Modeling the effect of rate and geometry on peeling and tack of pressure-sensitive adhesives

A model is developed for predicting separation along interfaces of pressure sensitive adhesives. Many authors have used the cohesive zone approach to solve such problems but the parameter calibration of such models remains uncertain. This study reports a novel method for determining such parameters. In addition, it provides crucial evidence for the suitability of the cohesive zone model approach in modelling interface fractures. Peel tests were performed at various rates using specimens which consisted of a polyester backing membrane supporting an acrylic pressure-sensitive adhesive (PSA) adhered to a polyethylene substrate. Interfacial separation of the PSA from the polyethylene substrate was observed. Finite element (FE) peeling simulations were conducted which modeled the backing-membrane as an elasto-plastic power-law material, the adhesive as a viscoelastic material and the interfacial properties with a cohesive zone model (CZM). The material properties of the backing membrane and the pressure-sensitive adhesive were measured from tensile and stress relaxation experiments. The rate-dependent CZM parameters were measured directly from poker-chip probe-tack tests which were performed at pull-off speeds which corresponded to the rates employed for the peel tests. The effect of the PSA thickness and test rate on both tack and peel was investigated experimentally, as well as modeled numerically. Good agreement was found between the experimentally measured and numerically predicted peel forces for different peel angles, speeds and PSA thicknesses. In addition, it was proven that the rate dependence observed in the peel and probe-tack data was dominated by the rate dependence of the interface properties, i.e. the time dependence of the two CZM parameters of maximum stress and fracture energy, rather than the time-dependent bulk viscoelasticity of the PSA peel arm

A systematic approach to the formulation of anti-onychomycotic nail patches

Nail patches have a potential role as drug carriers for the topical treatment of nail diseases such as onychomycosis, a common condition. O ur aim was therefore to develop a systematic and novel appr oach to the formulat ion of a simple drug -in-adhesive ungual patch. Twelve pressure -sensitive adhesives (PSAs), four backing membranes, two release liners and three drugs were screened for pharmaceutical and mechanical properties . From this initial screeni ng, two PSAs, two drugs, one backing membrane and one release liner were selected for further investigation. Patches were prepared by solvent -casting and characterised. The patches had good uniformity of thickness and of drug content, and showed minimal drug crystallisation during six month s of storage. Meanwhile, the d rug stability in the patch upon storage and patch adhesion to the nail was influenced by the nature of the drug, the PSA and the backing membrane . The reported methodology paves the way for a systematic formulation of ungual nail patches to add to the armamentarium of nail medicines . Further , from this work, the best patch formulation has been identified

The effects of strain rate and temperature on commercial acrylic artist paints aged one year to decades

Acrylic artist paints are viscoelastic composites containing a high molecular weight copolymer, pigment and a variety of additives. The glass transition temperature of the latex binder is typically slightly below ambient conditions, giving mechanical properties that are strongly dependent on strain rate and temperature. In previous work, the viscoelastic behaviour of custom-formulated latex artist paints was reported for films with known volume fractions of pigment using data from uniaxial tensile tests at different strain rates and temperatures. Secant Young’s modulus and failure strain master curves were constructed for each film through time-temperature superposition, allowing predictions beyond the experimental timescale at a selected reference temperature. A similar analysis is now presented for a small set of commercial artist paints tested at ages of 1 and 27 years. Experimental shift factor values are reported with fits to the Arrhenius, WLF and Vogel Fulcher equations, along with a comparison with published data for acrylic polymers. The tensile results highlight a spectrum of properties that acrylic paints may exhibit—brittle glass to hyperelastic—depending on the conditions during deformation. Strong similarities are shown between products from different manufacturers, and the findings suggest a high degree of stability with age. A method for predicting failure as a function of strain rate and temperature is also presented, and the methodology gives a framework for investigating other artist materials and the factors influencing their mechanical properties

On modelling the constitutive and damage behaviour of highly non-linear bio-composites - Mesh sensitivity of the viscoplastic-damage law computations

The large strain fracture of non-linear complex solids concerns a wide range of applications, such as material forming, food oral processing, surgical instrumental penetration as well as more recently, the design of biodegradable composites for packaging and bio-medical use. Although simulations are a powerful tool towards understanding and designing such processes, modelling ductile fracture in materials such as soft natural composites imposes a new challenge, particularly when the fracture patterns cannot be pre-defined. Here we bring to light new information on these aspects of benefit to the multidisciplinary community, by characterising and modelling the deformation and fracture of short cellulose fibre starch extruded composites. Hyperviscoelastic-Mullins damage laws show merits in modelling such complex systems. Yet they are inferior to a viscoplastic-damage law able to capture exactly their highly non-linear, rate dependent and pressure dependent pseudo-plastic stress-strain response. The viscoplastic-damage law also predicts fracture based on experimental toughness values without pre-specifying the crack path in a Finite Element (FE) model, displaying superiority over the conventional cohesive zone approach. Yet, despite using a toughness parameter to drive crack propagation, spurious mesh dependency is still observed while other previously unreported sources of error imposed by the finite element aspect ratio are also highlighted. The latter is rectified by developing a novel numerical strategy for calculating the characteristic element length used in the damage computations. Inherent mesh dependency suggests that non-local damage models may be essential to model this newly investigated class of natural composites

Hierarchical multi-scale models for mechanical response prediction of highly filled elastic–plastic and viscoplastic particulate composites

Though a vast amount of literature can be found on modelling particulate reinforced composites and suspensions, the treatment of such materials at very high volume fractions (>90%), typical of high performance energetic materials, remains a challenge. The latter is due to the very wide particle size distribution needed to reach such a high value of In order to meet this challenge, multiscale models that can treat the presence of particles at various scales are needed. This study presents a novel hierarchical multiscale method for predicting the effective properties of elasto-viscoplastic polymeric composites at high . Firstly, simulated microstructures with randomly packed spherical inclusions in a polymeric matrix were generated. Homogenised properties predicted using the finite element (FE) method were then iteratively passed in a hierarchical multi-scale manner as modified matrix properties until the desired filler was achieved. The validated hierarchical model was then applied to a real composite with microstructures reconstructed from image scan data, incorporating cohesive elements to predict debonding of the filler particles and subsequent catastrophic failure. The predicted behaviour was compared to data from uniaxial tensile tests. Our method is applicable to the prediction of mechanical behaviour of any highly filled composite with a non-linear matrix, arbitrary particle filler shape and a large particle size distribution, surpassing limitations of traditional analytical models and other published computational models

A systematic approach to the formulation of anti-onychomycotic nail patches

Nail patches have a potential role as drug carriers for the topical treatment of nail diseases such as onychomycosis, a common condition. Our aim was therefore to develop a systematic and novel approach to the formulation of a simple drug-in-adhesive ungual patch. Twelve pressure-sensitive adhesives (PSAs), four backing membranes, two release liners and three drugs were screened for pharmaceutical and mechanical properties. From this initial screening, two PSAs, two drugs, one backing membrane and one release liner were selected for further investigation. Patches were prepared by solvent-casting and characterised. The patches had good uniformity of thickness and of drug content, and showed minimal drug crystallisation during six months of storage. Meanwhile, the drug stability in the patch upon storage and patch adhesion to the nail was influenced by the nature of the drug, the PSA and the backing membrane. The reported methodology paves the way for a systematic formulation of ungual nail patches to add to the armamentarium of nail medicines. Further, from this work, the best patch formulation has been identified

Determination of a critical stress and distance criterion for crack propagation in cutting models of cheese

A critical stress at a critical distance crack propagation criterion is a good way to model the fracture in cheese. This physical criterion states that the crack-tip node debonds when the stress at a specified distance ahead of the crack tip on the assumed crack path reaches a critical value. Although this criterion is already used in other research domains, no consistent information exists on how the critical stress and distance should be determined. A repeatable method for the determination of this criterion which combines experimental and numerical single edge notched bending tests was acquired. This criterion was validated with wire cutting experiments of cheese. The experimental and numerical results showed the same trend with a clear wire indentation and steady state cutting phase. The determination of a critical stress and distance criterion as proposed in this research is a good approach to model fracture and cutting of cheese