921 research outputs found
Nucleus-Electron Model for States Changing from a Liquid Metal to a Plasma and the Saha Equation
We extend the quantal hypernetted-chain (QHNC) method, which has been proved
to yield accurate results for liquid metals, to treat a partially ionized
plasma. In a plasma, the electrons change from a quantum to a classical fluid
gradually with increasing temperature; the QHNC method applied to the electron
gas is in fact able to provide the electron-electron correlation at arbitrary
temperature. As an illustrating example of this approach, we investigate how
liquid rubidium becomes a plasma by increasing the temperature from 0 to 30 eV
at a fixed normal ion-density . The electron-ion
radial distribution function (RDF) in liquid Rb has distinct inner-core and
outer-core parts. Even at a temperature of 1 eV, this clear distinction remains
as a characteristic of a liquid metal. At a temperature of 3 eV, this
distinction disappears, and rubidium becomes a plasma with the ionization 1.21.
The temperature variations of bound levels in each ion and the average
ionization are calculated in Rb plasmas at the same time. Using the
density-functional theory, we also derive the Saha equation applicable even to
a high-density plasma at low temperatures. The QHNC method provides a procedure
to solve this Saha equation with ease by using a recursive formula; the charge
population of differently ionized species are obtained in Rb plasmas at several
temperatures. In this way, it is shown that, with the atomic number as the only
input, the QHNC method produces the average ionization, the electron-ion and
ion-ion RDF's, and the charge population which are consistent with the atomic
structure of each ion for a partially ionized plasma.Comment: 28 pages(TeX) and 11 figures (PS
Structure Factor and Electronic Structure of Compressed Liquid Rubidium
We have applied the quantal hypernetted-chain equations in combination with
the Rosenfeld bridge-functional to calculate the atomic and the electronic
structure of compressed liquid-rubidium under high pressure (0.2, 2.5, 3.9, and
6.1 GPa); the calculated structure factors are in good agreement with
experimental results measured by Tsuji et al. along the melting curve. We found
that the Rb-pseudoatom remains under these high pressures almost unchanged with
respect to the pseudoatom at room pressure; thus, the effective ion-ion
interaction is practically the same for all pressure-values. We observe that
all structure factors calculated for this pressure-variation coincide almost
into a single curve if wavenumbers are scaled in units of the Wigner-Seitz
radius although no corresponding scaling feature is observed in the
effective ion-ion interaction.This scaling property of the structure factors
signifies that the compression in liquid-rubidium is uniform with increasing
pressure; in absolute Q-values this means that the first peak-position ()
of the structure factor increases proportionally to ( being the
specific volume per ion), as was experimentally observed by Tsuji et al.Comment: 18 pages, 11 figure
Pressure formulas for liquid metals and plasmas based on the density-functional theory
At first, pressure formulas for the electrons under the external potential
produced by fixed nuclei are derived both in the surface integral and volume
integral forms concerning an arbitrary volume chosen in the system; the surface
integral form is described by a pressure tensor consisting of a sum of the
kinetic and exchange-correlation parts in the density-functional theory, and
the volume integral form represents the virial theorem with subtraction of the
nuclear virial. Secondly on the basis of these formulas, the thermodynamical
pressure of liquid metals and plasmas is represented in the forms of the
surface integral and the volume integral including the nuclear contribution.
From these results, we obtain a virial pressure formula for liquid metals,
which is more accurate and simpler than the standard representation. From the
view point of our formulation, some comments are made on pressure formulas
derived previously and on a definition of pressure widely used.Comment: 18 pages, no figur
Polynomial solutions of nonlinear integral equations
We analyze the polynomial solutions of a nonlinear integral equation,
generalizing the work of C. Bender and E. Ben-Naim. We show that, in some
cases, an orthogonal solution exists and we give its general form in terms of
kernel polynomials.Comment: 10 page
How to construct spin chains with perfect state transfer
It is shown how to systematically construct the quantum spin chains with
nearest-neighbor interactions that allow perfect state transfer (PST). Sets of
orthogonal polynomials (OPs) are in correspondence with such systems. The key
observation is that for any admissible one-excitation energy spectrum, the
weight function of the associated OPs is uniquely prescribed. This entails the
complete characterization of these PST models with the mirror symmetry property
arising as a corollary. A simple and efficient algorithm to obtain the
corresponding Hamiltonians is presented. A new model connected to a special
case of the symmetric -Racah polynomials is offered. It is also explained
how additional models with PST can be derived from a parent system by removing
energy levels from the one-excitation spectrum of the latter. This is achieved
through Christoffel transformations and is also completely constructive in
regards to the Hamiltonians.Comment: 7 page
Operator ordering in Two-dimensional N=1 supersymmetry with curved manifold
We investigate an operator ordering problem in two-dimensional N=1
supersymmetric model which consists of n real superfields. There arises an
operator ordering problem when the target space is curved. We have to fix the
ordering in quantum operator properly to obtain the correct supersymmetry
algebra. We demonstrate that the super-Poincar\'{e} algebra fixes the correct
operator ordering. We obtain a supercurrent with correct operator ordering and
a central extension of supersymmetry algebra.Comment: 7 page
Wigner quantization of some one-dimensional Hamiltonians
Recently, several papers have been dedicated to the Wigner quantization of
different Hamiltonians. In these examples, many interesting mathematical and
physical properties have been shown. Among those we have the ubiquitous
relation with Lie superalgebras and their representations. In this paper, we
study two one-dimensional Hamiltonians for which the Wigner quantization is
related with the orthosymplectic Lie superalgebra osp(1|2). One of them, the
Hamiltonian H = xp, is popular due to its connection with the Riemann zeros,
discovered by Berry and Keating on the one hand and Connes on the other. The
Hamiltonian of the free particle, H_f = p^2/2, is the second Hamiltonian we
will examine. Wigner quantization introduces an extra representation parameter
for both of these Hamiltonians. Canonical quantization is recovered by
restricting to a specific representation of the Lie superalgebra osp(1|2)
Probing Ion-Ion and Electron-Ion Correlations in Liquid Metals within the Quantum Hypernetted Chain Approximation
We use the Quantum Hypernetted Chain Approximation (QHNC) to calculate the
ion-ion and electron-ion correlations for liquid metallic Li, Be, Na, Mg, Al,
K, Ca, and Ga. We discuss trends in electron-ion structure factors and radial
distribution functions, and also calculate the free-atom and metallic-atom
form-factors, focusing on how bonding effects affect the interpretation of
X-ray scattering experiments, especially experimental measurements of the
ion-ion structure factor in the liquid metallic phase.Comment: RevTeX, 19 pages, 7 figure
Cosine and Sine Operators Related with Orthogonal Polynomial Sets on the Intervall [-1,1]
The quantization of phase is still an open problem. In the approach of
Susskind and Glogower so called cosine and sine operators play a fundamental
role. Their eigenstates in the Fock representation are related with the
Chebyshev polynomials of the second kind. Here we introduce more general cosine
and sine operators whose eigenfunctions in the Fock basis are related in a
similar way with arbitrary orthogonal polynomial sets on the intervall [-1,1].
To each polynomial set defined in terms of a weight function there corresponds
a pair of cosine and sine operators. Depending on the symmetry of the weight
function we distinguish generalized or extended operators. Their eigenstates
are used to define cosine and sine representations and probability
distributions. We consider also the inverse arccosine and arcsine operators and
use their eigenstates to define cosine-phase and sine-phase distributions,
respectively. Specific, numerical and graphical results are given for the
classical orthogonal polynomials and for particular Fock and coherent states.Comment: 1 tex-file (24 pages), 11 figure
The rotating Morse potential model for diatomic molecules in the tridiagonal J-matrix representation: I. Bound states
This is the first in a series of articles in which we study the rotating
Morse potential model for diatomic molecules in the tridiagonal J-matrix
representation. Here, we compute the bound states energy spectrum by
diagonalizing the finite dimensional Hamiltonian matrix of H2, LiH, HCl and CO
molecules for arbitrary angular momentum. The calculation was performed using
the J-matrix basis that supports a tridiagonal matrix representation for the
reference Hamiltonian. Our results for these diatomic molecules have been
compared with available numerical data satisfactorily. The proposed method is
handy, very efficient, and it enhances accuracy by combining analytic power
with a convergent and stable numerical technique.Comment: 18 Pages, 6 Tables, 4 Figure
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