Sulfur loss from subducted altered oceanic crust and implications for mantle oxidation

© The Author(s), [year]. This article is distributed under the terms of the Creative Commons Attribution License. The definitive version was published in Walters, J. B., Cruz-Uribe, A. M., & Marschall, H. R. Sulfur loss from subducted altered oceanic crust and implications for mantle oxidation. Geochemical Perspectives Letters, 13, (2020): 36-41, doi:10.7185/geochemlet.2011.Oxygen fugacity (fO2) is a controlling factor of the physics of Earth’s mantle; however, the mechanisms driving spatial and secular changes in fO2 associated with convergent margins are highly debated. We present new thermodynamic models and petrographic observations to predict that oxidised sulfur species are produced during the subduction of altered oceanic crust. Sulfur loss from the subducting slab is a function of the protolith Fe3+/ΣFe ratio and subduction zone thermal structure, with elevated sulfur fluxes predicted for oxidised slabs in cold subduction zones. We also predict bi-modal release of sulfur-bearing fluids, with a low volume shallow flux of reduced sulfur followed by an enhanced deep flux of sulfate and sulfite species, consistent with oxidised arc magmas and associated copper porphyry deposits. The variable SOx release predicted by our models both across and among active margins may introduce fO2 heterogeneity to the upper mantle.We thank James Connolly for modelling support and Peter van Keken for providing updated P–T paths for the Syracuse et al. (2010) models. The manuscript benefited from the editorial handling by Helen Williams and from constructive reviews of Maryjo Brounce, Katy Evans, and an anonymous reviewer. JBW acknowledges Fulbright and Chase Distinguished Research fellowships. This work was supported by NSF grant EAR1725301 awarded to AMC

Opposite polarity field with convective downflow and its relation to magnetic spines in a sunspot penumbra

We discuss NICOLE inversions of Fe I 630.15 nm and 630.25 nm Stokes spectra from a sunspot penumbra recorded with the CRISP imaging spectropolarimeter on the Swedish 1-m Solar Telescope at a spatial resolution close to 0.15". We report on narrow radially extended lanes of opposite polarity field, located at the boundaries between areas of relatively horizontal magnetic field (the intra-spines) and much more vertical field (the spines). These lanes harbor convective downflows of about 1 km/s. The locations of these downflows close to the spines agree with predictions from the convective gap model (the "gappy penumbra") proposed six years ago, and more recent 3D MHD simulations. We also confirm the existence of strong convective flows throughout the entire penumbra, showing the expected correlation between temperature and vertical velocity, and having vertical RMS velocities of about 1.2 km/s.Comment: Accepted for publication in A&A (06-March-2013). Minor corrections made in this version

Symmetry Aspects in Nonrelativistic Multi-Scalar Field Models and Application to a Coupled Two-Species Dilute Bose Gas

We discuss unusual aspects of symmetry that can happen due to entropic effects in the context of multi-scalar field theories at finite temperature. We present their consequences, in special, for the case of nonrelativistic models of hard core spheres. We show that for nonrelativistic models phenomena like inverse symmetry breaking and symmetry non-restoration cannot take place, but a reentrant phase at high temperatures is shown to be possible for some region of parameters. We then develop a model of interest in studies of Bose-Einstein condensation in dilute atomic gases and discuss about its phase transition patterns. In this application to a Bose-Einstein condensation model, however, no reentrant phases are found.Comment: 8 pages, 1 eps figure, IOP style. Based on a talk given by R. O. Ramos at the QFEXT05 workshop, Barcelona, Spain, September 5-9, 2005. One reference was update