Densification and preservation of ceramic nanocrystalline character by spark plasma sintering

Spark plasma sintering is a hot pressing technique where rapid heating by dc electric pulses is used simultaneously with applied pressure. Thus, spark plasma sintering is highly suitable for rapid densification of ceramic nanoparticles and preservation of the final nanostructure. A considerable portion of the shrinkage during densification of the green compact of nanoparticles in the first and intermediate stages of sintering occurs during heating by particle rearrangement by sliding and rotation. Further densification to the final stage of sintering takes place by either plastic yield or diffusional processes. Full densification in the final stage of sintering is associated with diffusional processes only. Nanoparticle sliding and rotation during heating may also lead to grain coalescence, with much faster kinetics than normal grain growth at higher temperatures. Based on existing models for particle rearrangement and sliding, the contributions of these processes in conjunction with nanoparticle properties and process parameters were highlighted

Drivers of the Recent Tropical Expansion in the Southern Hemisphere: Changing SSTs or Ozone Depletion?

Observational evidence indicates that the southern edge of the Hadley cell (HC) has shifted southward during austral summer in recent decades. However, there is no consensus on the cause of this shift, with several studies reaching opposite conclusions as to the relative role of changes in sea surface temperatures (SSTs) and stratospheric ozone depletion in causing this shift. Here, the authors perform a meta-analysis of the extant literature on this subject and quantitatively compare the results of all published studies that have used single-forcing model integrations to isolate the role of different factors on the HC expansion during austral summer. It is shown that the weight of the evidence clearly points to stratospheric ozone depletion as the dominant driver of the tropical summertime expansion over the period in which an ozone hole was formed (1979 to late 1990s), although SST trends have contributed to trends since then. Studies that have claimed SSTs as the major driver of tropical expansion since 1979 have used prescribed ozone fields that underrepresent the observed Antarctic ozone depletion

Psychologiczna analiza religijno\u15bci niesp\uf3jnej

Klasyfikacja tematyczna: Psychologia osobowo\u15bci; Psychologia religii; Antropologia spo\u142eczna; Socjologia religii; Filozofia religii; Filozofia warto\u15bc

Does the Holton–Tan Mechanism Explain How the Quasi-Biennial Oscillation Modulates the Arctic Polar Vortex?

Idealized experiments with the Whole Atmosphere Community Climate Model (WACCM) are used to explore the mechanism(s) whereby the stratospheric quasi-biennial oscillation (QBO) modulates the Northern Hemisphere wintertime stratospheric polar vortex. Overall, the effect of the critical line emphasized in the Holton–Tan mechanism is less important than the effect of the mean meridional circulation associated with QBO winds for the polar response to the QBO. More specifically, the introduction of easterly winds at the equator near 50 hPa 1) causes enhanced synoptic-scale Eliassen–Palm flux (EPF) convergence in the subtropics from 150 to 50 hPa, which leads to the subtropical critical line moving poleward in the lower stratosphere, and 2) creates a barrier to planetary wave propagation from subpolar latitudes to midlatitudes in the middle and upper stratosphere (e.g., less equatorward EPF near 50°N), which leads to enhanced planetary wave convergence in the polar vortex region. These two effects are mechanistically distinct; while the former is related to the subtropical critical line, the latter is due to the mean meridional circulation of the QBO. All of these effects are consistent with linear theory, although the evolution of the entire wind distribution is only quasi-linear because induced zonal wind changes cause the wave driving to shift and thereby positively feed back on the zonal wind changes. Finally, downward propagation of the QBO in the equatorial stratosphere, upper stratospheric equatorial zonal wind, and changes in the tropospheric circulation appear to be less important than lower stratospheric easterlies for the polar stratospheric response. Overall, an easterly QBO wind anomaly in the lower stratosphere leads to a weakened stratospheric polar vortex, in agreement with previous studies, although not because of changes in the subtropical critical line

Contrasting Effects of Central Pacific and Eastern Pacific El Nino on Stratospheric Water Vapor

Targeted experiments with a comprehensive chemistry-climate model are used to demonstrate that seasonality and the location of the peak warming of sea surface temperatures dictate the response of stratospheric water vapor to El Nino. In spring, El Nino events in which sea surface temperature anomalies peak in the eastern Pacific lead to a warming at the tropopause above the warm pool region, and subsequently to more stratospheric water vapor (consistent with previous work). However, in fall and in early winter, and also during El Nino events in which the sea surface temperature anomaly is found mainly in the central Pacific, the response is qualitatively different: temperature changes in the warm pool region are nonuniform and less water vapor enters the stratosphere. The difference in water vapor in the lower stratosphere between the two variants of El Nino approaches 0.3 ppmv, while the difference between the winter and spring responses exceeds 0.5 ppmv

Connections Between the TTL and Sea Surface Temperatures: Interannual Variability and Trends

Comprehensive chemistry climate models and satellite data are used to investigate the forcing of variability in the tropical lower stratosphere and upper troposphere. As this region is the origination region for air parcels which enter the stratosphere, it is important to understand variability in this region on timescales ranging from the seasonal to decadal. The warming trend in the tropical upper troposphere over the past 30 years is strongest near the Indo Pacific warm pool, while the warming trend in the western and central Pacific is much weaker. In the lower stratosphere, these trends are reversed: the historical cooling trend is strongest over the Indo Pacific warm pool and is weakest in the western and central Pacific. These zonal variations are stronger than the zonal mean response in boreal winter. Targeted experiments with a chemistry climate model are used to demonstrate that sea surface temperature trends are driving the zonal asymmetry in upper tropospheric and lower stratospheric tropical temperature trends. The anomalous circulation set up by the changing SSTs has led to zonal structure in the ozone and water vapor trends near the tropopause, and subsequently to less water vapor entering the stratosphere. Projected future sea surface temperatures appear to drive a temperature and water vapor response whose zonal structure is similar to the historical response. In the lower stratosphere, the changes in water vapor and temperature due to projected future sea surface temperatures is of similar strength to, though slightly weaker than, that due directly to projected future CO2, ozone, and methane. Finally, targeted experiments with a chemistry climate model are used to demonstrate that seasonality and the location of the peak warming of sea surface temperatures dictate the response of stratospheric water vapor to El Nino. In spring, El Nino events in which sea surface temperature anomalies peak in the eastern Pacific lead to a warming at the tropopause above the warm pool region, and subsequently to more stratospheric water vapor (consistent with previous work). However, in fall and in early winter, and also during El Nino events in which the sea surface temperature anomaly is found mainly in the central Pacific, the response is qualitatively different: temperature changes in the warm pool region are nonuniform and less water vapor enters the stratosphere. The difference in water vapor in the lower stratosphere between the two variants of El Nino approaches 0.3 ppmv, while the difference between the winter and spring responses exceeds 0.5 ppmv

Panoramic optical and near-infrared SETI instrument: prototype design and testing

The Pulsed All-sky Near-infrared Optical Search for ExtraTerrestrial Intelligence (PANOSETI) is an instrument program that aims to search for fast transient signals (nano-second to seconds) of artificial or astrophysical origin. The PANOSETI instrument objective is to sample the entire observable sky during all observable time at optical and near-infrared wavelengths over 300 - 1650 nm$^1$. The PANOSETI instrument is designed with a number of modular telescope units using Fresnel lenses ($\sim$0.5m) arranged on two geodesic domes in order to maximize sky coverage$^2$. We present the prototype design and tests of these modular Fresnel telescope units. This consists of the design of mechanical components such as the lens mounting and module frame. One of the most important goals of the modules is to maintain the characteristics of the Fresnel lens under a variety of operating conditions. We discuss how we account for a range of operating temperatures, humidity, and module orientations in our design in order to minimize undesirable changes to our focal length or angular resolution.Comment: 12 pages, 8 figures, 1 tabl