11 research outputs found
Photocatalytic Monofluorination of Unactivated C(sp3)–H Bonds by N-Fluorobenzenesulfimide Involving the Decatungstate Anion and the Effect of Water Additives on These Reactions
Oxidative 1,2-carboamination of alkenes with alkyl nitriles and amines toward γ-amino alkyl nitriles
2.5 Radical–Polar Crossover Reactions
International audienceAbstract Radical–polar crossover reactions, that is, single-electron redox events allowing for the interconversion between radical and ionic intermediates, make it possible to connect radical and polar processes in the same synthetic transformation. Such a combination is the basis of much original synthetic methodology, which is particularly useful in the context of domino, tandem, or multicomponent reactions. This chapter comprehensively covers the field of radical–polar crossover reactions, with a primary emphasis on transformations wherein both the radical and polar processes provide synthetic elaboration