Effects of Lizardite Addition on Technological Properties of Forsterite-monticellite Rich Ceramics Prepared from Natural Magnesite and Dolomite

Lizardite rich peridotite has never been used to prepare ceramic specimens, especially in Morocco. For this raison, potential use of naturally abundant lazirditic material from the Rif domain, as a supply for ceramic industry, has been evaluated. The effects of lizardite addition to magnesite and dolomite mixtures on the thermomechanical properties of the calcined ceramics were also detailed. To achieve this target, natural lizardite, magnesite and dolomite samples were collected in ultrabasic Beni Bousra massif. Those raw samples were used for the synthesis of a forsterite-monticellite rich ceramics. Both raw and sintered samples were characterized by x-ray diffraction, scanning electron microscope and fourier transform infrared. The obtained results showed that both magnesite and dolomite were mainly composed of MgCO3 and CaCO3. In contrast, lizardite sample showed high amounts of SiO2, MgO and Fe2O3. An increased amount of lizardite in the initial mixtures enhanced mechanical and dimensional properties of the prepared ceramic specimens, and subsequently, the production of ceramics with the required technological properties. Thus, the preparation of Moroccan lizardite-based ceramics is technically feasible, economically justifiable and socially desirable due to the contribution to the economic growth of the raw materials sector, especially ceramic industry

Processing and characterization of alumina–mullite ceramics

Processing of mullite and alumina based refractory ceramic by unidirectional dry pressing, from two mixtures that include silica sand, pure alumina (PA) and recycled alumina (RA) is described. The samples were sintered up to 1600 °C to study the refractory properties. The fired properties of materials (firing shrinkage, water absorption, density, flexural strength, refractoriness, and SEM microstructure) were evaluated. Promising refractories materials based on mullite and alumina were obtained

Recent advances in silica-alumina refractory: A review

In this article, the elaboration and the characterization of silica-alumina refractory have been reviewed. Refractory oxides encompass a broad range of unary, binary, and ternary ceramic compounds that can be used in structural, insulating, and other applications. This paper provides a historical perspective on the elaboration and the use of silica-alumina refractory, reviews applications for refractory oxides, describes typical processing routes, overviews fundamental structure–property relations, and summarizes the properties of these materials

Review on the elaboration and characterization of ceramics refractories based on magnesite and dolomite

One of the most important elements of furnaces, boilers and other heating units is the structure (lining), usually made of silica–alumina, basic or special refractories. The basic refractories are materials that are increasingly in demand and whose manufacturing involves necessarily the use of MgO and CaO. In this article, the description and characterization of magnesite (MgCO3) and dolomite (Mg,Ca(CO3)2) and their contribution in industrial ceramics-refractories have been reviewed

Complete characterization of Berrechid clays (Morocco) and manufacturing of new ceramic using minimal amounts of feldspars: Economic implication

This work proposes the mixing of two varieties of Moroccan clay (C1 and C2) with silica sand in order to minimize the amount of the feldspar used. The raw materials were previously characterized in terms of their composition and thermal behavior. Two formulations noted M1 and M2 were elaborated according to the experimental protocol and they were evaluated in terms of their mechanical and thermal characteristics. The addition of C2 clay in the formulation allows a reduction in the amounts of feldspar of the order of 5%, while improving the technological characteristics of this new ceramic (M2) compared to that obtained by the conventional formulation. Indeed, the obtained ceramic (M2) shows the following characteristics: porosity (11.65%); density (2.71 g/cm3); shrinkage (4.91%); flexural strength (30.05 N mm−2) and thermal conductivity (2.73 W/mK). Results of this study permit a reduction in the amount of the feldspar used, a relatively expensive raw material, and consequently reduces the cost of ceramics

Effects of slag addition and sintering temperature on the technological properties of dolomite based porous ceramics

This work focuses on the synthesis of basic porous ceramics prepared from Moroccan dolomite. The effect of the addition of slag on the technological and mechanical properties of the final product was also described. The starting materials were characterized in terms of chemical composition (XRF), mineralogical (XRD), and thermal characterizations (DTA-TG). Next, Different ceramic bodies were prepared by the uniaxial pressing and sintering methods at different temperatures up to 1300 °C. The effect of sintering in the range of 1100–1300 °C on the morphology, composition of the developed phases, technological properties (i.e., porosity, water absorption, density and shrinkage), resistance to flexural stress, and also chemical resistance were investigated. The optimum sintering temperature is 1200 °C, in which the porosity was 50.28–41.4%, the density was 1.7–1.89 g/cm3, the water absorption was 28.07–24.8%, and the shrinkage was 1.55–6.25% as well as varying the amount of slag added. The experimental results showed clearly that slag was a good candidate to enhance the quality of ceramic products especially for mechanical properties

Elaboration of a high mechanical performance refractory from halloysite and recycled alumina

The present study is a contribution to the valorization of halloysite clay from North Eastern Rif (Nador, Morocco) in the field of Silica-alumina refractory. For this purpose, six mixtures (M1–M6) were tested using marl, diatomite and silica sand aggregates in order to enhance halloysite performances, and to develop high temperature ceramic up to 1300 °C (silico-aluminous refractory “S-Al-R”). Among all the mixtures tested, the mixture M6 provides good technical quality: Porosity (P) = 21.75%; density (d) = 1.94 g/cm3; thermal shrinkage (R) = 2.7% and flexural strength (Rf) = 29.05 MPa. Addition to the mixture (M6) of 25% of the recycled alumina “Rec-Al”, obtained from silico-aluminous refractory bricks waste, has substantially strengthened the mechanical performance of the silico-aluminous refractory (Rf = 45.08 MPa).Waste valoraisatio