Dynamic Radio-Frequency Transverse Susceptibility in Magnetic Nanoparticle Systems

A novel resonant method based on a tunnel-diode oscillator (TDO) is used to study the dynamic transverse susceptibility in a Fe nanoparticle system. The magnetic system consists of an aggregate of nanometer-size core (Au)-shell (Fe) structure, synthesized by reverse micelle methods. Static and dynamic magnetization measurements carried out in order to characterize the system reveal a superparamagnetic behavior at high temperature. The field-dependent transverse susceptibility at radio-frequencies (RF), for different temperatures reveals distinct peak structure at characteristics fields (H_k, H_c) which changes with temperature. It is proposed that relaxation processes could explain the influence of the temperature on the field dependence of the transverse susceptibility on the MI.Comment: 3 pages, 2-column, 3 figures, To be published in J. Appl. Phys. 2000 (44th Annual MMM proceedings

Simple bonding technique for high-temperature ceramic coatings

Coatings, consisting of zirconia powder bonded with orthophosphoric acid and a small amount of hydrofluoric acid, are hard, strong, and refractory, resist thermal shock, and provide good thermal protection. After the aqueous coating is applied to a metallic surface, only a 600 deg F cure is required before service

A fluorometric method for determining chlorophylls a, b, and c

A method for the determination of chlorophylls a, b, and c by fluorometric techniques is presented. The effects of accessory carotenoids and chlorophyll derivatives on the accuracy of this method are analyzed…

Concentration and state of cerium in coastal waters

The cerium contents of several coastal water samples were found to be 0.1 to 0.6 µg/l. These are in contrast to the cerium concentrations of 0.004 and 0.014 µg/l observed in samples taken near Bermuda…

Comparison and evaluation of currently employed modifications of the Winkler method for determining dissolved oxygen in seawater; A NASCO report

This report discusses the basic chemistry of the Winkler procedure as well as various results obtained from fi eld and laborator y studies and experiments designed to determine the accuracy or precision of measuring the concentration of dissolved oxygen in seawater with currently used modifications of the Winkler method...

Recognition of 3-D Objects from Multiple 2-D Views by a Self-Organizing Neural Architecture

The recognition of 3-D objects from sequences of their 2-D views is modeled by a neural architecture, called VIEWNET that uses View Information Encoded With NETworks. VIEWNET illustrates how several types of noise and varialbility in image data can be progressively removed while incornplcte image features are restored and invariant features are discovered using an appropriately designed cascade of processing stages. VIEWNET first processes 2-D views of 3-D objects using the CORT-X 2 filter, which discounts the illuminant, regularizes and completes figural boundaries, and removes noise from the images. Boundary regularization and cornpletion are achieved by the same mechanisms that suppress image noise. A log-polar transform is taken with respect to the centroid of the resulting figure and then re-centered to achieve 2-D scale and rotation invariance. The invariant images are coarse coded to further reduce noise, reduce foreshortening effects, and increase generalization. These compressed codes are input into a supervised learning system based on the fuzzy ARTMAP algorithm. Recognition categories of 2-D views are learned before evidence from sequences of 2-D view categories is accumulated to improve object recognition. Recognition is studied with noisy and clean images using slow and fast learning. VIEWNET is demonstrated on an MIT Lincoln Laboratory database of 2-D views of jet aircraft with and without additive noise. A recognition rate of 90% is achieved with one 2-D view category and of 98.5% correct with three 2-D view categories.National Science Foundation (IRI 90-24877); Office of Naval Research (N00014-91-J-1309, N00014-91-J-4100, N00014-92-J-0499); Air Force Office of Scientific Research (F9620-92-J-0499, 90-0083

Spin transition in Gd3_3N@C80_{80}, detected by low-temperature on-chip SQUID technique

We present a magnetic study of the Gd$_3$N@C$_{80}$ molecule, consisting of a Gd-trimer via a Nitrogen atom, encapsulated in a C$_{80}$ cage. This molecular system can be an efficient contrast agent for Magnetic Resonance Imaging (MRI) applications. We used a low-temperature technique able to detect small magnetic signals by placing the sample in the vicinity of an on-chip SQUID. The technique implemented at NHMFL has the particularity to operate in high magnetic fields of up to 7 T. The Gd$_3$N@C$_{80}$ shows a paramagnetic behavior and we find a spin transition of the Gd$_3$N structure at 1.2 K. We perform quantum mechanical simulations, which indicate that one of the Gd ions changes from a $^8S_{7/2}$ state ($L=0, S=7/2$) to a $^7F_{6}$ state ($L=S=3, J=6$), likely due to a charge transfer between the C$_{80}$ cage and the ion

THE STRUCTURE OF EMPLOYMENT AND UNEMPLOYMENT IN A DECLINING RURAL COMMUNITY

Labor and Human Capital,

Characterization of oxidation resistant Fe@M (M=Cr, Ni) core@shell nanoparticles prepared by a modified reverse micelle reaction

Iron-based nanoparticles are the forerunners in the field of nanotechnology due to their high magnetizationsaturation and biocompability which affords them use in a variety of applications. However, iron-based nanoparticles, due to a high surface-to-volume ratio, suffer from oxidation and limit its practicality by lowering the magnetic moment significantly. To avoid this oxidation, the surfaces of the particles have to be passivated. One such way to accomplish this passivation is to synthesize core@shell nanoparticles that have a surface treatment of chromium or nickel. These core@shell nanoparticles have been synthesized using a reverse micelle technique. The Cr and Ni passivated ironnanoparticles were characterized by x-ray diffraction, transmission electron microscopy, vibrating sample magnetometry, and x-ray photoelectron spectroscopy to determine their phase, morphology, surface properties, and magnetizationsaturation. A high magnetizationsaturation of 160 and 165 emu/g for Cr and Ni passivated iron core@shell nanoparticles was achieved