760 research outputs found
Pressure formulas for liquid metals and plasmas based on the density-functional theory
At first, pressure formulas for the electrons under the external potential
produced by fixed nuclei are derived both in the surface integral and volume
integral forms concerning an arbitrary volume chosen in the system; the surface
integral form is described by a pressure tensor consisting of a sum of the
kinetic and exchange-correlation parts in the density-functional theory, and
the volume integral form represents the virial theorem with subtraction of the
nuclear virial. Secondly on the basis of these formulas, the thermodynamical
pressure of liquid metals and plasmas is represented in the forms of the
surface integral and the volume integral including the nuclear contribution.
From these results, we obtain a virial pressure formula for liquid metals,
which is more accurate and simpler than the standard representation. From the
view point of our formulation, some comments are made on pressure formulas
derived previously and on a definition of pressure widely used.Comment: 18 pages, no figur
Polynomial solutions of nonlinear integral equations
We analyze the polynomial solutions of a nonlinear integral equation,
generalizing the work of C. Bender and E. Ben-Naim. We show that, in some
cases, an orthogonal solution exists and we give its general form in terms of
kernel polynomials.Comment: 10 page
Wigner quantization of some one-dimensional Hamiltonians
Recently, several papers have been dedicated to the Wigner quantization of
different Hamiltonians. In these examples, many interesting mathematical and
physical properties have been shown. Among those we have the ubiquitous
relation with Lie superalgebras and their representations. In this paper, we
study two one-dimensional Hamiltonians for which the Wigner quantization is
related with the orthosymplectic Lie superalgebra osp(1|2). One of them, the
Hamiltonian H = xp, is popular due to its connection with the Riemann zeros,
discovered by Berry and Keating on the one hand and Connes on the other. The
Hamiltonian of the free particle, H_f = p^2/2, is the second Hamiltonian we
will examine. Wigner quantization introduces an extra representation parameter
for both of these Hamiltonians. Canonical quantization is recovered by
restricting to a specific representation of the Lie superalgebra osp(1|2)
Probing Ion-Ion and Electron-Ion Correlations in Liquid Metals within the Quantum Hypernetted Chain Approximation
We use the Quantum Hypernetted Chain Approximation (QHNC) to calculate the
ion-ion and electron-ion correlations for liquid metallic Li, Be, Na, Mg, Al,
K, Ca, and Ga. We discuss trends in electron-ion structure factors and radial
distribution functions, and also calculate the free-atom and metallic-atom
form-factors, focusing on how bonding effects affect the interpretation of
X-ray scattering experiments, especially experimental measurements of the
ion-ion structure factor in the liquid metallic phase.Comment: RevTeX, 19 pages, 7 figure
Cosine and Sine Operators Related with Orthogonal Polynomial Sets on the Intervall [-1,1]
The quantization of phase is still an open problem. In the approach of
Susskind and Glogower so called cosine and sine operators play a fundamental
role. Their eigenstates in the Fock representation are related with the
Chebyshev polynomials of the second kind. Here we introduce more general cosine
and sine operators whose eigenfunctions in the Fock basis are related in a
similar way with arbitrary orthogonal polynomial sets on the intervall [-1,1].
To each polynomial set defined in terms of a weight function there corresponds
a pair of cosine and sine operators. Depending on the symmetry of the weight
function we distinguish generalized or extended operators. Their eigenstates
are used to define cosine and sine representations and probability
distributions. We consider also the inverse arccosine and arcsine operators and
use their eigenstates to define cosine-phase and sine-phase distributions,
respectively. Specific, numerical and graphical results are given for the
classical orthogonal polynomials and for particular Fock and coherent states.Comment: 1 tex-file (24 pages), 11 figure
The rotating Morse potential model for diatomic molecules in the tridiagonal J-matrix representation: I. Bound states
This is the first in a series of articles in which we study the rotating
Morse potential model for diatomic molecules in the tridiagonal J-matrix
representation. Here, we compute the bound states energy spectrum by
diagonalizing the finite dimensional Hamiltonian matrix of H2, LiH, HCl and CO
molecules for arbitrary angular momentum. The calculation was performed using
the J-matrix basis that supports a tridiagonal matrix representation for the
reference Hamiltonian. Our results for these diatomic molecules have been
compared with available numerical data satisfactorily. The proposed method is
handy, very efficient, and it enhances accuracy by combining analytic power
with a convergent and stable numerical technique.Comment: 18 Pages, 6 Tables, 4 Figure
A Novel Multi-parameter Family of Quantum Systems with Partially Broken N-fold Supersymmetry
We develop a systematic algorithm for constructing an N-fold supersymmetric
system from a given vector space invariant under one of the supercharges.
Applying this algorithm to spaces of monomials, we construct a new
multi-parameter family of N-fold supersymmetric models, which shall be referred
to as "type C". We investigate various aspects of these type C models in
detail. It turns out that in certain cases these systems exhibit a novel
phenomenon, namely, partial breaking of N-fold supersymmetry.Comment: RevTeX 4, 28 pages, no figure
Block orthogonal polynomials: I. Definition and properties
Constrained orthogonal polynomials have been recently introduced in the study
of the Hohenberg-Kohn functional to provide basis functions satisfying particle
number conservation for an expansion of the particle density. More generally,
we define block orthogonal (BO) polynomials which are orthogonal, with respect
to a first Euclidean scalar product, to a given -dimensional subspace of polynomials associated with the constraints. In addition, they are
mutually orthogonal with respect to a second Euclidean scalar product. We
recast the determination of these polynomials into a general problem of finding
particular orthogonal bases in an Euclidean vector space endowed with distinct
scalar products. An explicit two step Gram-Schmidt orthogonalization (G-SO)
procedure to determine these bases is given. By definition, the standard block
orthogonal (SBO) polynomials are associated with a choice of equal
to the subspace of polynomials of degree less than . We investigate their
properties, emphasizing similarities to and differences from the standard
orthogonal polynomials. Applications to classical orthogonal polynomials will
be given in forthcoming papers.Comment: This is a reduced version of the initial manuscript, the number of
pages being reduced from 34 to 2
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