The \u3csup\u3e13\u3c/sup\u3eC-NMR Solid State Spectroscopy of Various Classes of Coals

The 13C-NMR spectra of various classes of coal obtained in the solid state show two resonances, one of which is assigned to aromatic carbon and the other to aliphatic carbon. The resonances are very broad with the high field resonance centered at about 7 ppm below tetramethylsilane and a low field resonance centered at about 140 ppm below tetramethysilane. Based on our previous solid state 13C-NMR studies of graphite and diamond, the high field resonance is typical of a sp3 carbon whereas the low fields resonance is assigned to a sp2 carbon whereas the low fields resonance is assigned to a sp2 carbon. It is found that the antracitic coals have more aromatic (sp2) carbons than the bituminous, subbituminous and lignite coals. The analytical implications of this technique are briefly discussed

The Solid State \u3csup\u3e13\u3c/sup\u3eC-NMR Spectra of Some Carbides

The utility of NMR spectroscopy to the study of liquids or solids dissolved in liquids is well known. This technique has been used infrequently to studies in the solid state[I,2]. Work has been done on diamond, graphite and coa113-6]. The 13C-NMR of ebony and ivory have been studied by the magic angle technique[7]. The solid state 13C-NMR spectra of graphite and diamond can be interpreted in terms of tetrahedral (sp3) and trigonal planar (sp2) carbon atoms[8]. We now report our investigations using solid state 13C-NMR spectroscopy to study various types of carbides

A TiO study of the black-hole binary GRO J0422+32 in a very low state

We present 53 simultaneous photometric (I band) and spectroscopic (6900-9500 Angstroms) observations of J0422+32, taken during December 1997. From these we determine that J0422+32 was in its lowest state yet observed, at I=20.44+/-0.08. Using relative spectrophotometry, we show that it is possible to correct very accurately for telluric absorption. Following this, we use the TiO bands at 7055 Angstroms and 7589 Angstroms for a radial velocity study and thereby obtain a semi-amplitude of 378+/-16kms-1, which yields f(M)=1.191+/-0.021M_solar and q=9.0+2.2-2.7, consistent with previous observations. We further demonstrate that this little explored method is very powerful for such systems. We also determine a new orbital ephemeris of HJD=2450274.4156+/-0.0009 + 0.2121600+/-0.0000002E. We see some evidence for an ellipsoidal modulation, from which we determine the orbital inclination of J0422+32 to be less than 45 degrees. We therefore calculate a minimum mass for the primary of 2.22M_solar, consistent with a black hole, but not necessarily the super-massive one proposed by Beekman et al (1997). We obtain an M4-5 spectral type for the secondary star and determine that the secondary contributes 38+/-2% of the flux that we observe from J0422+32 over the range 6950-8400 Angstroms. From this we calculate the distance to the system to be 1.39+/-0.15kpc.Comment: (1) Department of Physics, Keele University, Keele, Staffordshire, ST5 5BG (2) Department of Astrophysics, Nuclear Physics Laboratory, Keble Road, Oxfo rd, OX1 3RH Accepted, to appear in MNRAS 8 pages, 5 figure

Spectroscopic Identification of the Infrared Counterpart to GX5-1

Using CGS4 on UKIRT, we have obtained a 1.95-2.45 micron infrared spectrum of the primary candidate counterpart to the bright Z LMXB GX5-1. IR photometry by Naylor, Charles, & Longmore (1992) and the astrometry of Jonker et al. (2000) had previously identified this star as the most likely counterpart to GX5-1. The spectrum presented here clearly shows Brackett gamma and He lines in emission, for the first time confirming the identity of the counterpart. Similar to our previous spectroscopy of the Z source LMXBs Sco X-1 and Sco X-2 (Bandyopadhyay et al. 1999), the K-band spectrum of GX5-1 shows emission lines only. We briefly discuss the implications of this spectrum for the nature of the Z sources.Comment: accepted for publication as a Letter in MNRA

Loan sales as a response to market-based capital constraints

A model of bank asset sales in which information asymmetries create the incentive for unregulated banks to originate and sell loans to other banks, rather than fund them with deposit liabilities. Private information implies that bankers can fund local loans only to the extent that their capital can absorb potential losses. Loan sales are effectively a means of employing nonlocal bank capital to support local investments.Bank capital ; Bank loans