Interface free energy or surface tension: definition and basic properties

Interface free energy is the contribution to the free energy of a system due to the presence of an interface separating two coexisting phases at equilibrium. It is also called surface tension. The content of the paper is 1) the definition of the interface free energy from first principles of statistical mechanics; 2) a detailed exposition of its basic properties. We consider lattice models with short range interactions, like the Ising model. A nice feature of lattice models is that the interface free energy is anisotropic so that some results are pertinent to the case of a crystal in equilibrium with its vapor. The results of section 2 hold in full generality.Comment: 20 pages, 2 figure

Non-Analyticity and the van der Waals Limit

We study the analyticity properties of the free energy f_\ga(m) of the Kac model at points of first order phase transition, in the van der Waals limit \ga\searrow 0. We show that there exists an inverse temperature $\beta_0$ and \ga_0>0 such that for all $\beta\geq \beta_0$ and for all \ga\in(0,\ga_0), f_\ga(m) has no analytic continuation along the path $m\searrow m^*$ ($m^*$ denotes spontaneous magnetization). The proof consists in studying high order derivatives of the pressure p_\ga(h), which is related to the free energy f_\ga(m) by a Legendre transform

The metaphysics of Machian frame-dragging

The paper investigates the kind of dependence relation that best portrays Machian frame-dragging in general relativity. The question is tricky because frame-dragging relates local inertial frames to distant distributions of matter in a time-independent way, thus establishing some sort of non-local link between the two. For this reason, a plain causal interpretation of frame-dragging faces huge challenges. The paper will shed light on the issue by using a generalized structural equation model analysis in terms of manipulationist counterfactuals recently applied in the context of metaphysical enquiry by Schaffer (2016) and Wilson (2017). The verdict of the analysis will be that frame-dragging is best understood in terms of a novel type of dependence relation that is half-way between causation and grounding

General approach for studying first-order phase transitions at low temperatures

By combining different ideas, a general and efficient protocol to deal with discontinuous phase transitions at low temperatures is proposed. For small $T$'s, it is possible to derive a generic analytic expression for appropriate order parameters, whose coefficients are obtained from simple simulations. Once in such regimes simulations by standard algorithms are not reliable, an enhanced tempering method, the parallel tempering -- accurate for small and intermediate system sizes with rather low computational cost -- is used. Finally, from finite size analysis, one can obtain the thermodynamic limit. The procedure is illustrated for four distinct models, demonstrating its power, e.g., to locate coexistence lines and the phases density at the coexistence.Comment: 5 page

Hydrological connectivity inferred from diatom transport through the riparian-stream system

Funding for this research was provided by the Luxembourg National Research Fund (FNR) in the framework of the BIGSTREAM (C09/SR/14), ECSTREAM (C12/SR/40/8854) and CAOS (INTER/DFG/11/01) projects. We are most grateful to the Administration des Services Techniques de l’Agriculture (ASTA) for providing meteorological data. We also acknowledge Delphine Collard for technical assistance in diatom sample treatment and preparation, François Barnich for the water chemistry analyses, and Jean-François Iffly, Christophe Hissler, Jérôme Juilleret, Laurent Gourdol and Julian Klaus for their constructive comments on the project and technical assistance in the field.Peer reviewedPublisher PD