11,306 research outputs found
Stabilization of Polystyrene by Friedel-Crafts Chemistry: Effect of Position of Alcohol and the Catalyst
Polystyrene has been copolymerized with 4-vinylbenzyl alcohol, 4-(2-hydroxyethyl)styrene, and 4-(3-hydroxypropyl)styrene and it has been shown that thermal cross-linking of these copolymers is dependent upon the alcohol content. When the alcohol content is low, no thermal cross-linking is observed. When various phosphate esters are present as catalysts with these low alcohol content copolymers, cross-linking is observed at temperatures of about 250°C but not at lower temperatures. Cross-linking enhances the thermal stability of the copolymers. Studies of the thermal stability of the copolymers and their blends with the catalysts have been performed using thermogravimetric analysis and thermogravimetric analysis coupled to Fourier transform infrared spectroscopy. There is little difference in the thermal stability of all three copolymers and their blends with the catalysts
An XPS study of the thermal degradation of polystyrene-clay nanocomposites
X-ray photoelectron spectroscopy, XPS, has been used to examine several polystyrene-clay nanocomposites. The accumulation of oxygen, from the almuniosilicate, on the surface of the polymer was observed, along with the loss of carbon. This confirms that the barrier properties of the clay provide a mechanism by which nanocomposite formation can enhance the fire retardancy of the polymers. No difference is detected depending upon the extent of exfoliation or intercalation of the nanocomposite. #2002 Elsevier Science Ltd. All rights reserved
An XPS Investigation of Thermal Degradation and Charring of PMMA Clay Nanocomposites
Poly(methyl methacrylate)–clay nanocomposites have been studied using X-ray photoelectron spectroscopy. It is clear that as the polymer undergoes thermal degradation, the clay accumulates at the surface and the barrier properties which result from this clay accumulation have been described as the reason for the decreased heat release rate for nanocomposites. The surface composition of the clay changes as the nanocomposite is heated and the changes are affected by the organic-modification that were applied to the clay in order to prepare the nanocomposite
Crown Ether-Modified Clays and their Polystyrene Nanocomposites
Crown ether-modified clays were obtained by the combination of sodium and potassium clays with crown ethers and cryptands. Polystyrene nanocomposites were prepared by bulk polymerization in the presence of these clays. The structures of nanocomposites were characterized by X-ray diffraction and transmission electron microscopy. Their thermal stability and flame retardancy were measured by thermogravimetric analysis and cone calorimetry, respectively. Nanocomposites can be formed only from the potassium clays; apparently the sodium clays are not sufficiently organophilic to enable nanocomposite formation. The onset temperature of the degradation is higher for the nanocomposites compared to virgin polystyrene, and the peak heat release rate is decreased by 25% to 30%
Long-term Evolution of Protostellar and Protoplanetary Disks. I. Outbursts
As an initial investigation into the long-term evolution of protostellar
disks, we explore the conditions required to explain the large outbursts of
disk accretion seen in some young stellar objects. We use one-dimensional
time-dependent disk models with a phenomenological treatment of the
magnetorotational instability (MRI) and gravitational torques to follow disk
evolution over long timescales. Comparison with our previous two-dimensional
disk model calculations (Zhu et al. 2009b, Z2009b) indicates that the neglect
of radial effects and two-dimensional disk structure in the one-dimensional
case makes only modest differences in the results; this allows us to use the
simpler models to explore parameter space efficiently. We find that the mass
infall rates typically estimated for low-mass protostars generally result in
AU-scale disk accretion outbursts, as predicted by our previous analysis (Zhu
et al. 2009a,Z2009a). We also confirm quasi-steady accretion behavior for high
mass infall rates if the values of -parameter for the magnetorotational
instability is small, while at this high accretion rate convection from the
thermal instability may lead to some variations. We further constrain the
combinations of the -parameter and the MRI critical temperature, which
can reproduce observed outburst behavior. Our results suggest that dust
sublimation may be connected with full activation of the MRI. This is
consistent with the idea that small dust captures ions and electrons to
suppress the MRI. In a later paper we will explore both long-term outburst and
disk evolution with this model, allowing for infall from protostellar envelopes
with differing angular momenta.Comment: Accepted to publish in Ap
- …