422 research outputs found
Novel Scintillating Materials Based on Phenyl-Polysiloxane for Neutron Detection and Monitoring
Neutron detectors are extensively used at many nuclear research facilities
across Europe. Their application range covers many topics in basic and applied
nuclear research: in nuclear structure and reaction dynamics (reaction
reconstruction and decay studies); in nuclear astrophysics (neutron emission
probabilities); in nuclear technology (nuclear data measurements and
in-core/off-core monitors); in nuclear medicine (radiation monitors,
dosimeters); in materials science (neutron imaging techniques); in homeland
security applications (fissile materials investigation and cargo inspection).
Liquid scintillators, widely used at present, have however some drawbacks given
by toxicity, flammability, volatility and sensitivity to oxygen that limit
their duration and quality. Even plastic scintillators are not satisfactory
because they have low radiation hardness and low thermal stability. Moreover
organic solvents may affect their optical properties due to crazing. In order
to overcome these problems, phenyl-polysiloxane based scintillators have been
recently developed at Legnaro National Laboratory. This new solution showed
very good chemical and thermal stability and high radiation hardness. The
results on the different samples performance will be presented, paying special
attention to a characterization comparison between synthesized phenyl
containing polysiloxane resins where a Pt catalyst has been used and a
scintillating material obtained by condensation reaction, where tin based
compounds are used as catalysts. Different structural arrangements as a result
of different substituents on the main chain have been investigated by High
Resolution X-Ray Diffraction, while the effect of improved optical
transmittance on the scintillation yield has been elucidated by a combination
of excitation/fluorescence measurements and scintillation yield under exposure
to alpha and {\gamma}-rays.Comment: InterM 2013 - International Multidisciplinary Microscopy Congres
Removal of ammonium from wastewater with geopolymer sorbents fabricated via additive manufacturing
Geopolymers have been recently explored as sorbents for wastewater treatment, thanks to their mechanical and chemical stability and to their low-energy manufacturing process. One specific application could be the removal of ammonium (NH4+) through exchange with Na+ ions. Additive manufacturing (AM) represents an especially interesting option for fabrication, as it allows to tailor the size, distribution, shape, and interconnectivity of pores, and therefore the access to charge-bearing sites. The present study provides a proof of concept for NH4+ removal from wastewater using porous geopolymer components fabricated via direct ink writing (DIW) AM approach. A metakaolin-based ink was employed for the fabrication of a log-pile structure with 45\ub0 rotation between layers, producing continuous yet tortuous macropores which are responsible for the high permeability of the sorbents. The ink consolidates in an amorphous, mesoporous network, with the mesopores acting as preferential sites for ion exchange. The printed sorbents were characterized for their physicochemical and mechanical properties and the NH4+ removal capacity in continuous-flow column experiments by using a model effluent. The lattices present high permeability and high cation exchange capacity and maintained a high amount of active ions after four cycles, allowing to reuse them multiple times
ZnS (Mn) Nanoparticles as Luminescent Centers for Siloxane Based Scintillators
Synthesis of oleic acid stabilized ZnS nanocrystals activated with Mn is pursued. A hydrothermal method where high pressure and temperature are applied to control the nanocrystals growth is adopted. Capping the nanoparticle surface with oleic acid (OA) improved light output. Samples loaded with both the phosphor and the neutron sensitizer have been produced and tested in a preliminary test as alpha particle detectors and secondly as thermal neutron detectors. The results support further development for siloxane-based scintillator detectors employing ZnS (Mn) nanoparticles
Constraints on coupling constant between dark energy and dark matter
We have investigated constraints on the coupling between dark matter and the
interacting Chaplygin gas. Our results indicate that the coupling constant
between these two entities can take arbitrary values, which can be either
positive or negative, thus giving arbitrary freedom to the inter-conversion
between Chaplygin gas and dark matter. Thus our results indicate that the
restriction on the coupling constant occurs as a very special case. Our
analysis also supports the existence of phantom energy under certain conditions
on the coupling constant.Comment: 16 Pages, 3 figure
Novel correlations between spectroscopic and morphological properties of activated carbons from waste coffee grounds
Massive quantities of spent coffee grounds (SCGs) are generated by users around the world. Different processes have been proposed for SCG valorization, including pyrolytic processes to achieve carbonaceous materials. Here, we report the preparation of activated carbons through pyrolytic processes carried out under different experimental conditions and in the presence of various porosity activators. Textural and chemical characterization of the obtained carbons have been achieved through Brunauer–Emmett–Teller (BET), ESEM,13C solid state NMR, XPS, XRD, thermogravimetric and spectroscopic determinations. The aim of the paper is to relate these data to the preparation method, evaluating the correlation between the spectroscopic data and the physical and textural properties, also in comparison with the corresponding data obtained for three commercial activated carbons used in industrial adsorption processes. Some correlations have been observed between the Raman and XPS data
Role of Modified Chaplygin Gas as a Dark Energy Model in Collapsing Spherically Symmetric Cloud
In this work, gravitational collapse of a spherical cloud, consists of both
dark matter and dark energy in the form of modified Chaplygin gas is studied.
It is found that dark energy alone in the form of modified Chaplygin gas forms
black hole. Also when both components of the fluid are present then the
collapse favors the formation of black hole in cases the dark energy dominates
over dark matter. The conclusion is totally opposite to the usually known
results.Comment: 7 Latex Pages, RexTex style, No figure
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