Electron energy-loss spectroscopy and ab initio electronic structure of the LaOFeP superconductor

The electronic band structures of the LaOFeP superconductor have been calculated theoretically by the first principles method and measured experimentally by electron energy loss spectroscopy. The calculations indicate that the Fe atom in LaOFeP crystal shows a weak magnetic moment and does not form a long-range magnetic ordering. Band structure, Fermi surfaces and fluorine-doping effects are also analyzed based on the data of the density functional theory. The fine structures of the EELS data have been carefully examined in both the low loss energy region and the core losses region (O K, Fe L2,3, and La M4,5). A slight bump edge at 44 eV shows notable orientation-dependence: it can be observed in the low loss EELS spectra with q parallel to c, but becomes almost invisible in the q vertical to c spectra. Annealing experiments indicate that low oxygen pressure favors the appearance of superconductivity in LaOFeP, this fact is also confirmed by the changes of Fe L2,3 and O K excitation edges in the experimental EELS data

Are there contagion effects in the REIT market? The case of Brexit

On June 23, 2016 the Brexit event that tremendously surprised and shocked investors around the world was considered the largest black swan with a political earthquake in 2016, and even spread to the international financial market and real estate market. This study uses the heteroscedasticity biases based on correlation coefficients by Forbes and Rigobon and the GJR-GARCH model to examine the contagion effects of the Brexit event on global REITs markets. The data are collected at the daily interval covering the time period from June 23, 2015 to December 30, 2016. Evidence reveals that no REITs markets suffered from Brexit, suggesting no transmission of Brexit across REITs markets, even the neighbouring markets, is found

Thermodynamic analysis of an LNG fuelled combined cycle power plant with waste heat recovery and utilization system

SUMMARY This paper has proposed an improved liquefied natural gas (LNG) fuelled combined cycle power plant with a waste heat recovery and utilization system. The proposed combined cycle, which provides power outputs and thermal energy, consists of the gas/steam combined cycle, the subsystem utilizing the latent heat of spent steam from the steam turbine to vaporize LNG, the subsystem that recovers both the sensible heat and the latent heat of water vapour in the exhaust gas from the heat recovery steam generator (HRSG) by installing a condensing heat exchanger, and the HRSG waste heat utilization subsystem. The conventional combined cycle and the proposed combined cycle are modelled, considering mass, energy and exergy balances for every component and both energy and exergy analyses are conducted. Parametric analyses are performed for the proposed combined cycle to evaluate the effects of several factors, such as the gas turbine inlet temperature (TIT), the condenser pressure, the pinch point temperature difference of the condensing heat exchanger and the fuel gas heating temperature on the performance of the proposed combined cycle through simulation calculations. The results show that the net electrical efficiency and the exergy efficiency of the proposed combined cycle can be increased by 1.6 and 2.84% than those of the conventional combined cycle, respectively. The heat recovery per kg of flue gas is equal to 86.27 kJ s À1 . One MW of electric power for operating sea water pumps can be saved. The net electrical efficiency and the heat recovery ratio increase as the condenser pressure decreases. The higher heat recovery from the HRSG exit flue gas is achieved at higher gas TIT and at lower pinch point temperature of the condensing heat exchanger