Optical Chemosensor for the Detection of Cyanide in Water Based On Ethyl(hydroxyethyl)cellulose Functionalized with Brooker’s Merocyanine

Ethyl­(hydroxyethyl)­cellulose was functionalized with Brooker’s merocyanine. The modified polymer was easily transformed in a film, which could be used as a highly selective chromogenic and fluorogenic chemosensor for the detection of cyanide in water, with detection limits of 1.9 × 10^–5 and 1.0 × 10^–7 mol L^–1. The film was successfully applied to the detection of cyanide in cassava (<i>Manihot esculenta</i> Crantz) roots, which are a well-known source of endogenous biological cyanide

Synthesis and Solvatochromism of Substituted 4‑(Nitrostyryl)phenolate Dyes

4-(Nitrostyryl)­phenols <b>2a</b>–<b>9a</b> were synthesized, and by deprotonation in solution, the solvatochromic phenolates <b>2b</b>–<b>9b</b> were formed. Their absorption bands in the vis region of the spectra are due to π–π* electronic transitions, of an intramolecular charge-transfer nature, from the electron-donor phenolate toward the electron-acceptor nitroarene moiety. The frontier molecular orbitals and natural bond orbitals were analyzed for the protonated and deprotonated forms. The calculated geometries are in agreement with X-ray structures observed for <b>4a</b>, <b>6a</b>, and <b>8a</b>. The HOMO–LUMO energy gaps suggest that, after their deprotonation, an increase in the electron delocalization is observed. In the protonated compounds, the HOMO is primarily localized over the phenol ring and the CC bridge. After deprotonation, it extends toward the entire molecule, including the NO₂ groups. The solvatochromism of each dye was studied in 28 organic solvents, and it was found that all compounds exhibit a reversal in solvatochromism, which is interpreted in terms of the ability of the media to stabilize their electronic ground and excited states to different extents. The Catalán multiparameter equation is used in the interpretation of the solvatochromic data, revealing that the most important contribution to the solute/solvent interaction is the hydrogen-bond donor acidity of the solvent