39,801 research outputs found
Modeling of secondary organic aerosol yields from laboratory chamber data
Laboratory chamber data serve as the basis for constraining models of secondary organic aerosol (SOA) formation. Current models fall into three categories: empirical two-product (Odum), product-specific, and volatility basis set. The product-specific and volatility basis set models are applied here to represent laboratory data on the ozonolysis of α-pinene under dry, dark, and low-NOx conditions in the presence of ammonium sulfate seed aerosol. Using five major identified products, the model is fit to the chamber data. From the optimal fitting, SOA oxygen-to-carbon (O/C) and hydrogen-to-carbon (H/C) ratios are modeled. The discrepancy between measured H/C ratios and those based on the oxidation products used in the model fitting suggests the potential importance of particle-phase reactions. Data fitting is also carried out using the volatility basis set, wherein oxidation products are parsed into volatility bins. The product-specific model is most likely hindered by lack of explicit inclusion of particle-phase accretion compounds. While prospects for identification of the majority of SOA products for major volatile organic compounds (VOCs) classes remain promising, for the near future empirical product or volatility basis set models remain the approaches of choice
Axiomatic Holonomy Maps and Generalized Yang-Mills Moduli Space
This article is a follow-up of ``Holonomy and Path Structures in General
Relativity and Yang-Mills Theory" by Barrett, J. W. (Int.J.Theor.Phys., vol.30,
No.9, 1991). Its main goal is to provide an alternative proof of this part of
the reconstruction theorem which concerns the existence of a connection. A
construction of connection 1-form is presented. The formula expressing the
local coefficients of connection in terms of the holonomy map is obtained as an
immediate consequence of that construction. Thus the derived formula coincides
with that used in "On Loop Space Formulation of Gauge Theories" by Chan, H.-M.,
Scharbach, P. and Tsou S.T. (Ann.Phys., vol.167, 454-472, 1986). The
reconstruction and representation theorems form a generalization of the fact
that the pointed configuration space of the classical Yang-Mills theory is
equivalent to the set of all holonomy maps. The point of this generalization is
that there is a one-to-one correspondence not only between the holonomy maps
and the orbits in the space of connections, but also between all maps from the
loop space on to group fulfilling some axioms and all possible
equivalence classes of bundles with connection, where the equivalence
relation is defined by bundle isomorphism in a natural way.Comment: amslatex, 7 pages, no figure
Observation of the single-electron regime in a highly tunable silicon quantum dot
We report on low-temperature electronic transport measurements of a silicon
metal-oxide-semiconductor quantum dot, with independent gate control of
electron densities in the leads and the quantum dot island. This architecture
allows the dot energy levels to be probed without affecting the electron
density in the leads, and vice versa. Appropriate gate biasing enables the dot
occupancy to be reduced to the single-electron level, as evidenced by
magnetospectroscopy measurements of the ground state of the first two charge
transitions. Independent gate control of the electron reservoirs also enables
discrimination between excited states of the dot and density of states
modulations in the leads.Comment: 4 pages, 3 figures, accepted for Applied Physics Letter
Supercritical multicomponent solvent coal extraction
The yield of organic extract from the supercritical extraction of coal with larger diameter organic solvents such as toluene is increased by use of a minor amount of from 0.1 to 10% by weight of a second solvent such as methanol having a molecular diameter significantly smaller than the average pore diameter of the coal
Optimum structures
The design of the best structure for a given purpose
depends upon the criterion used for optimisation. Structures
may be designed to safely transmit a given system of forces using
the least weight of material.. They may also be designed to have
maximum stiffness of a certain type for a given weight or
alternatively to have the greatest possible fundamental
frequency of vibration. These problems, although in general
distinct from one another, are closely related and much can be
achieved towards maximisation of stiffness and frequency by the
use of minimum weight designs. In fact it can be shown that a
minimum weight framework is the stiffest structure of that weight
for the force system, which it is designed to carry.x
The present report is concerned exclusively with the problem of
the design of structures of minimum weight, which are required
to transmit specified forces. Some attention will be given to
frameworks because, in particular, methods of approximate
numerical analysis are more readily formulated for this type of
structure, but the main emphasis will be placed upon the design
of structures formed from plates of variable thickness reinforced
by direct load carrying members.
See para,l.
Secondary organic aerosol formation from m-xylene, toluene, and benzene
Secondary organic aerosol (SOA) formation from the photooxidation of m-xylene, toluene, and benzene is investigated in the Caltech environmental chambers. Experiments are performed under two limiting NOx conditions; under high-NOx conditions the peroxy radicals (RO2) react only with NO, while under low-NOx conditions they react only with HO2. For all three aromatics studied (m-xylene, toluene, and benzene), the SOA yields (defined as the ratio of the mass of organic aerosol formed to the mass of parent hydrocarbon reacted) under low-NOx conditions substantially exceed those under high-NOx conditions, suggesting the importance of peroxy radical chemistry in SOA formation. Under low-NOx conditions, the SOA yields for m-xylene, toluene, and benzene are constant (36%, 30%, and 37%, respectively), indicating that the SOA formed is effectively nonvolatile under the range of Mo(>10 μg m−3) studied. Under high-NOx conditions, aerosol growth occurs essentially immediately, even when NO concentration is high. The SOA yield curves exhibit behavior similar to that observed by Odum et al. (1996, 1997a, b), although the values are somewhat higher than in the earlier study. The yields measured under high-NOx conditions are higher than previous measurements, suggesting a "rate effect" in SOA formation, in which SOA yields are higher when the oxidation rate is faster. Experiments carried out in the presence of acidic seed aerosol reveal no change of SOA yields from the aromatics as compared with those using neutral seed aerosol
Black string and velocity frame dragging
We investigate velocity frame dragging with the boosted Schwarzschild black
string solution and the boosted Kaluza-Klein bubble solution, in which a
translational symmetry along the boosted -coordinate is implemented. The
velocity frame dragging effect can be nullified by the motion of an observer
using the boost symmetry along the coordinate if it is not compact.
However, in spacetime with the compact coordinate, we show that the effect
cannot be removed since the compactification breaks the global Lorentz boost
symmetry. As a result, the comoving velocity is dependent on and the
momentum parameter along the coordinate becomes an observer independent
characteristic quantity of the black string and bubble solutions. The dragging
induces a spherical ergo-region around the black string.Comment: 8 pages, no figure, some correction
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