Proof of principle for a molecular 1:2 demultiplexer to function as an autonomously switching theranostic device

Cataloged from PDF version of article.Guided by the digital design concepts, we synthesized a two-module molecular demultiplexer (DEMUX) where the output is switched between emission at near IR, and cytotoxic singlet oxygen, with light at 625 nm as the input (I), and acid as the control (c). In the neutral form, the compound fluoresces brightly under excitation at 625 nm, however, acid addition moves the absorption bands of the two modules in opposite directions, resulting in an effective reversal of excitation energy transfer direction, with a concomitant upsurge of singlet oxygen generation and decrease in emission intensity

Cascading of Molecular Logic Gates for Advanced Functions: A Self-Reporting, Activatable Photosensitizer

Cataloged from PDF version of article.Logical progress: Independent molecular logic gates have been designed and characterized. Then, the individual molecular logic gates were coerced to work together within a micelle. Information relay between the two logic gates was achieved through the intermediacy of singlet oxygen. Working together, these concatenated logic gates result in a self-reporting and activatable photosensitizer. GSH=glutathione

Forward tunneling current in Pt/p-InGaN and Pt/n-InGaN Schottky barriers in a wide temperature range

Cataloged from PDF version of article.The current-transport mechanisms of the Pt contacts on p-InGaN and n-InGaN were investigated in a wide temperature range (80-360 K) and in the forward bias regime. It was found that the ideality factor (n) values and Schottky barrier heights (SBHs), as determined by thermionic emission (TE), were a strong function of temperature and Phi(b0) show the unusual behavior of increasing linearly with an increase in temperature from 80 to 360 K for both Schottky contacts. The tunneling saturation (J(TU)(0)) and tunneling parameters (E-0) were calculated for both Schottky contacts. We observed a weak temperature dependence of the saturation current and a fairly small dependence on the temperature of the tunneling parameters in this temperature range. The results indicate that the dominant mechanism of the charge transport across the Pt/p-InGaN and Pt/n-InGaN Schottky contacts are electron tunneling to deep levels in the vicinity of mixed/screw dislocations in the temperature range of 80-360 K. (c) 2012 Elsevier B.V. All rights reserved

Multichannel optical diode with unidirectional diffraction relevant total transmission

Cataloged from PDF version of article.We will show that broadband unidirectional optical transmission with a total transmission maximum inside the band can be obtained for linearly polarized incident waves in the nonsymmetric photonic crystal gratings made of isotropic linear materials at a fixed nonzero or zero angle of incidence. Being based on the merging of diffraction and dispersion effects, the basic physical mechanism studied exploits the transmission channels associated with higher orders, for which asymmetry in the coupling conditions at the two grating interfaces appears when spatial inversion symmetry is broken. Total transmission in one direction and zero transmission in the opposite direction can be obtained due to hybridization of Fabry-Perot type resonances with a diffraction anomaly that yields a diode-like operation regime. Single-beam deflection and two-beam splitting can be obtained, for which transmission can be (nearly) total, if the corrugated side is illuminated. In contrast to the previous studies, it is also shown that unidirectional transmission can appear only at a fixed frequency and only due to diffractions, when total transmission occurs at the noncorrugated-side illumination, being in agreement with the Lorentz Lemma. (c) 2012 Optical Society of America

Spatial filtering using dielectric photonic crystals at beam-type excitation

Cataloged from PDF version of article.Spatial filtering is demonstrated at beam-type excitations by utilizing finite thickness slabs of two-dimensional dielectric photonic crystals (PCs) showing exotic Fabry-Perot resonances that are preserved over a wide range of variation of the incidence angle. Bandstop and dual-bandpass filtering effects are illustrated theoretically and the corresponding filters are validated in the microwave experiments by using square-lattice PCs. It is shown that the basic transmission features that were observed earlier for a plane-wave illumination are also recognizable at beam-type excitations. The proposed spatial filtering mechanism exhibits directional beaming. The desired widths and the locations of the passbands and stopbands are attainable in the angle domain with a proper choice of the operating frequency for the given excitation characteristics. c 2010 American Institute of Physics. [doi:10.1063/1.3498810

Near-field light localization using subwavelength apertures incorporated with metamaterials

Cataloged from PDF version of article.We report strong near-field electromagnetic localization by using subwavelength apertures and metamaterials that operate at microwave frequencies. We designed split ring resonators with distinct configurations in order to obtain extraordinary transmission results. Furthermore, we analyzed the field localization and focusing characteristics of the transmitted evanescent waves. The employed metamaterial configurations yielded an improvement on the transmission efficiency on the order of 27 dB and 50 dB for the deep subwavelength apertures. The metamaterial loaded apertures are considered as a total system that offered spot size conversion ratios as high as 7.12 and 9.11 for the corresponding metamaterial configurations. The proposed system is shown to intensify the electric fields of the source located in the near-field. It also narrows down the electromagnetic waves such that a full width at half maximum value of λ/29 is obtained. © 2012 Elsevier B.V. All rights reserved

Simultaneously opening transmission channels with negative and positive phase velocities for the stacked subwavelength apertures in fishnet metamaterials with hybrid unit lattices

Cataloged from PDF version of article.Hybridization of the unit lattice along the propagation direction was demonstrated to produce a negative-phase-velocity transmission band in the absence of the contributions from the higher diffraction orders for a stacked metallic fishnet grid with subwavelength apertures. This extraordinary transmission band is governed by the stacked resonators. The hybridized unit lattice configurations are not just slight modifications of the configurations with homogenous unit lattices. The volumetric proportions of different dielectric media are a key factor in the partitioned unit lattice for the estimation of the stacking and coupling effects between the resonators. The contribution of the coupling mechanisms enhances the transmission results almost by the same factor for the investigated lattice separations along the propagation direction in hybrid unit cells while the densely stacked resonators yield much higher transmission results, both around the regarding extraordinary transmission band that is associated with the negative phase velocity. A positive-phase-velocity transmission band was also exhibited by the hybridized unit lattice configuration when combined with a cavity resonator. Experimental transmission results of the hybrid configuration supported the theoretical predictions. The hybrid configurations are scalable to the near-infrared regime. (C) 2012 Society of Photo-Optical Instrumentation Engineers (SPIE). [DOI: 10.1117/1.JNP.6.061608

Induction of triacylglycerol production in Chlamydomonas reinhardtii: Comparative analysis of different element regimes

Cataloged from PDF version of article.In this study, impacts of different element absence (nitrogen, sulfur, phosphorus and magnesium) and supplementation (nitrogen and zinc) on element uptake and triacylglycerol production was followed in wild type Chlamydomonas reinhardtii CC-124 strain. Macro- and microelement composition of C. reinhardtii greatly differed under element regimes studied. In particular, heavy metal quotas of the microalgae increased strikingly under zinc supplementation. Growth was suppressed, cell biovolume, carbohydrate, total neutral lipid and triacylglycerol levels increased when microalgae were incubated under these element regimes. Most of the intracellular space was occupied by lipid bodies under all nutrient starvations, as observed by confocal microscopy and transmission electron micrographs. Results suggest that sulfur, magnesium and phosphorus deprivations are superior to nitrogen deprivation for the induction triacylglycerol production in C. reinhardtii. On the other hand, FAME profiles of the nitrogen, sulfur and phosphorus deprived cells were found to meet the requirements of international standards for biodiesel. Crown Copyright (C) 2013 Published by Elsevier Ltd. All rights reserved