2 research outputs found
Above-11%-Efficiency Organic–Inorganic Hybrid Solar Cells with Omnidirectional Harvesting Characteristics by Employing Hierarchical Photon-Trapping Structures
Hierarchical
structures consisting of micropyramids and nanowires
are used in Si/PEDOT:PSS hybrid solar cells to achieve a power conversion
efficiency (PCE) up to 11.48% with excellent omnidirectionality. The
structure provides a combined concepts of superior light trapping
ability, significant increase of p–n junction areas, and short
carrier diffusion distance, improving the photovoltaic characteristics
including short-circuit current density, fill factor, and PCE. The
enhancement of power generation is up to 253.8% at high incident angles,
showing the outstanding omnidirectional operation ability of hybrid
cells with hierarchical Si surfaces. This properly designed hierarchical-structured
device paves a promising way for developing low-cost, high-efficiency,
and omnidirectional solar applications in the future
Realizing High-Efficiency Omnidirectional n‑Type Si Solar Cells <i>via</i> the Hierarchical Architecture Concept with Radial Junctions
Hierarchical structures combining micropyramids and nanowires with appropriate control of surface carrier recombination represent a class of architectures for radial p-n junction solar cells that synergizes the advantageous features including excellent broad-band, omnidirectional light-harvesting and efficient separation/collection of photoexcited carriers. The heterojunction solar cells fabricated with hierarchical structures exhibit the efficiency of 15.14% using cost-effective as-cut Czochralski n-type Si substrates, which is the highest reported efficiency among all n-type Si nanostructured solar cells. We also demonstrate the omnidirectional solar cell that exhibits the daily generated power enhancement of 44.2% by using hierarchical structures, as compared to conventional micropyramid control cells. The concurrent improvement in optical and electrical properties for realizing high-efficiency omnidirectional solar cells using as-cut Czochralski n-type Si substrates demonstrated here makes a hierarchical architecture concept promising for large-area and cost-effective mass production