“On the fly” characterization of YbIII:ErIII co-doped upconversion nanoparticle nonlinear optical response from single-particle trajectories

Spectroscopic characterization of individual nanoparticles is essential for understanding their structure-property relationship and for applications. Upconversion nanoparticles (UCNPs) in condensed phases can undergo both nonlinear optical and stochastic dynamics when interacting with near-infrared sources. By integrating optical trapping microspectroscopy, stochastic dynamics and light-matter interactions experiments and simulations, in the present work we study how individual trajectories of YbIII:ErIII co-doped UCNPs can be used to perform “on the fly” characterization of their nonlinear optical power-law response upon near-infrared excitation. We illustrate the methodology in the case of freely diffusing and optically trapped UCNPs as well as with particles bound to the substrate. The approach presented in this work can be applied to UCNPs with varying composition and morphological features, particularly in single-particle studies.Fil: Cavalcante, Isabela N.. Universidade Estadual de Campinas; BrasilFil: Marchi, María Claudia. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Ciudad Universitaria. Instituto de Física de Buenos Aires. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Instituto de Física de Buenos Aires; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Ciudad Universitaria. Instituto de Química, Física de los Materiales, Medioambiente y Energía. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Instituto de Química, Física de los Materiales, Medioambiente y Energía; Argentina. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Centro de Microscopías Avanzadas; ArgentinaFil: Sigoli, Fernando A.. Universidade Estadual de Campinas; BrasilFil: de Sousa Filho, Paulo C.. Universidade Estadual de Campinas; BrasilFil: Barja, Beatriz Carmen. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Ciudad Universitaria. Instituto de Química, Física de los Materiales, Medioambiente y Energía. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Instituto de Química, Física de los Materiales, Medioambiente y Energía; ArgentinaFil: Nome, René A.. Universidade Estadual de Campinas; Brasi

Crossing Symmetry Violation of Unitarized Pion-Pion Amplitude in the Resonance Region

Pion-pion scattering amplitude obtained from one-loop Chiral Perturbation Theory (ChPT) is crossing symmetric, however the corresponding partial wave amplitudes do not respect exact unitarity relation. There are different approaches to get unitarized partial wave amplitudes from ChPT. Here we consider the inverse amplitude method (IAM) that is often used to fit pion-pion phase shifts to experimental data, by adjusting free parameters. We measure the amount of crossing symmetry violation (CSV) in this case and we show that crossing symmetry is badly violated by the IAM unitarized ChPT amplitude in the resonance region. Important CSV also occurs when all free parameters are set equal to zero.Comment: 6 pages, 4 figure

Nucleon-nucleon interaction in the Skyrme model

We consider the interaction of two skyrmions in the framework of the sudden approximation. The widely used product ansatz is investigated. Its failure in reproducing an attractive central potential is associated with terms that violate G-parity. We discuss the construction of alternative ans\"atze and identify a plausible solution to the problem.Comment: 18 pages, 9 figure