Effects of nano-void density, size, and spatial population on thermal conductivity: a case study of GaN crystal

The thermal conductivity of a crystal is sensitive to the presence of surfaces and nanoscale defects. While this opens tremendous opportunities to tailor thermal conductivity, a true "phonon engineering" of nanocrystals for a specific electronic or thermoelectric application can only be achieved when the dependence of thermal conductivity on the defect density, size, and spatial population is understood and quantified. Unfortunately, experimental studies of effects of nanoscale defects are quite challenging. While molecular dynamics simulations are effective in calculating thermal conductivity, the defect density range that can be explored with feasible computing resources is unrealistically high. As a result, previous work has not generated a fully detailed understanding of the dependence of thermal conductivity on nanoscale defects. Using GaN as an example, we have combined physically-motivated analytical model and highly-converged large scale molecular dynamics simulations to study effects of defects on thermal conductivity. An analytical expression for thermal conductivity as a function of void density, size, and population has been derived and corroborated with the model, simulations, and experiments

Correlations among superconductivity, structural instability, and band filling in Nb1-xB2 at the critical point x=0.2

We performed an extensive investigation on the correlations among superconductivity, structural instability and band filling in Nb1-xB2 materials. Structural measurements reveal that a notable phase transformation occurs at x=0.2, corresponding to the Fermi level (EF) in the pseudogap with the minimum total density of states (DOS) as demonstrated by the first-principles calculations. Superconductivity in Nb1-xB2 generally becomes visible in the Nb-deficient materials with x=0.2. Electron energy-loss spectroscopy (EELS) measurements on B K-edge directly demonstrated the presence of a chemical shift arising from the structural transformation. Our systematical experimental results in combination with theoretical analysis suggest that the emergence of hole states in the sigma-bands plays an important role for understanding the superconductivity and structural transition in Nb1-xB2.Comment: 16 pages, 4 figure

Pupal surveys for Aedes aegypti surveillance and potential targeted control in residential areas of Mérida, México.

A mosquito larval-pupal survey was conducted in 1,160 households of the Mexican city of Mérida during the rainy season of 2003 to determine their differential productivity for Aedes aegypti. Larvae and pupae were detected in 15 broad categories of container types. All breeding sites were found in the patios (backyards) and were potentially rain filled. Ae. aegypti pupae were produced from all categories of breeding site, and no single container type was predominately responsible for pupal production. The most productive buckets comprised 42% of the pupae-positive containers and provided 34% of the total pupae collected. Pupal production in buckets, together with plastic rubbish, pet dishes and basins, utensils for cooking and washing, tires, and flowerpots, accounted for almost 87% of pupal production. However, the most important pupal producers had low infestation indices for immature forms, illustrating that the use of positive-container indices can underestimate the importance of certain breeding sites. Overall, 40% of containers that were observed harboring Ae. aegypti pupae were classified as disposable. The remaining containers were considered useful, although some were seldom used. The discussion focuses on the potential utility of the pupal survey for targeting control, and its resulting pupae-per-person entomological indicator, both for comparison with a theoretical threshold for dengue transmission and for targeting vector control in this Mexican city

Optical Interferometry of early-type stars with PAVO@CHARA. I. Fundamental stellar properties

We present interferometric observations of 7 main-sequence and 3 giant stars with spectral types from B2 to F6 using the PAVO beam combiner at the CHARA array. We have directly determined the angular diameters for these objects with an average precision of 2.3%. We have also computed bolometric fluxes using available photometry in the visible and infrared wavelengths, as well as space-based ultraviolet spectroscopy. Combined with precise \textit{Hipparcos} parallaxes, we have derived a set of fundamental stellar properties including linear radius, luminosity and effective temperature. Fitting the latter to computed isochrone models, we have inferred masses and ages of the stars. The effective temperatures obtained are in good agreement (at a 3% level) with nearly-independent temperature estimations from spectroscopy. They validate recent sixth-order polynomial (B-V)-$T_\mathrm{eff}$ empirical relations \citep{Boyajian2012a}, but suggest that a more conservative third-order solution \citep{vanBelle2009} could adequately describe the (V-K)-$T_\mathrm{eff}$ relation for main-sequence stars of spectral type A0 and later. Finally, we have compared mass values obtained combining surface gravity with inferred stellar radius (\textit{gravity mass}) and as a result of the comparison of computed luminosity and temperature values with stellar evolutionary models (\textit{isochrone mass}). The strong discrepancy between isochrone and gravity mass obtained for one of the observed stars, $\gamma$\,Lyr, suggests that determination of the stellar atmosphere parameters should be revised.Comment: 13 pages, 9 figures, accepted for publication in MNRA

A Titanium Nitride Absorber for Controlling Optical Crosstalk in Horn-Coupled Aluminum LEKID Arrays for Millimeter Wavelengths

We discuss the design and measured performance of a titanium nitride (TiN) mesh absorber we are developing for controlling optical crosstalk in horn-coupled lumped-element kinetic inductance detector arrays for millimeter-wavelengths. This absorber was added to the fused silica anti-reflection coating attached to previously-characterized, 20-element prototype arrays of LEKIDs fabricated from thin-film aluminum on silicon substrates. To test the TiN crosstalk absorber, we compared the measured response and noise properties of LEKID arrays with and without the TiN mesh. For this test, the LEKIDs were illuminated with an adjustable, incoherent electronic millimeter-wave source. Our measurements show that the optical crosstalk in the LEKID array with the TiN absorber is reduced by 66\% on average, so the approach is effective and a viable candidate for future kilo-pixel arrays.Comment: 7 pages, 5 figures, accepted for publication in the Journal of Low Temperature Physic

Directional Freeze-Casting : A Bioinspired Method to Assemble Multifunctional Aligned Porous Structures for Advanced Applications

Herein, the potential of directional freeze-casting techniques as a very generic, green, and straightforward approach for the processing of various functional porous materials is introduced. These materials include 3D monoliths, films, fibers, and microspheres/beads, which are obtained by the assembly of network building blocks originated from cryoassembly of the various aqueous-based systems. The process simply relies on 1) directional freezing of the slurry through contact with a cold surface, 2) maintaining the slurry at the frozen state for a particular time with controlling the freezing parameters and directions, and 3) sublimation of the created ice crystal templates inside the developed structure to translate the ice growth pattern to final porous structure. The materials developed with such a cryogenic process contain a highly complex porous structure, e.g., a hierarchical and well-aligned microstructure in different levels, which renders a high control over the physicochemical and mechanical functionalities. Due to the versatility and controllability of this technique, the process can also be extended for the mimicking of the structures found in natural materials to the bulk materials to assemble bioinspired porous composites with many useful mechanical and physical features. The aim, herein, is to give a brief overview of the recent advances in developing anisotropic porous inorganic, organic, hybrid, and carbonaceous materials with a particular emphasis on materials with biomimicking microstructure using directional ice templating approach and to highlight their recent breakthrough for different high-performance applications.Peer reviewe

Scaling of Traction Forces with Size of Cohesive Cell Colonies

To understand how the mechanical properties of tissues emerge from interactions of multiple cells, we measure traction stresses of cohesive colonies of 1-27 cells adherent to soft substrates. We find that traction stresses are generally localized at the periphery of the colony and the total traction force scales with the colony radius. For large colony sizes, the scaling appears to approach linear, suggesting the emergence of an apparent surface tension of order 1E-3 N/m. A simple model of the cell colony as a contractile elastic medium coupled to the substrate captures the spatial distribution of traction forces and the scaling of traction forces with the colony size.Comment: 5 pages, 3 figure