Schottky barrier heights and interface chemistry in Ag, In, and Al overlayers on GaP(110)

We have carried out a study of the chemical reaction of silver, indium, and aluminium layers with cleaved GaP(110) surfaces using photoemission with synchrotron radiation. Core level photoelectron spectra show that silver and indium overlayers do not cause an interface reaction with GaP(110). The deposition of Al, on the other hand, leads to an extensive exchange reaction which also proceeds at low temperature, although influenced by changes in overlayer growth morphology. Surface band bending induced by the metallic overlayers was investigated as a function of deposition for n‐ and p‐type material. In contrast to earlier findings, almost identical Schottky barrier heights for In and Ag deposition are obtained, despite the large difference in work function between these two metals. Results for Al also suggest that a small range of pinning positions is responsible for the Schottky barrier heights for junctions of these metals with GaP(110). We find that large peak shifts due to a surface photovoltage induced by the photoemission light source affect the determination of the Schottky barrier heights. This and other possible reasons for the discrepancy with earlier work are discussed

Density Functional Molecular Study on the Full Conformational Space of the S-4-(2-Hydroxypropoxy)carbazol Fragment of Carvedilol (1-(9H−Carbazol-4-yloxy)-3- [2-(2-methoxyphenoxy)ethylamino]-2-propanol) in Vacuum and in Different Solvent Media

Density functional theory (DFT) conformational analysis was carried out on the potential energy hypersurface (PEHS) of the carbazole-containing molecular fragment, S-4-(2-hydroxypropoxy)-carbazol, of the chiral cardiovascular drug molecule carvedilol, (1-(9H-carbazol-4-yloxy)-3-[2-(2-methoxy-phenoxy)ethylamino]-2-propanol) . The PEHS was computed in vacuum, chloroform, ethanol, DMSO, and water at the B3LYP/6-31G(d) level of theory. The carbazole ring system was confirmed to be planar, and the resultant PEHS in vacuum contained 19 converged minima, of which the global minima possessed a conformation with chi(1), chi(2), and chi(3) in the anti position and chi(10) in the g position. Conformer stability for the S-4-(2-hydroxypropoxy)carbazol PEHS was influenced by intramolecular hydrogen bonding. Tomasi PCM reaction-field calculations revealed that the lowest SCF energies, relative conformer energies, and solvation free energies (DeltaG (solvation)) for the S-4-(2-hydroxypropoxy)carbazol PEHS were in protic solvents, ethanol and water, because of the larger hydrogen bond donor values of these solvents, which aid in stabilization of the dipole moment created by the carbazole ring system and the oxygen and nitrogen atoms. However, solvent effects contributed most significantly to the stabilization of S-4-(2-hydroxypropoxy)carbazol conformers that contained no internal hydrogen bonding, whereas solvent effects were not as important for conformers that contained intramolecular hydrogen bonding

New Measurements of Upsilon(1S) Decays to Charmonium Final States

Using substantially larger data samples collected by the CLEO III detector, we report on new measurements of the decays of Upsilon(1S) to charmonium final states, including J/Psi, psi(2S), and chi_cJ. The latter two are first observations of these decays. We measure the branching fractions as follows: B(Y(1S)--> J/Psi+X)=(6.4+-0.4+-0.6)x10^-4, B(Y(1S)--> psi(2S)+X)/B(Y(1S)--> J/Psi+X)=0.41+-0.11+-0.08, B(Y(1S)--> chi_c1+X)/B(Y(1S)--> J/Psi+X)=0.35+-0.08+-0.06, B(Y(1S)--> chi_c2+X)/B(Y(1S)--> J/Psi+X)=0.52+-0.12+-0.09, and B(Y(1S)--> chi_c0+X)/B(Y(1S)--> J/Psi+X)<7.4% at 90% confidence level. We also report on the momentum and angular spectra of J/Psi's in Upsilon(1S) decay. The results are compared to predictions of the color octet and color singlet models.Comment: 27 pages postscript,also available through http://w4.lns.cornell.edu/public/CLNS/, submitted to PR

Search for X(3872) in gamma gamma Fusion and ISR at CLEO

We report on a search for the recently reported X(3872) state using 15.1 fb^{-1} e+ e- data taken in the \sqrt{s} = 9.46-11.30 GeV region. Separate searches for the production of X(3872) in untagged gamma-gamma fusion and e+ e- annihilation following initial state radiation (ISR) are made by taking advantage of the unique correlation of J/psi -> l+ l- in X(3872) decay to pi+ pi- J/psi. No signals are observed in either case, and 90% confidence upper limits are established as (2J+1)\Gamma_{\gamma\gamma}B(X -> pi+ pi- J/psi) < 12.9 eV and \Gamma_{ee}B(X -> pi+ pi- J/psi) < 8.3 eV.Comment: 8 pages postscript,also available through http://www.lns.cornell.edu/public/CLNS/2004/, submitted to PR

The Search for eta(1440) --> K^0_S K^pm \pi^mp in Two-Photon Fusion at CLEO

We analyze 13.8 \rm fb^{-1} of the integrated e^+e^- luminosity collected at 10.6 GeV center-of-mass energy with the CLEO II and CLEO II.V detectors to study exclusive two-photon production of hadrons with masses below 1.7{\rm \ GeV/c^2} decaying into the K^0_S K^\pm \pi^\mp final state. We observe two statistically significant enhancements in the \eta(1440) mass region. These enhancements have large transverse momentum which rules them out as being due to pseudoscalar resonances but is consistent with the production of axial-vector mesons. We use tagged two-photon events to study the properties of the observed enhancements and associate them with the production of f_1(1285) and f_1(1420). Our non-observation of \eta(1440) is inconsistent by more than two standard deviations with the first observation of this resonance in two-photon collisions by the L3 experiment. We present our estimates for 90% confidence level upper limits on the products of two-photon partial widths of pseudoscalar hadrons and their branching fractions into K^0_S(\pi^+\pi^-)K^\pm\pi^\mp.Comment: 24 pages postscript,also available through http://www.lns.cornell.edu/public/CLNS/2004/, submitted to PR

Measurement of \cal{B}(D^+ --> mu^+ nu) and the Pseudoscalar Decay Constant fD+f_{D^+}

In 60 pb-1 of data taken on the psi(3770) resonance with the CLEO-c detector, we find 8 D+ to mu+ nu event candidates that are mostly signal, containing only 1 estimated background. Using this statistically compelling sample, we measure preliminary values of B(D+ to mu+ nu) = (3.5 +- 1.4 +- 0.6)*10^{-4}, and determine f_{D+} =(201+- 41+- 17) MeV.Comment: 17 pages postscript, also available through http://www.lns.cornell.edu/public/CONF/2004/, Presented at ICHEP Aug 16-22,2004, Beijing, Chin

Study of tau Decays to Four-Hadron Final States with Kaons

The tau decays to four hadrons have been studied with the CLEO III detector at the Cornell Electron Storage Ring (CESR) using (7.56 +- 0.15) fb^{-1} of data collected near the Y(4S) resonance. We present the first statistically significant measurements of B(tau- -> K- pi+pi- pi0 nu, excluding K^0) = (7.4 +- 0.8 +- 1.1) x 10^{-4} and B(tau--> K- K+ pi- pi0 nu) = (5.5 +- 1.4 +- 1.2) x 10^{-5}, including the first observation of the decay, tau- -> K- omega nu, with branching fraction (4.1 +- 0.6 +- 0.7) x 10^{-4}. We also publish the first upper limit for B(tau- -> K- K+ K- pi0 nu) < 4.8 (6.1) x 10^{-6} at 90% (95%) confidence level (C.L.).Comment: 9 pages postscript, also available from http://www.lns.cornell.edu/public/CLNS/2004/, submitted to PR

Photon transitions in Upsilon(2S) and Upsilon(3S)

We have studied the inclusive photon spectra in Upsilon(2S) and \Upsilon(3S) decays using a large statistics data sample obtained with the CLEO III detector. We present the most precise measurements of electric dipole (E1) photon transition rates and photon energies for Upsilon(2S)->gamma chi_bJ(1P) and Upsilon(3S)->gamma chi_bJ(2P) J=0,1,2. We measure the rate for a rare E1 transition Upsilon(3S)->gamma chi_b0(1P) for the first time. We also set upper limits on the rates for the hindered magnetic dipole (M1) transitions to the eta_b(1S) and eta_b(2S) states.Comment: 10 pages postscript,also available through http://www.lns.cornell.edu/public/CLNS/2004/, submitted to PR

Limits on Neutral D Mixing in Semileptonic Decays

Using the CLEO II.V detector observing e+e- collisions at around 10.6 GeV we search for neutral D mixing in semileptonic D0 decays tagged in charged D* decays. Combining the results from the Kenu and K*enu channels we find that the rate for D mixing is less than 0.0078 at 90% C.L.Comment: 9 pages postscript,also available through http://www.lns.cornell.edu/public/CLNS/2005/, submitted to PR

Measurement of Absolute Hadronic Branching Fractions of D Mesons and e^+e^- --> D barD Cross Sections at E_cm = 3773 MeV

Using 55.8 pb^-1 of e^+e^- collisions recorded at the psi(3770) resonance with the CLEO-c detector at CESR, we determine absolute hadronic branching fractions of charged and neutral D mesons using a double tag technique. Among measurements for three D^0 and six D^+ modes, we obtain reference branching fractions B(D^0 -> K^- pi^+)=(3.91 +- 0.08 +- 0.09)% and B(D^+ -> K^- pi^+ pi^+)=(9.5 +- 0.2 +- 0.3)%, where the uncertainties are statistical and systematic, respectively. Final state radiation is included in these branching fractions by allowing for additional, unobserved, photons in the final state. Using a determination of the integrated luminosity, we also extract the cross sections sigma(e^+e^- -> D^0 \bar D^0)=(3.60 +- 0.07 +0.07-0.05) nb and sigma(e^+e^- -> D^+D^-)=(2.79 +- 0.07 +0.10-0.04) nb.Comment: 9 pages postscript,also available through http://www.lns.cornell.edu/public/CLNS/2005/, submitted to PR