Magnetic Iron Oxide Nanoparticles: Synthesis and Surface Functionalization Strategies

Surface functionalized magnetic iron oxide nanoparticles (NPs) are a kind of novel functional materials, which have been widely used in the biotechnology and catalysis. This review focuses on the recent development and various strategies in preparation, structure, and magnetic properties of naked and surface functionalized iron oxide NPs and their corresponding application briefly. In order to implement the practical application, the particles must have combined properties of high magnetic saturation, stability, biocompatibility, and interactive functions at the surface. Moreover, the surface of iron oxide NPs could be modified by organic materials or inorganic materials, such as polymers, biomolecules, silica, metals, etc. The problems and major challenges, along with the directions for the synthesis and surface functionalization of iron oxide NPs, are considered. Finally, some future trends and prospective in these research areas are also discussed

Copper salt–assisted polymerization of bispropargyl ether–bismaleimide blend

Bispropargyl ether (BPE) of bisphenol-A was prepared. It was blended with 4,4’-bismaleimido diphenyl methane (BMI, 0.5:0.5 mol). The copper sulphate pentahydrate (CuSO4·5H2O) was blended (1% w/w) separately with pure BPE and BPE-BMI blend and the materials were thermally cured. The structural characterization of the materials was done using a Fourier-transform infrared spectrophotometer. The curing behaviour of the materials was investigated using differential scanning calorimetry. The presence of copper salt in BPE shifted the curing temperature to lower temperature region. The presence of copper salt in BPE-BMI blend also decreased the curing onset temperature by approximately 15°C. The thermal property of the polymers was investigated using thermogravimetry. The incorporation of copper salt in BPE-BMI blend led to polymer with increased thermal stability. </jats:p

Studies on structurally different benzoxazines

Bisbenzoxazines were prepared by the condensation of the respective bisphenols bisphenol A (BA), indane bisphenol (IBP), and spirobiindane bisphenol (SBI) with paraformaldehyde and aniline. The apparent activation energies for the polymerization curing process ( Ea-C) and the degradation process ( Ea-D) were calculated using Flynn–Wall–Ozawa, Vyazovkin, and Friedman methods. The variation in Ea-C noted for the thermal curing of different bisbenzoxazines is attributed to the operation of different mechanisms for the curing process. The variation of the Ea-D for the degradation of spirobiindane benzoxazine polymerized at high temperature was different from the other materials investigated and is attributed to its complex structure. The volatile products obtained during the thermal degradation of the polymers were analyzed using thermogravimetric–Fourier transform infrared analyses. Aniline was found to be the major product and was released during the primary degradation. At higher temperatures, breakage of the isopropylidine, indane, and biindane structural entities were favored. </jats:p

Thermal, mechanical, and electrical properties of difunctional and trifunctional epoxy blends with nanoporous materials

In the present study, the aim is to synthesize the particulate nanocomposites with difunctional and trifunctional epoxy blend as matrix and synthesized nanoporous materials as fillers. Organic/inorganic hybrid networks were prepared by the novel solvent free method. Viscoelastic, thermal, and electrical properties of di- and trifunctional epoxy and the effect of different nanoparticles in the particulate nanocomposites have been studied by dynamic mechanical analyzer, thermogravimetry (TGA), and dielectric strength. Epoxy mixed with different compositions of TGPAP and particulate nanocomposites by the addition of different types of nanomaterials shows higher storage modulus than the pure epoxy. The addition of TGPAP and nanofillers decreases the thermal stability of epoxy matrix. The evolved gas analysis (TG-FTIR) was also done in order to study the products formed during degradation. An increase in dielectric strength and impact strength (4%) was also observed in the particulate nanocomposites. </jats:p