external pressure with the angular frequency that corresponds to the ultrasound. If the perturbation introduced by such process is weak - its statistical-mechanical treatment can be done with the use of the linear response theory. We treat the liquid as a system of interacting sites, so that all the response/aftereffect functions as well as the energy dissipation and generalized (wave-vector and frequency dependent) ultrasonic absorption coefficient are obtained in terms of familiar site-site static and time correlation functions such as static structure factors or intermediate scattering functions. To express the site-site intermediate scattering functions we refer to the site-site memory equations in the mode-coupling approximation for the first-order memory kernels, while equilibrium properties such as site-site static structure factors, direct and total correlation functions are deduced from the integral equation theory of molecular liquids known as RISM or one of its generalizations. All the formalism is phrased in a general manner, hence the obtained results are expected to work for arbitrary type of molecular liquid including simple, ionic, polar, and non-polar liquids.Comment: 14 pages, 1 eps-figure, RevTeX4-forma

Low temperature acoustic properties of amorphous silica and the Tunneling Model

Internal friction and speed of sound of a-SiO(2) was measured above 6 mK using a torsional oscillator at 90 kHz, controlling for thermal decoupling, non-linear effects, and clamping losses. Strain amplitudes e(A) = 10^{-8} mark the transition between the linear and non-linear regime. In the linear regime, excellent agreement with the Tunneling Model was observed for both the internal friction and speed of sound, with a cut-off energy of E(min) = 6.6 mK. In the non-linear regime, two different behaviors were observed. Above 10 mK the behavior was typical for non-linear harmonic oscillators, while below 10 mK a different behavior was found. Its origin is not understood.Comment: 1 tex file, 6 figure

Casimir Surface Force on a Dilute Dielectric Ball

The Casimir surface force density F on a dielectric dilute spherical ball of radius a, surrounded by a vacuum, is calculated at zero temperature. We treat (n-1) (n being the refractive index) as a small parameter. The dispersive properties of the material are taken into account by adopting a simple dispersion relation, involving a sharp high frequency cutoff at omega = omega_0. For a nondispersive medium there appears (after regularization) a finite, physical, force F^{nondisp} which is repulsive. By means of a uniform asymptotic expansion of the Riccati-Bessel functions we calculate F^{nondisp} up to the fourth order in 1/nu. For a dispersive medium the main part of the force F^{disp} is also repulsive. The dominant term in F^{disp} is proportional to (n-1)^2{omega_0}^3/a, and will under usual physical conditions outweigh F^{nondisp} by several orders of magnitude.Comment: 24 pages, latex, no figures, some additions to the Acknowledments sectio

Demography and Life Histories of Sympatric Patas Monkeys, Erythrocebus patas, and Vervets, Cercopithecus aethiops, in Laikipia, Kenya

Mortality patterns are thought to be strong selective forces on life history traits, with high adult mortality and low immature mortality favoring early and rapid reproduction. Patas monkeys (Erythrocebus patas) have the highest potential rates of population increase for their body size of any haplorhine primate because they reproduce both earlier and more often. We report here 10 yr of comparative demographic data on a population of patas monkeys and a sympatric population of vervet monkeys (Cercopithecus aethiops), a closely related species differing in aspects of social system, ecology, and life history. The data reveal that 1) adult female patas monkeys have significantly higher mortality than adult female vervets; 2) infant mortality in patas monkeys is relatively low compared to the norm for mammals because it is not significantly different from that of adult female patas monkeys; and 3) infant mortality is significantly higher than adult female mortality in vervets. For both species, much of the mortality could be attributed to predation. An epidemic illness was also a major contributor to the mortality of adult female patas monkeys whereas chronic exposure to pathogens in a cold and damp microenvironment may have contributed to the mortality of infant vervets. Both populations experienced large fluctuations during the study period. Our results support the prediction from demographic models of life history evolution that high adult mortality relative to immature mortality selects for early maturation

Modelling Sonoluminescence

In single-bubble sonoluminescence, a bubble trapped by a sound wave in a flask of liquid is forced to expand and contract; exactly once per cycle, the bubble emits a very sharp ($< 50 ps$) pulse of visible light. This is a robust phenomenon observable to the naked eye, yet the mechanism whereby the light is produced is not well understood. One model that has been proposed is that the light is "vacuum radiation" generated by the coupling of the electromagnetic fields to the surface of the bubble. In this paper, we simulate vacuum radiation by solving Maxwell's equations with an additional term that couples the field to the bubble's motion. We show that, in the static case originally considered by Casimir, we reproduce Casimir's result. In a simple purely time-dependent example, we find that an instability occurs and the pulse of radiation grows exponentially. In the more realistic case of spherically-symmetric bubble motion, we again find exponential growth in the context of a small-radius approximation.Comment: Expanded introduction, appendix on duality, 18 pages, plain Te

Management practices for control of ragwort species

The ragwort species common or tansy ragwort (Jacobaea vulgaris, formerly Senecio jacobaea), marsh ragwort (S. aquaticus), Oxford ragwort (S. squalidus) and hoary ragwort (S. erucifolius) are native in Europe, but invaded North America, Australia and New Zealand as weeds. The abundance of ragwort species is increasing in west-and central Europe. Ragwort species contain different groups of secondary plant compounds defending them against generalist herbivores, contributing to their success as weeds. They are mainly known for containing pyrrolizidine alkaloids, which are toxic to grazing cattle and other livestock causing considerable losses to agricultural revenue. Consequently, control of ragwort is obligatory by law in the UK, Ireland and Australia. Commonly used management practices to control ragwort include mechanical removal, grazing, pasture management, biological control and chemical control. In this review the biology of ragwort species is shortly described and the different management practices are discussed

An overview of NMR-based metabolomics to identify secondary plant compounds involved in host plant resistance

Secondary metabolites provide a potential source for the generation of host plant resistance and development of biopesticides. This is especially important in view of the rapid and vast spread of agricultural and horticultural pests worldwide. Multiple pests control tactics in the framework of an integrated pest management (IPM) programme are necessary. One important strategy of IPM is the use of chemical host plant resistance. Up to now the study of chemical host plant resistance has, for technical reasons, been restricted to the identification of single compounds applying specific chemical analyses adapted to the compound in question. In biological processes however, usually more than one compound is involved. Metabolomics allows the simultaneous detection of a wide range of compounds, providing an immediate image of the metabolome of a plant. One of the most universally used metabolomic approaches comprises nuclear magnetic resonance spectroscopy (NMR). It has been NMR which has been applied as a proof of principle to show that metabolomics can constitute a major advancement in the study of host plant resistance. Here we give an overview on the application of NMR to identify candidate compounds for host plant resistance. We focus on host plant resistance to western flower thrips (Frankliniella occidentalis) which has been used as a model for different plant species

THE KAPITZA RESISTANCE AND HEAT TRANSFER AT LOW TEMPERATURES

Dans cet article nous rappelons quelques problèmes importants de transfert de chaleur à des températures voisines du Kelvin. Nous traitons plus particulièrement de la résistance de contact thermique entre solides et de la résistance thermique entre solides et hélium superfluide (résistance de Kapitza). Nous faisons une comparaison entre les résultats expérimentaux et les modèles théoriques existants, en particulier le modèle de rayonnement de phonons, limite supérieure de transfert de chaleur.A brief review is given of some important heat transfer problems at 1 °K and below. Included are discussions of the thermal contact resistance between solid-solid and solid-liquid helium II boundaries (Kapitza resistance). The results are compared to available theoretical models, with particular interest placed on the upper limit, the phonon radiation model

EXPERIMENTS ON THERMAL PHONON RADIATION INTO QUARTZ SUBSTRATES

Nous présentons les résultats des expériences de mesure de température des films d'or, d'indium et d'étain déposés sur un substrat de quartz coupe Z. Une technique de réflexion d'impulsions électriques comme celle de Herth et Weis a été employée. Dans tous les cas nous trouvons un bon accord entre l'expérience et le modèle théorique de Little. Nous concluons que la théorie de Little s'applique bien aux résistances de contact solide-solide, même quand un des milieux est assez anisotrope.Results are presented for the radiation temperature of gold, indium and tin films deposited on a Z cut quartz substrate. A pulse reflection technique developed by Herth and Weis was used for these experiments. In all cases good agreement is found between experiment and the predictions of Little's model calculated on the basis of averages of the appropriate sound velocities. Convincing support for the validity of the present theory of the solid-solid thermal contact resistance is thus obtained, even for the case where one of the solids is quite anisotropic