12 research outputs found
Recent advances on porphyrin complexes of transition metals as catalysts in amination reactions
No full textSynthesis of Ar-BIAN Ligands (Ar-BIAN = Bis(aryl)acenaphthenequinonediimine) Having Strong Electron-Withdrawing Substituents on the Aryl Rings and Their Relative Coordination Strength toward Palladium(0) and -(II) Complexes
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The Key Intermediate in the Aminations of Saturated C-H Bonds: Synthesis, X-ray Characterization and Catalytic Activity of Ru(TPP)(NAr)2 (Ar = 3,5-(CF3)2C6H5)
No full textThe complex Ru(TPP)(NAr)2inserts a nitrene group into allylic and benzylic C-H bonds and is the key intermediate in the ruthenium porphyrin-catalyzed amination of hydrocarbons by aryl azides. © 2009 The Royal Society of Chemistry
Origin of the deactivation in styrene aziridination by aryl azides, catalyzed by ruthenium porphyrin complexes. Structural characterization of a Δ2-1,2,3-triazoline RuII(TPP)CO complex
No full textThe reaction of Ru(TPP)CO (TPP = dianion of tetraphenylporphyrin) with 1-(p-nitrophenyl)-5-methyl-5-phenyl-1,2,3-triazoline yielded a Δ2-1,2,3-triazoline ruthenium(II) porphyrin complex, which is responsible for the catalyst deactivation in the aziridination reaction of α-methylstyrene by p-nitrophenyl azide. © 2005 American Chemical Society
Syntheses, Structures, and Reactivity of Polynuclear Pyrazolato Copper(I) Complexes, Including an ab-Initio XRPD Study of [Cu(dmnpz)] 3
No full textDesigning new ligands: Asymmetric cyclopropanation by Cu(I) complexes based on functionalised pyridine-containing macrocyclic ligands
No full textThe synthesis and characterisation of copper(i) complexes, including two crystal structures of the new chiral pyridine-containing macrocyclic ligands (PC-type), and their use as catalysts in asymmetric cyclopropanation reactions are reported. © 2008 The Royal Society of Chemistry
Reaction of dioxygen with poly[(3,5-dimethylpyrazolato)copper]. Crystal structure, reactivity, and catalytic properties of [Cu8(dmpz)8(OH)8]
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