Growth mechanism of nanocrystals in solution: ZnO, a case study

We investigate the mechanism of growth of nanocrystals from solution using the case of ZnO. Spanning a wide range of values of the parameters, such as the temperature and the reactant concentration, that control the growth, our results establish a qualitative departure from the widely accepted diffusion controlled coarsening (Ostwald ripening) process quantified in terms of the Lifshitz-Slyozov-Wagner theory. Further, we show that these experimental observations can be qualitatively and quantitatively understood within a growth mechanism that is intermediate between the two well-defined limits of diffusion control and kinetic control.Comment: 10 pages, 4 figure

Oscillating magnetoresistance due to fragile spin structure in metallic GdPd3_3

Studies on the phenomenon of magnetoresistance (MR) have produced intriguing and application-oriented outcomes for decades--colossal MR, giant MR and recently discovered extremely large MR of millions of percents in semimetals can be taken as examples. We report here the investigation of oscillating MR in a cubic intermetallic compound GdPd$_3$, which is the only compound that exhibits MR oscillations between positive and negative values. Our study shows that a very strong correlation between magnetic, electrical and magnetotransport properties is present in this compound. The magnetic structure in GdPd$_3$ is highly fragile since applied magnetic fields of moderate strength significantly alter the spin arrangement within the system--a behavior that manifests itself in the oscillating MR. Intriguing magnetotransport characteristics of GdPd$_3$ are appealing for field-sensitive device applications, especially if the MR oscillation could materialize at higher temperature by manipulating the magnetic interaction through perturbations caused by chemical substitutions.Comment: 10 pages, 7 figures. A slightly modified version is published in Scientific Report

Relating transverse structure of various parton distributions

We present the results of T-even TMDs in a light front quark-diquark model of nucleons with the wave functions constructed from the soft-wall AdS/QCD prediction. The relations amongst TMDs are discussed. The $p_\perp$ dependence of the TMDs are compared with the $t$-dependence of the GPDs. AdS/QCD wave function provides an explanation behind the approximate $x$ and $p_\perp$ factorization observed in lattice TMD calculations.Comment: 11 pages, 8 figures, modified extensively, added new results and discusssion

Phase diagram of vortex matter in layered superconductors with random point pinning

We study the phase diagram of the superconducting vortex system in layered high-temperature superconductors in the presence of a magnetic field perpendicular to the layers and of random atomic scale point pinning centers. We consider the highly anisotropic limit where the pancake vortices on different layer are coupled only by their electromagnetic interaction. The free energy of the vortex system is then represented as a Ramakrishnan-Yussouff free energy functional of the time averaged vortex density. We numerically minimize this functional and examine the properties of the resulting phases. We find that, in the temperature ($T$) -- pinning strength ($s$) plane at constant magnetic induction, the equilibrium phase at low $T$ and $s$ is a Bragg glass. As one increases $s$ or $T$ a first order phase transition occurs to another phase that we characterize as a pinned vortex liquid. The weakly pinned vortex liquid obtained for high $T$ and small $s$ smoothly crosses over to the strongly pinned vortex liquid as $T$ is decreased or $s$ increased -- we do not find evidence for the existence, in thermodynamic equilibrium, of a distinct vortex glass phase in the range of pinning parameters considered here. %cdr We present results for the density correlation functions, the density and defect distributions, and the local field distribution accessible via $\mu$SR experiments. These results are compared with those of existing theoretical, numerical and experimental studies.Comment: 15 pages, including figures. Higher resolution files for Figs 3a and 11 available from author

Approximation of Rupture Directivity in Regional Phases Using Upgoing and Downgoing Wave Fields

Recent broadband modeling of regional events suggests that vertical directivity is particularly important at high frequency. Conventionally, such directivity is obtained by summing a grid of point sources. This relatively time-consuming procedure can be greatly reduced by introducing directivity time histories appropriate for the various crustal phases in terms of upgoing and downgoing paths that are calculated at only one depth. To achieve this, we formulated frequency-wavenumber solutions for a simultaneous computation of surface displacement for three wave fields, upgoing, downgoing, and the total from a seismic source buried in a layered medium (Appendix A). The concept of upgoing and downgoing wave field is introduced in the source layer matrix explicitly before allowing the source coefficients to interact with the propagation of the stress-displacement vector. Using this new algorithm, we generated a set of upgoing and downgoing wave fields at a fixed depth for different crustal models. We also simulated the effects of rupture propagation using distributed point-source summations and predicted the same effect by summing the upgoing and downgoing wave fields calculated at a single depth, each convolved with a separate analytical boxcar function representing the far-field rupture. A library of these new Green's functions should prove much more effective in modeling recorded motions than using point-source Green's functions alone

Evaluation of rice–legume–rice cropping system on grain yield, nutrient uptake, nitrogen fixation, and chemical, physical, and biological properties of soil

To achieve higher yields and better soil quality under rice–legume–rice (RLR) rotation in a rainfed production system, we formulated integrated nutrient management (INM) comprised of Azospirillum (Azo), Rhizobium (Rh), and phosphate-solubilizing bacteria (PSB) with phosphate rock (PR), compost, and muriate of potash (MOP). Performance of bacterial bioinoculants was evaluated by determining grain yield, nitrogenase activity, uptake and balance of N, P, and Zn, changes in water stability and distribution of soil aggregates, soil organic C and pH, fungal/bacterial biomass C ratio, casting activities of earthworms, and bacterial community composition using denaturing gradient gel electrophoresis (DGGE) fingerprinting. The performance comparison was made against the prevailing farmers’ nutrient management practices [N/P2O5/K2O at 40:20:20 kg ha−1 for rice and 20:30:20 kg ha−1 for legume as urea/single super-phosphate/MOP (urea/SSP/MOP)]. Cumulative grain yields of crops increased by 7–16% per RLR rotation and removal of N and P by six crops of 2 years rotation increased significantly (P < 0.05) in bacterial bioinoculants-based INM plots over that in compost alone or urea/SSP/MOP plots. Apparent loss of soil total N and P at 0–15 cm soil depth was minimum and apparent N gain at 15–30 cm depth was maximum in Azo/Rh plus PSB dual INM plots. Zinc uptake by rice crop and diethylenetriaminepentaacetate-extractable Zn content in soil increased significantly (P < 0.05) in bacterial bioinoculants-based INM plots compared to other nutrient management plots. Total organic C content in soil declined at 0–15 cm depth and increased at 15–30 cm depth in all nutrient management plots after a 2-year crop cycle; however, bacterial bioinoculants-based INM plots showed minimum loss and maximum gain of total organic C content in the corresponding soil depths. Water-stable aggregation and distribution of soil aggregates in 53–250- and 250–2,000 μm classes increased significantly (P < 0.05) in bacterial bioinoculants-based INM plots compared to other nutrient management plots. Fungal/bacterial biomass C ratio seems to be a more reliable indicator of C and N dynamics in acidic soils than total microbial biomass C. Compost alone or Azo/Rh plus PSB dual INM plots showed significantly (P < 0.05) higher numbers of earthworms’ casts compared to urea/SSP/MOP alone and bacterial bioinoculants with urea or SSP-applied plots. Hierarchical cluster analysis based on similarity matrix of DGGE profiles revealed changes in bacterial community composition in soils due to differences in nutrient management, and these changes were seen to occur according to the states of C and N dynamics in acidic soil under RLR rotation

Innovative Technologies for Enhanced Availability of Bajra-Napier Hybrid Rooted Slips

Livestock occupies a crucial position in Indian agriculture and directly contributing 4.1% of total GDP of the country. India, with 2.29% of the world land area, is maintaining about 10.71% of the world’s livestock population. To sustain the present milk growth rate of 4.04% and for further expansion to meet the demands of ever growing human population, livestock needs sustainable supply of feed material. The area under fodder cultivation is estimated to be about 4% of the gross cropped area which remained static for the last four decades.The traditional grazing lands are gradually diminishing because of urbanization, expansion of cultivable area, grazing pressure and industrialization etc. These factors resulted in severe shortage of feed and fodder to the extent of 26% in dry-crop residues, 35.6% in green fodder and 41% of concentrates (Anon, 2013). To reduce the demand and supply gap, the production and productivity of fodder crops needs to be enhanced. The utilization of non-cultivable space viz., field bunds, common grazing lands, backyards apart from regular cultivation of high biomass species like Bajra-Napier hybrid (BN hybrid), guinea grass, Trispecific hybrid helps in enhanced production of green fodder. Bajra-Napier hybrid is one of the high biomass grasses with fodder potential of 300 tons/ha/year. However, this grass can be propagated only through rooted slips as it does not form any viable seed. Several varieties suitable to different agro-climatic zones were released for the successful cultivation of this grass throughout India. Due to increasing demand both from small and marginal farmers as well as well-structured large scale diary industry, there is severe shortage of rooted slips of this grass. The traditional uprooting of tussocks not only destructs the mother tussock but also highly labour intensive and difficult to transport to long distances. Keeping in view of all these constraints, two novel technologies were developed for the large scale multiplication of BN hybrid rooted slips

Hydrodynamics of superfluids confined in blocked rings and wedges

Motivated by many recent experimental studies of non-classical rotational inertia (NCRI) in superfluid and supersolid samples, we present a study of the hydrodynamics of a superfluid confined in the two-dimensional region (equivalent to a long cylinder) between two concentric arcs of radii $b$ and $a$ ($b<a$) subtending an angle $\beta$, with $0 \le \beta \le 2\pi$. The case $\beta= 2 \pi$ corresponds to a blocked ring. We discuss the methodology to compute the NCRI effects, and calculate these effects both for small angular velocities, when no vortices are present, and in the presence of a vortex. We find that, for a blocked ring, the NCRI effect is small, and that therefore there will be a large discontinuity in the moment of inertia associated with blocking or unblocking circular paths. For blocked wedges ($b=0$) with $\beta > \pi$, we find an unexpected divergence of the velocity at the origin, which implies the presence of either a region of normal fluid or a vortex for {\it any} nonzero value of the angular velocity. Implications of our results for experiments on "supersolid" behavior in solid $^4{\rm He}$ are discussed. A number of mathematical issues are pointed out and resolved.Comment: 15 pages, including figures. To appear in Phys. Rev.

Biometric Personal Identification based on Iris Patterns

This paper discusses an analysis of human iris patterns for recognition of biometric system which consists of a segmentation system that is based on the Hough transform, and is able to localize the circular iris and pupil region, occluding eyelids and eyelashes, and reflections. The extracted iris region is then normalized into a rectangular block with constant dimensions to account for imaging inconsistencies. To encode the unique pattern of the iris into a bit-wise biometric template, 1D Log-Gabor filter is used.Finally to match two iris templates hamming distance is used as matching metric. The system performance is analyzed on 312 iris images taken from standard CASIA Iris Interval database version 4. To establish the verification accuracy of iris representation and matching approach, each iris image in the database is matched with all the other iris images in the database and genuine and imposter distribution is found .The performance of the system is implemented by evaluating the Decidability Index (DI), False match rate (FMR), False Non-match rate (FNMR), Genuine Accept Rate (GAR) and Equal error rate (EER)

Role of Vertex Index in Substructure Identification and Activity Prediction: A Study on Antitubercular Activity of a Series of Acid Alkyl Ester Derivatives

Tuberculosis (TB) is a life threatening disease caused due to infection from Mycobacterium tu¬berculosis (Mtb). That most of the TB strains have become resistant to various existing drugs, develop¬ment of effective novel drug candidates to combat this disease is a need of the day. In spite of intensive research world-wide, the success rate of discovering a new anti-TB drug is very poor. Therefore, novel drug discovery methods have to be tried. We have used a rule based computational method that utilizes a vertex index, named ‘distance exponent index (Dx)’ (taken x = –4 here) for predicting anti-TB activity of a series of acid alkyl ester derivatives. The method is meant to identify activity related substructures from a series a compounds and predict activity of a compound on that basis. The high degree of successful pre¬diction in the present study suggests that the said method may be useful in discovering effective anti-TB compound. It is also apparent that substructural approaches may be leveraged for wide purposes in com¬puter-aided drug design. (doi: 10.5562/cca2306