Negative electronic compressibility and nanoscale inhomogeneity in ionic-liquid gated two-dimensional superconductors

When the electron density of highly crystalline thin films is tuned by chemical doping or ionic liq- uid gating, interesting effects appear including unconventional superconductivity, sizeable spin-orbit coupling, competition with charge-density waves, and a debated low-temperature metallic state that seems to avoid the superconducting or insulating fate of standard two-dimensional electron systems. Some experiments also find a marked tendency to a negative electronic compressibility. We suggest that this indicates an inclination for electronic phase separation resulting in a nanoscopic inhomo- geneity. Although the mild modulation of the inhomogeneous landscape is compatible with a high electron mobility in the metallic state, this intrinsically inhomogeneous character is highlighted by the peculiar behaviour of the metal-to-superconductor transition. Modelling the system with super- conducting puddles embedded in a metallic matrix, we fit the peculiar resistance vs. temperature curves of systems like TiSe2, MoS2, and ZrNCl. In this framework also the low-temperature debated metallic state finds a natural explanation in terms of the pristine metallic background embedding non-percolating superconducting clusters. An intrinsically inhomogeneous character naturally raises the question of the formation mechanism(s). We propose a mechanism based on the interplay be- tween electrons and the charges of the gating ionic liquid.Comment: substantially modified presentation: 12 pages 7 figure

Phase separation and long wave-length charge instabilities in spin-orbit coupled systems

We investigate a two-dimensional electron model with Rashba spin-orbit interaction where the coupling constant $g=g(n)$ depends on the electronic density. It is shown that this dependence may drive the system unstable towards a long-wave length charge density wave (CDW) where the associated second order instability occurs in close vicinity to global phase separation. For very low electron densities the CDW instability is nesting-induced and the modulation follows the Fermi momentum $k_F$. At higher density the instability criterion becomes independent of $k_F$ and the system may become unstable in a broad momentum range. Finally, upon filling the upper spin-orbit split band, finite momentum instabilities disappear in favor of phase separation alone. We discuss our results with regard to the inhomogeneous phases observed at the LaAlO$_3$/SrTiO$_3$ or LaTiO$_3$/SrTiO$_3$ interfaces.Comment: 6 pages, 6 figure

Theory of the spin galvanic effect at oxide interfaces

The spin galvanic effect (SGE) describes the conversion of a non-equilibrium spin polarization into a transverse charge current. Recent experiments have demonstrated a large conversion efficiency for the two-dimensional electron gas formed at the interface between two insulating oxides, LaAlO$_3$ and SrTiO$_3$. Here we analyze the SGE for oxide interfaces within a three-band model for the Ti t$_{2g}$ orbitals which displays an interesting variety of effective spin-orbit couplings in the individual bands that contribute differently to the spin-charge conversion. Our analytical approach is supplemented by a numerical treatment where we also investigate the influence of disorder and temperature, which turns out to be crucial to provide an appropriate description of the experimental data.Comment: 5 pages, 3 figure

Dynamical charge density waves rule the phase diagram of cuprates

In the last few years charge density waves (CDWs) have been ubiquitously observed in high-temperature superconducting cuprates and are now the most investigated among the competing orders in the still hot debate on these systems. A wealth of new experimental data raise several fundamental issues that challenge the various theoretical proposals. Here, we account for the complex experimental temperature vs. doping phase diagram and we provide a coherent scenario explaining why different CDW onset curves are observed by different experimental probes and seem to extrapolate at zero temperature into seemingly different quantum critical points (QCPs) in the intermediate and overdoped region. We also account for the pseudogap and its onset temperature T*(p) on the basis of dynamically fluctuating CDWs. The nearly singular anisotropic scattering mediated by these fluctuations also account for the rapid changes of the Hall number seen in experiments and provides the first necessary step for a possible Fermi surface reconstruction fully establishing at lower doping. Finally we show that phase fluctuations of the CDWs, which are enhanced in the presence of strong correlations near the Mott insulating phase, naturally account for the disappearance of the CDWs at low doping with yet another QCP.Comment: 13 pages, 7 figure

Phase diagrams of voltage-gated oxide interfaces with strong Rashba coupling

We propose a model for the two-dimensional electron gas formed at the interface of oxide heterostructures that includes a Rashba spin-orbit coupling proportional to an electric field oriented perpendicularly to the interface. Taking into account the electron density dependence of this electric field confining the electron gas at the interface, we report the occurrence of a phase separation instability (signaled by a negative compressibility) for realistic values of the spin-orbit coupling and of the electronic band-structure parameters at zero temperature. We extend the analysis to finite temperatures and in the presence of an in-plane magnetic field, thereby obtaining two phase diagrams which exhibit a phase separation dome. By varying the gating potential the phase separation dome may shrink and vanish at zero temperature into a quantum critical point where the charge fluctuates dynamically. Similarly the phase separation may be spoiled by a planar magnetic field even at zero temperature leading to a line of quantum critical points.Comment: 17 pages, 17 figure

Kinks and waterfalls as signatures of competing order in angle-resolved photoemission spectra of La_{2-x}Sr_xCuO_4

We show that the so-called kinks and waterfalls observed in angle-resolved photoemission spectra of La2-xSrxCuO4, a prototypical high-Tc superconducting cuprate, result from the coupling of quasiparticles with two distinct nearly critical collective modes with finite characteristic wave vectors, typical of charge and spin fluctuations near a stripe instability. Both phonon-like charge and spin collective modes are needed to account for the kinked quasiparticle dispersions. This clarifies the long-standing question whether kinks are due to phonons or spin waves and the nature of the bosonic mediators of the electron-electron effective interaction in La2-xSrxCuO4.Comment: 5 pages, 4 figure

Density inhomogeneities and Rashba spin-orbit coupling interplay in oxide interfaces

There is steadily increasing evidence that the two-dimensional electron gas (2DEG) formed at the interface of some insulating oxides like LaAlO3/SrTiO3 and LaTiO3/SrTiO3 is strongly inhomogeneous. The inhomogeneous distribution of electron density is accompanied by an inhomogeneous distribution of the (self-consistent) electric field confining the electrons at the interface. In turn this inhomogeneous transverse electric field induces an inhomogeneous Rashba spin-orbit coupling (RSOC). After an introductory summary on two mechanisms possibly giving rise to an electronic phase separation accounting for the above inhomogeneity,we introduce a phenomenological model to describe the density-dependent RSOC and its consequences. Besides being itself a possible source of inhomogeneity or charge-density waves, the density-dependent RSOC gives rise to interesting physical effects like the occurrence of inhomogeneous spin-current distributions and inhomogeneous quantum-Hall states with chiral "edge" states taking place in the bulk of the 2DEG. The inhomogeneous RSOC can also be exploited for spintronic devices since it can be used to produce a disorder-robust spin Hall effect.Comment: 13 pages, 15 figure

Doping-driven transition to a time-reversal breaking state in the phase diagram of the cuprates

Motivated by recent tunnelling and Andreev-reflection experiments, we study the conditions for a quantum transition within the superconducting phase of the cuprates,in which a bulk imaginary (time-reversal breaking) $id_{xy}$component appears in addition to the $d_{x^2 - y^2}$ order parameter. We examine in detail the role of some important physical features of the cuprates.In particular we show that a closed Fermi surface,a bilayer splitting, an orthorhombic distortion,and the proximity to a quantum critical point around optimal doping favor the appearance of the imaginary component. These findings could explain why the mixed $d_{x^2 - y^2}+ id_{xy}$ order parameter is observed in YBCO and LSCO, and suggest that it could appear also in Bi2212. We also predict that, in all cuprates, the mixed state should be stable only in a limited doping region all contained beneath the $d_{x^2 - y^2}$ dome. The behavior of the specific heat at the secondary transition is discussed.Comment: 8 pages, 3 figures. Expanded text, 1 extra figur

Electronic polymers and soft-matter-like broken symmetries in underdoped cuprates

Empirical evidence in heavy fermion, pnictide, and other systems suggests that unconventional superconductivity appears associated to some form of real-space electronic order. For the cuprates, despite several proposals, the emergence of order in the phase diagram between the commensurate antiferromagnetic state and the superconducting state is not well understood. Here we show that in this regime doped holes assemble in "electronic polymers." Within a Monte Carlo study we find, that in clean systems by lowering the temperature the polymer melt condenses first in a smectic state and then in a Wigner crystal both with the addition of inversion symmetry breaking. Disorder blurs the positional order leaving a robust inversion symmetry breaking and a nematic order, accompanied by vector chiral spin order and with the persistence of a thermodynamic transition. Such electronic phases, whose properties are reminiscent of soft-matter physics, produce charge and spin responses in good accord with experiments.Comment: 10 pages, 4 figures plus supplementary informatio

Possible mechanisms of electronic phase separation in oxide interfaces

LaAlO3/SrTiO3 ad LaTiO3/SrTiO3 interfaces are known to host a strongly inhomogeneous (nearly) two-dimensional electron gas (2DEG). In this work we present three unconventional electronic mechanisms of electronic phase separation (EPS) in a 2DEG as a possible source of inhomogeneity in oxide interfaces. Common to all three mechanisms is the dependence of some (interaction) potential on the 2DEG's density. We first consider a mechanism resulting from a sizable density-dependent Rashba spin-orbit coupling. Next, we point out that an EPS may also occur in the case of a density-dependent superconducting pairing interaction. Finally, we show that the confinement of the 2DEG to the interface by a density-dependent, self-consistent electrostatic potential can by itself cause an EPS.Comment: 4 pages and 4 figures, Proceedings of the International Conference "Superstripes 2014", 25-31 July 2015, Erice, Ital