Effect of Different Urine Cow Nitrogen Rates and Different Moisture Conditions on Nitrogen Mineralization in an Andisol from Southern Chile

Urea present in cattle urine contributes large amounts of nitrogen (N) to grazed pastures, which can be an equivalent to approximately 1000 kg N ha−1. However, there are no studies in volcanic soils of southern Chile on the effect of different concentrations of urinary N deposited in the soil, nor of different wetting and drying conditions mimicking the variation of weather conditions on the nitrification process, from urea to NH4+ and total oxidized nitrogen (TON), throughout time. In addition, the inhibition on nitrification driven by the accumulation of NH3 at high rates of N applied to an Andisol have not been evaluated. Fresh cattle urine was applied at three different rates of N equivalent to 247 kg N ha−1 (Low N), 461 kg N ha−1 (Medium N), 921 kg N ha−1 (High N), and de-ionized water as Control. Further, three moisture conditions were imposed: constant moisture (CM), drying-rewetting (DRW) cycles at 7 days interval, and soil drying (SD). Destructive soil cores samples were evaluated for top and bottom halves individually every 7 days over a 36-d period to measure changes on inorganic N and pH. There were no interaction effects for N rates and soil moisture. The main effect of the different rates of N on mineralization was significant throughout the incubation period, while the effect of the different moisture conditions was var-iable over time. The High N was associated with elevated NH3 concentrations and could explain that total N mineralization was partially inhibited. These results suggest that the presence of different nitrifying microorganisms in the soil under different chemical and physical conditions determines nitrification, thus, the oxidation of ammonia should be studied in more detail as the first step of nitrification, specifically in volcanic soils

The challenge of modelling nitrogen management at the field scale : simulation and sensitivity analysis of N2O fluxes across nine experimental sites using DailyDayCent

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Metastable states in the Blume-Emery-Griffiths spin glass model

We study the Blume-Emery-Griffiths spin glass model in presence of an attractive coupling between real replicas, and evaluate the effective potential as a function of the density overlap. We find that there is a region, above the first order transition of the model, where metastable states with a large density overlap exist. The line where these metastable states appear should correspond to a purely dynamical transition, with a breaking of ergodicity. Differently from what happens in p-spin glasses, in this model the dynamical transition would not be the precursor of a 1-step RSB transition, but (probably) of a full RSB transition.Comment: RevTeX, 4 pages, 2 fig

PANIC: the new panoramic NIR camera for Calar Alto

PANIC is a wide-field NIR camera, which is currently under development for the Calar Alto observatory (CAHA) in Spain. It uses a mosaic of four Hawaii-2RG detectors and covers the spectral range from 0.8-2.5 micron(z to K-band). The field-of-view is 30x30 arcmin. This instrument can be used at the 2.2m telescope (0.45arcsec/pixel, 0.5x0.5 degree FOV) and at the 3.5m telescope (0.23arcsec/pixel, 0.25x0.25 degree FOV). The operating temperature is about 77K, achieved by liquid Nitrogen cooling. The cryogenic optics has three flat folding mirrors with diameters up to 282 mm and nine lenses with diameters between 130 mm and 255 mm. A compact filter unit can carry up to 19 filters distributed over four filter wheels. Narrow band (1%) filters can be used. The instrument has a diameter of 1.1 m and it is about 1 m long. The weight limit of 400 kg at the 2.2m telescope requires a light-weight cryostat design. The aluminium vacuum vessel and radiation shield have wall thicknesses of only 6 mm and 3 mm respectively.Comment: This paper has been presented in the SPIE of Astronomical Telescopes and Instrumentation 2008 in Marseille (France

Experimental Investigation of the Distribution of Shock Effects in Regolith Impact Ejecta Using an Ejecta Recovery Chamber

Because the mass-flux of solar system meteoroids is concentrated in the approx. 200 microns size range, small-scale impacts play a key role in driving the space weathering of regoliths on airless bodies. Quantifying this role requires improved data linking the mass, density and velocity of the incoming impactors to the nature of the shock effects produced, with particular emphasis on effects, such as production of impact melt and vapor, that drive the optical changes seen in space weathered regoliths. Of particular importance with regard to space weathering is understanding not only the composition of the shock melt created in small-scale impacts, but also how it is partitioned volumetrically between the local impact site and more widely distributed ejecta. To improve the ability of hypervelocity impact experiments to obtain this type of information, we have developed an enclosed sample target chamber with multiple-geometry interior capture cells for in-situ retention of ejecta from granular targets. A key design objective was to select and test capture cell materials that could meet three requirements: 1) Capture ejecta fragments traveling at various trajectories and velocities away from the impact point, while inducing minimal additional damage relative to the primary shock effects; 2) facilitate follow-up characterization of the ejecta either on or in the cell material by analytical SEM, or ex-situ by microprobe, TEM and other methods; and 3) enable the trajectories of the captured and characterized ejecta to be reconstructed relative to the target

Effect of cattle urine addition on the surface emissions and subsurface concentrations of greenhouse gases in a UK peat grassland

Grazing systems represent a substantial percentage of the global anthropogenic flux of nitrous oxide (N2O) as a result of nitrogen addition to the soil. The pool of available carbon that is added to the soil from livestock excreta also provides substrate for the production of carbon dioxide (CO2) and methane (CH4) by soil microorganisms. A study into the production and emission of CO2, CH4 and N2O from cattle urine amended pasture was carried out on the Somerset Levels and Moors, UK over a three-month period. Urine-amended plots (50 g N m−2) were compared to control plots to which only water (12 mg N m−2) was applied. CO2 emission peaked at 5200 mg CO2 m−2 d−1 directly after application. CH4 flux decreased to −2000 μg CH4 m−2 d−1 two days after application; however, net CH4 flux was positive from urine treated plots and negative from control plots. N2O emission peaked at 88 mg N2O m−2 d−1 12 days after application. Subsurface CH4 and N2O concentrations were higher in the urine treated plots than the controls. There was no effect of treatment on subsurface CO2 concentrations. Subsurface N2O peaked at 500 ppm 12 days after and 1200 ppm 56 days after application. Subsurface NO3− concentration peaked at approximately 300 mg N kg dry soil−1 12 days after application. Results indicate that denitrification is the key driver for N2O release in peatlands and that this production is strongly related to rainfall events and water-table movement. N2O production at depth continued long after emissions were detected at the surface. Further understanding of the interaction between subsurface gas concentrations, surface emissions and soil hydrological conditions is required to successfully predict greenhouse gas production and emission

Preliminary optical design of PANIC, a wide-field infrared camera for CAHA

In this paper, we present the preliminary optical design of PANIC (PAnoramic Near Infrared camera for Calar Alto), a wide-field infrared imager for the Calar Alto 2.2 m telescope. The camera optical design is a folded single optical train that images the sky onto the focal plane with a plate scale of 0.45 arcsec per 18 micron pixel. A mosaic of four Hawaii 2RG of 2k x 2k made by Teledyne is used as detector and will give a field of view of 31.9 arcmin x 31.9 arcmin. This cryogenic instrument has been optimized for the Y, J, H and K bands. Special care has been taken in the selection of the standard IR materials used for the optics in order to maximize the instrument throughput and to include the z band. The main challenges of this design are: to produce a well defined internal pupil which allows reducing the thermal background by a cryogenic pupil stop; the correction of off-axis aberrations due to the large field available; the correction of chromatic aberration because of the wide spectral coverage; and the capability of introduction of narrow band filters (~1%) in the system minimizing the degradation in the filter passband without a collimated stage in the camera. We show the optomechanical error budget and compensation strategy that allows our as built design to met the performances from an optical point of view. Finally, we demonstrate the flexibility of the design showing the performances of PANIC at the CAHA 3.5m telescope.Comment: This paper has been presented in the SPIE of Astronomical Telescopes and Instrumentation 2008 in Marseille (France

A Doubly Nudged Elastic Band Method for Finding Transition States

A modification of the nudged elastic band (NEB) method is presented that enables stable optimisations to be run using both the limited-memory quasi-Newton (L-BFGS) and slow-response quenched velocity Verlet (SQVV) minimisers. The performance of this new `doubly nudged' DNEB method is analysed in conjunction with both minimisers and compared with previous NEB formulations. We find that the fastest DNEB approach (DNEB/L-BFGS) can be quicker by up to two orders of magnitude. Applications to permutational rearrangements of the seven-atom Lennard-Jones cluster (LJ7) and highly cooperative rearrangements of LJ38 and LJ75 are presented. We also outline an updated algorithm for constructing complicated multi-step pathways using successive DNEB runs.Comment: 13 pages, 8 figures, 2 table

The impact of drought length and intensity on N cycling gene abundance, transcription and the size of an N2O hot moment from a temperate grassland soil

This study aimed to investigate the relationship between drought length, drought intensity and the size of the N2O hot moment. It selected two treatments to deduce the main nitrogen cycling process producing N2O (increasing WFPS from 40% to 90%, and from 70% to 90%), by destructively sampling soil cores to analyse gene abundance, transcription, and changes in soil chemistry (TON, NH4+, DOC). Five other drought and rewetting treatments on packed soil cores were selected to create the drought curves described in Barrat et al. (2020): these included increases of WFPS from 40% to 90%, 50%–90%, 60%–90%, 70%–90%, and 30%–60%. For each treatment, drought lengths were imposed from 0 to 30 days. A quadratic linear regression was fitted to the cumulative emissions data. This model explained a significant proportion of the total variation in the data (R2 =0.72, p ≤ 0.001). All treatments had an increase in daily N2O emissions post wetting typical of a hot moment apart from the 30%–60% WFPS treatment. In terms of drought intensity, the 40%–90% WFPS was significantly larger than rest, probably due to a relatively larger change in water potential compared to the other treatments. The response to drought length followed a quadratic curve with a downward linear trend, with the largest emissions observed between 10 and 15 days of drought, and the smallest at 0 and 30 days. We suggest a 2-stage dormancy strategy to explain this, where microbes under dry conditions store osmolytes which are catabolised upon rewetting, however at prolonged negative water potentials this strategy is no longer effective, and so they enter a deeper state of dormancy where they can no longer rapidly respond to the changing water potential. Given the delayed response after rewetting, and the inverted U shaped curve in terms of drought length, it seems likely that the majority of emissions are of biological origin. The soil’s chemistry data suggested that NH4+ was a key factor controlling the emission flux, but the transcriptional and genomic data were inconclusive. This study therefore suggests that future experiments should focus changes in osmolyte accumulation and catabolism as the key explanation for N2O hot moments, rather than changes in genomic and transcriptomic data or soil substrates, which do not always correlate with emissions