26,531 research outputs found
Nonlinear Boundary Value Problems via Minimization on Orlicz-Sobolev Spaces
We develop arguments on convexity and minimization of energy functionals on
Orlicz-Sobolev spaces to investigate existence of solution to the equation
\displaystyle -\mbox{div} (\phi(|\nabla u|) \nabla u) = f(x,u) + h \mbox{in}
\Omega under Dirichlet boundary conditions, where
is a bounded smooth domain, is a
suitable continuous function and
satisfies the Carath\'eodory conditions, while is a measure.Comment: 14 page
Adsorption of two pesticides on a clay surface: a theoretical study
The contamination of water resources with many organic xenobiotic compounds poses a challenge to environmental sciences and technologies [1]. Although in many cases these contaminants are present only in small concentrations, the large variety of such compounds (some of which are classified as priority pollutants) is a matter of concern. Adsorption, alone or as part of a more complex water or wastewater treatment process, has been seen as playing a very important role in the removal of many of these pollutants [2]. In this regard, the choice of adsorbent materials is crucial, which requires an understanding of the details involved in the adsorption of more or less complex organic molecules by a variety of surfaces of different types. In addition to laboratory studies, computational studies may be valuable in this study [3].
MCPA (2-methyl-4-chlorophenoxyacetic acid, a herbicide) and Clofibric acid (2-(4-chlorophenoxy)-2-methylpropanoic, the metabolite of a pharmaceutical, clofibrate, and also a herbicide) are two phenoxy acids that differ only slightly in their structures. However, a quite distinct behavior in adsorption phenomena on clay materials has been observed in past studies [4]. By relating those differences with the molecules' structural features through atomistic computational studies, some insight may be gained into the respective adsorption processes of this type of compounds.
In the present work quantum chemical calculations at density functional theory level have been performed to study the adsorption of MCPA and Clofibric acid by a clay surface model. Since hydration plays an important role for the adsorption process of these species, solvent effects were considered by inclusion of water molecules explicitly into the quantum chemical calculations.
The deprotonated negatively charged species were found to strongly interact with the surface and the distinct behavior of both species upon adsorption was compared with experimental evidences
Testing Intra-Industry Trade Between Portugal and Spain [1990-1996]
This paper shows how, in the period 1990-1996, economic integration between the two Iberian economies has deepened through intra-industry trade. The enquiry was led at the level of the main forty traded products. In this context, several tests have been made. Our analysis combines first the application of the Grubel and Lloyd index of the main forty products and the marginal intra-industry trade of Brulhart, and Brulhart and Elliot. On the basis of these indexes we defined our criterion for the selection of the competitive cluster of Portugal throughout the period. We have also considered the global intra-industry trade, in nominal and real terms, according to the method of Greenaway et al. In econometric terms we have tried to know which is the relation between the intra-industry trade index and the marginal intra-industry trade at the level of the main forty products, the results however were not unequivocal. The same is true as far as concerns the relation between the intra-industry trade index and the net export position at the level of the same products. Despite the fact that some attempts have been inconclusive, knowledge about Iberian trade has developed in a field essential to its upgrading, and the way is open for further research.intra-industry trade; marginal intra-industry trade; competitive cluster; net export position.
Differential temporal beta‐diversity patterns of native and non‐native arthropod species in a fragmented native forest landscape
An important factor that hinders the management of non‐native species is a general lack of information regarding the biogeography of non‐natives, and, in particular, their rates of turnover. Here, we address this research gap by analysing differences in temporal beta‐diversity (using both pairwise and multiple‐time dissimilarity metrics) between native and non‐native species, using a novel time‐series dataset of arthropods sampled in native forest fragments in the Azores. We use a null model approach to determine whether temporal beta‐diversity was due to deterministic processes or stochastic colonisation and extinction events, and linear modelling selection to assess the factors driving variation in temporal beta‐diversity between plots. In accordance with our predictions, we found that the temporal beta‐diversity was much greater for non‐native species than for native species, and the null model analyses indicated that the turnover of non‐native species was due to stochastic events. No predictor variables were found to explain the turnover of native or non‐native species. We attribute the greater turnover of non‐native species to source‐sink processes and the close proximity of anthropogenic habitats to the fragmented native forest plots sampled in our study. Thus, our findings point to ways in which the study of turnover can be adapted for future applications in habitat island systems. The implications of this for biodiversity conservation and management are significant. The high rate of stochastic turnover of non‐native species indicates that attempts to simply reduce the populations of non‐native species in situ within native habitats may not be successful. A more efficient management strategy would be to interrupt source‐sink dynamics by improving the harsh boundaries between native and adjacent anthropogenic habitats.Portuguese FCT‐NETBIOME – ISLANDBIODIV grant 0003/2011.info:eu-repo/semantics/publishedVersio
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