A new conducting polymer with exceptional visible-light photocatalytic activity derived from varbituric acid polycondensation

Abstract A novel covalent, metal-free, photocatalytic material is prepared by thermal polymerization of barbituric acid (BA). The structure of the photocatalyst is analyzed by using scanning electron microscopy, X-ray diffraction, and infrared, UV?visible, and 1H solution and 13C solid-state NMR spectroscopy. The photodegradation efficiency of BA thermally polymerized at different temperatures is tested by photocatalytic degradation of aquatic rhodamine B (RhB) dye under visible-light irradiation. It is shown that heating BA at an optimized temperature of 300 °C, that is, still in the range that polymer-like polycondensation takes place, results in a photocatalyst that can remove RhB with 96% photodegradation efficiency after 70 min exposure to visible light. The polycondensation reaction of BA is identified to process through precipitation of trimer units as primary building blocks. Reference experiments such as addition of scavengers and saturation with oxygen are studied to understand the photodegradation process. It is shown that the presence of triethanolamine, and excess of oxygen and p-benzoquinone in the solution of RhB and photocatalyst (BA300) is not beneficial, but decreases the photodegradation efficiency

Universality and correlations in individuals wandering through an online extremist space

The 'out of the blue' nature of recent terror attacks and the diversity of apparent motives, highlight the importance of understanding the online trajectories that individuals follow prior to developing high levels of extremist support. Here we show that the physics of stochastic walks, with and without temporal correlation, provides a unifying description of these online trajectories. Our unique dataset comprising all users of a global social media site, reveals universal characteristics in individuals' online lifetimes. Our accompanying theory generates analytical and numerical solutions that describe the characteristics shown by individuals that go on to develop high levels of extremist support, and those that do not. The existence of these temporal and also many-body correlations suggests that existing physics machinery can be used to quantify and perhaps mitigate the risk of future events

Evidence for anisotropic motion of the clouds in broad-line regions of BL Lacertae objects

The masses of central massive black holes in BL Lac objects are estimated from their host galaxy absolute magnitude at R-band by using the empirical relation between absolute magnitude of host galaxy and black hole mass. Only a small fraction of BL Lac objects exhibit weak broad-line emission, and we derive the sizes of the broad-line regions (BLRs) in these BL Lac objects from the widths of their broad emission lines on the assumption of the clouds being virilized in BLRs. It is found that the sizes of the BLRs in these sources are usually 2-3 orders of magnitude larger than that expected by the empirical correlation between BLR size and optical luminosity defined by a sample of Seyfert galaxies and quasars. We discuss a variety of possibilities and suggest it may probably be attributed to anisotropic motion of the BLR clouds in these BL Lac objects. If the BLR geometry of these sources is disk-like, the viewing angles between the axis and the line of sight are in the range of 2-12 degrees, which is consistent with the unification schemes.Comment: 5 pages, accepted for publication in Ap

Metal-to-insulator transition and magnetic ordering in CaRu_{1-x}Cu_xO_3

CaRuO_3 is perovskite with an orthorhombic distortion and is believed to be close to magnetic ordering. Magnetic studies of single crystal and polycrystalline CaRu_{1-x}Cu_xO_3 (0\le x \le 15 at.%Cu) reveal that spin-glass-like transition develops for x\le 7 at.%Cu and obtained value for effective magnetic moment p_{eff}=3.55 mu_B for x=5 at.% Cu, single crystal, indicates presence of Ru^{5+}. At higher Cu concentrations more complex magnetic behaviors are observed. Electrical resistivity measured on polycrystalline samples shows metal-to-insulator transition (MIT) at 51 K for only 2 at.% Cu. Charge compensation, which is assumed to be present upon Cu^{2+/3+} substitution, induces appearance of Ru^{5+} and/or creation of oxygen vacancies in crystal structure. Since the observed changes in physical properties are completely attributable to the charge compensation, they cannot be related to behaviors of pure compound where no such mechanism is present. This study provides the criterion for "good" chemical probes for studying Ru-based perovskites.Comment: 12 pages, 7 figure

An Agent Based Model for the Simulation of Transport Demand and Land Use

Agent based modelling has emerged as a promising tool to provide planners with insights on social behaviour and the interdependencies characterising urban system, particularly with respect to transport and infrastructure planning. This paper presents an agent based model for the simulation of land use and transport demand of an urban area of Sydney, Australia. Each individual in the model has a travel diary which comprises a sequence of trips the person makes in a representative day as well as trip attributes such as travel mode, trip purpose, and departure time. Individuals are associated with each other by their household relationship, which helps define the interdependencies of their travel diary and constrains their mode choice. This allows the model to not only realistically reproduce how the current population uses existing transport infrastructure but more importantly provide comprehensive insight into future transport demands. The router of the traffic micro-simulator TRANSIMS is incorporated in the model to inform the actual travel time of each trip and changes of traffic density on the road network. Simulation results show very good agreement with survey data in terms of the distribution of trips done by transport modes and by trip purposes, as well as the traffic density along the main road in the study area

Pinned Low Energy Electronic Excitation in Metal Exchanged Vanadium Oxide Nanoscrolls

We measured the optical properties of mixed valent vanadium oxide nanoscrolls and their metal exchanged derivatives in order to investigate the charge dynamics in these compounds. In contrast to the prediction of a metallic state for the metal exchanged derivatives within a rigid band model, we find that the injected charges in Mn$^{2+}$ exchanged vanadium oxide nanoscrolls are pinned. A low-energy electronic excitation associated with the pinned carriers appears in the far infrared and persists at low temperature, suggesting that the nanoscrolls are weak metals in their bulk form, dominated by inhomogeneous charge disproportionation and Madelung energy effects.Comment: 4 figure

Destruction of the Mott Insulating Ground State of Ca_2RuO_4 by a Structural Transition

We report a first-order phase transition at T_M=357 K in single crystal Ca_2RuO_4, an isomorph to the superconductor Sr_2RuO_4. The discontinuous decrease in electrical resistivity signals the near destruction of the Mott insulating phase and is triggered by a structural transition from the low temperature orthorhombic to a high temperature tetragonal phase. The magnetic susceptibility, which is temperature dependent but not Curie-like decreases abruptly at TM and becomes less temperature dependent. Unlike most insulator to metal transitions, the system is not magnetically ordered in either phase, though the Mott insulator phase is antiferromagnetic below T_N=110 K.Comment: Accepted for publication in Phys. Rev. B (Rapid Communications

The relation between star formation rate and accretion rate in LINERs

It is argued that there is a linear correlation between star formation rate (SFR) and accretion rate for normal bright active galactic nuclei (AGNs). However, it is still unclear whether this correlation holds for LINERs, of which the accretion rates are relatively lower than those of normal bright AGNs. The radiatively inefficient accretion flows (RIAFs) are believed to be present in these LINERs. In this work, we derive accretion rates for a sample of LINERs from their hard X-ray luminosities based on spectral calculations for RIAFs. We find that LINERs follow the same correlation between star formation rate and accretion rate defined by normal bright AGNs, when reasonable parameters are adopted for RIAFs. It means that the gases feed the black hole and star formation in these low-luminosity LINERs may follow the same way as that in normal bright AGNs, which is roughly consistent with recent numerical simulations on quasar evolution.Comment: 15 pages, 3 figures, accepted for publication in PASP, in pres