443 research outputs found
Correlations of a bound interface over a random substrate
The correlation function of a one-dimensional interface over a random
substrate, bound to the substrate by a pressure term, is studied by Monte-Carlo
simulation. It is found that the height correlation , averaged
over the substrate disorder, fits a form exp(-(j/b)^c) to a surprising
precision in the full range of j where the correlation is non-negligible. The
exponent c increases from 1.0 to 1.5 when the interface tension is taken larger
and larger.Comment: 7 pages, 5 figure
Dynamics of Spreading of Chainlike Molecules with Asymmetric Surface Interactions
In this work we study the spreading dynamics of tiny liquid droplets on solid
surfaces in the case where the ends of the molecules feel different
interactions with respect to the surface. We consider a simple model of dimers
and short chainlike molecules that cannot form chemical bonds with the surface.
We use constant temperature Molecular Dynamics techniques to examine in detail
the microscopic structure of the time dependent precursor film. We find that in
some cases it can exhibit a high degree of local order that can persist even
for flexible chains. Our model also reproduces the experimentally observed
early and late-time spreading regimes where the radius of the film grows
proportional to the square root of time. The ratios of the associated transport
coefficients are in good overall agreement with experiments. Our density
profiles are also in good agreement with measurements on the spreading of
molecules on hydrophobic surfaces.Comment: 12 pages, LaTeX with APS macros, 21 figures available by contacting
[email protected], to appear in Phys. Rev.
Dewetting, partial wetting and spreading of a two-dimensional monolayer on solid surface
We study the behavior of a semi-infinite monolayer, which is placed initially
on a half of an infinite in both directions, ideal crystalline surface, and
then evolves in time due to random motion of the monolayer particles. Particles
dynamics is modeled as the Kawasaki particle-vacancy exchange process in the
presence of long-range attractive particle-particle interactions. In terms of
an analytically solvable mean-field-type approximation we calculate the mean
displacement X(t) of the monolayer edge and discuss the conditions under which
such a monolayer spreads (X(t) > 0), partially wets (X(t) = 0) or dewets from
the solid surface (X(t) < 0).Comment: 4 pages, 2 figures, to appear in PRE (RC
Spreading of a Macroscopic Lattice Gas
We present a simple mechanical model for dynamic wetting phenomena. Metallic
balls spread along a periodically corrugated surface simulating molecules of
liquid advancing along a solid substrate. A vertical stack of balls mimics a
liquid droplet. Stochastic motion of the balls, driven by mechanical vibration
of the corrugated surface, induces diffusional motion. Simple theoretical
estimates are introduced and agree with the results of the analog experiments,
with numerical simulation, and with experimental data for microscopic spreading
dynamics.Comment: 19 pages, LaTeX, 9 Postscript figures, to be published in Phy. Rev. E
(September,1966
Force-velocity relation and density profiles for biased diffusion in an adsorbed monolayer
In this paper, which completes our earlier short publication [Phys. Rev.
Lett. 84, 511 (2000)], we study dynamics of a hard-core tracer particle (TP)
performing a biased random walk in an adsorbed monolayer, composed of mobile
hard-core particles undergoing continuous exchanges with a vapor phase. In
terms of an approximate approach, based on the decoupling of the third-order
correlation functions, we obtain the density profiles of the monolayer
particles around the TP and derive the force-velocity relation, determining the
TP terminal velocity, V_{tr}, as the function of the magnitude of external bias
and other system's parameters. Asymptotic forms of the monolayer particles
density profiles at large separations from the TP, and behavior of V_{tr} in
the limit of small external bias are found explicitly.Comment: Latex, 31 pages, 3 figure
Dynamics of liquid He-4 in confined geometries from Time-Dependent Density Functional calculations
We present numerical results obtained from Time-Dependent Density Functional
calculations of the dynamics of liquid He-4 in different environments
characterized by geometrical confinement. The time-dependent density profile
and velocity field of He-4 are obtained by means of direct numerical
integration of the non-linear Schrodinger equation associated with a
phenomenological energy functional which describes accurately both the static
and dynamic properties of bulk liquid He-4. Our implementation allows for a
general solution in 3-D (i.e. no symmetries are assumed in order to simplify
the calculations). We apply our method to study the real-time dynamics of pure
and alkali-doped clusters, of a monolayer film on a weakly attractive surface
and a nano-droplet spreading on a solid surface.Comment: q 1 tex file + 9 Ps figure
Challenges and opportunities of achieving European COâ‚‚ transportation and storage specifications for carbon capture in the iron and steel industry
The application of CCS in the iron and steel industry faces particular challenges for achieving European CO2 transportation and storage in meeting COâ‚‚ stream impurity limit specifications due to the unique and diverse composition of the steelworks off-gases targeted for COâ‚‚ capture and the separation efficiency of proposed COâ‚‚ capture solutions. This paper reviews the range and levels of compounds that could form potential COâ‚‚ impurities in steelworks off-gases and provides estimates of the quality of COâ‚‚ products obtained in primary COâ‚‚ capture steps from Blast Furnace Gas (BFG) using different technologies of Pressure-Swing Adsorption (PSA) and amine scrubbing. Published COâ‚‚ specifications from European transportation and storage operators are reviewed and compared. Additional suitable purification steps that are needed in order to reduce the levels of impurities from primary COâ‚‚ product streams in order to achieve European COâ‚‚ impurity limit specifications are identified, characterised and the associated cost implications discussed
Molecular ordering of precursor films during spreading of tiny liquid droplets
In this work we address a novel feature of spreading dynamics of tiny liquid
droplets on solid surfaces, namely the case where the ends of the molecules
feel different interactions to the surface. We consider a simple model of
dimers and short chain--like molecules which cannot form chemical bonds with
the surface. We study the spreading dynamics by Molecular Dynamics techniques.
In particular, we examine the microscopic structure of the time--dependent
precursor film and find that in some cases it can exhibit a high degree of
local order. This order persists even for flexible chains. Our results suggest
the possibility of extracting information about molecular interactions from the
structure of the precursor film.Comment: 4 pages, revtex, no figures, complete file available from
ftp://rock.helsinki.fi/pub/preprints/tft/ or at
http://www.physics.helsinki.fi/tft/tft_preprints.html (to appear in Phys.
Rev. E Rapid Comm.
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