Prince Rupert’s Drops: An analysis of fragmentation by thermal stresses and quench granulation of glass and bubbly glass

When volcanic eruptions involve interaction with external water (hydrovolcanism), the result is an ash-rich and energetic volcanic plume, as illustrated dramatically by the January 2022 Tonga eruption. The origin of the high explosive energy of these events remains an important question. We investigate this question by studying Prince Rupert's Drops (PRDs)-tadpole-shaped glass beads formed by dripping molten glass into water-which have long fascinated materials scientists because the great strength of the head contrasts with the explosivity of the metastable interior when the tail is broken. We show that the fragment size distribution (FSD) produced by explosive fragmentation changes systematically with PRD fragmentation in air, water, and syrup. Most FSDs are fractal over much of the size range, scaling that can be explained by the repeated fracture bifurcation observed in three-dimensional images from microcomputed tomography. The shapes of constituent fragments are determined by their position within the original PRD, with platey fragments formed from the outer (compressive) shell and blocky fragments formed by fractures perpendicular to interior voids. When molten drops fail to form PRDs, the glass disintegrates by quench granulation, a process that produces fractal FSDs but with a larger median size than explosively generated fragments. Critically, adding bubbles to the molten glass prevents PRD formation and promotes quench granulation, suggesting that granulation is modulated by heterogeneous stress fields formed around the bubbles during sudden cooling and contraction. Together, these observations provide insight into glass fragmentation and potentially, processes operating during hydrovolcanism

Architecture and dynamics of magma reservoirs.

This introductory article provides a synopsis of our current understanding of the form and dynamics of magma reservoirs in the crust. This knowledge is based on a range of experimental, observational and theoretical approaches, some of which are multidisclipinary and pioneering. We introduce and provide a contextual background for the papers in this issue, which cover a wide range of topics, encompassing magma storage, transport, behaviour and rheology, as well as the timescales on which magma reservoirs operate. We summarize the key findings that emerged from the meeting and the challenges that remain. The study of magma reservoirs has wide implications not only for understanding geothermal and magmatic systems, but also for natural oil and gas reservoirs and for ore deposit formation. This article is part of the Theo Murphy meeting issue 'Magma reservoir architecture and dynamics'

Mafic glass compositions: a record of magma storage conditions, mixing and ascent

The trans-crustal magma system paradigm is forcing us to re-think processes responsible for magma evolution and eruption. A key concept in petrology is the liquid line of descent (LLD), which relates a series of liquids derived from a single parent, and therefore tracks the inverse of the crystallization path. It is common practice to attribute multiple magma compositions, and/or multiple melt compositions (from melt inclusions and matrix glass), to a single LLD. However, growing evidence for rapid, and often syn-eruptive, assembly of multiple magma components (crystals and melts) from different parts of a magmatic system suggests that erupted magma and melt compositions will not necessarily represent a single LLD, but instead may reflect the multiple paths in pressure–temperature space. Here, we use examples from mafic magmatic systems in both ocean island and arc settings to illustrate the range of melt compositions present in erupted samples, and to explore how they are generated, and how they interact. We highlight processes that may be deduced from mafic melt compositions, including the mixing of heterogeneous primitive liquids from the mantle, pre-eruptive magma storage at a range of crustal and sub-Moho depths, and syn-eruptive mixing of melts generated from these storage regions. The relative dominance of these signatures in the glasses depends largely on the water content of the melts. We conclude that preserved melt compositions provide information that is complementary to that recorded by the volatile contents of crystal-hosted melt inclusions and coexisting mineral compositions, which together can be used to address questions about both the pre- and syn-eruptive state of volcanic systems