6 research outputs found
UV continuum emission and diagnostics of hydrogen-containing non-equilibrium plasmas
For the first time the emission of the radiative dissociation continuum of
the hydrogen molecule ( electronic
transition) is proposed to be used as a source of information for the
spectroscopic diagnostics of non-equilibrium plasmas. The detailed analysis of
excitation-deactivation kinetics, rate constants of various collisional and
radiative transitions and fitting procedures made it possible to develop two
new methods of diagnostics of: (1) the ground state
vibrational temperature from the relative intensity
distribution, and (2) the rate of electron impact dissociation
(d[\mbox{H_{2}}]/dt)_{\text{diss}} from the absolute intensity of the
continuum. A known method of determination of from relative
intensities of Fulcher- bands was seriously corrected and simplified
due to the revision of transition probabilities and cross sections of
electron impact excitation. General considerations are illustrated
with examples of experiments in pure hydrogen capillary-arc and H+Ar
microwave discharges.Comment: REVTeX, 25 pages + 12 figures + 9 tables. Phys. Rev. E, eprint
replaced because of resubmission to journal after referee's 2nd repor
Observation of Fluorescence from Heavy Rare-gas Hydrides and Deuterides in Electron-Irradiated Matrices of Solid Hydrogen and Deuterium
The first detection of neutral heavy rare-gas hydrides and deuterides produced in a solid is reported. XeD, XeH, and KrD were generated in Xe and Kr-doped matrices of the solid hydrogens irradiated by 2-keV electrons. The fluorescence bands peak close to the wavelength value of the bound-free hydride transition in the gas phase
Denitrification in a Laurentian Great Lakes coastal wetland invaded by hybrid cattail (Typha Ă glauca)
Wetland ecosystems maintain and improve water quality through the process of denitrification, an increasingly important ecosystem service due to global N pollution. Invasive plants have the potential to disrupt denitrification by altering the environmental conditions that facilitate this process. Great Lakes coastal wetlands are experiencing widespread invasion by highly productive hybrid cattail with largely uncertain biogeochemical effects. Through field and controlled mesocosm studies, we sought to determine the effects of cattail invasion through time on denitrification rates and associated environmental factors in a Great Lakes coastal wetland. In the field, we found that cattail density correlated with increased denitrification and a suite of environmental and plant community characteristics and denitrification rates were positively correlated with NH4 +, sediment organic matter, reduced water levels, and cattail stand age. Through our controlled mesocosm study, we documented conditions 1- and 5-year following invasion and found that denitrification rates and soil organic matter increased in year 5, and cattail and year-since-invasion altered plant communities and soil NH4 +. Only a weak correlation between denitrification rates and cattail treatments was noted, however, owing to high replicate variability. Our results indicate that with increasing cattail residence time, one ecosystem service, biodiversity, was negatively impacted, while two other services, denitrification and sediment carbon accumulation, were enhanced. Thus, this highly invaded wetland still provides valuable services to aquatic ecosystems and to society. A holistic perspective is therefore critical when evaluating invasive species impacts in which negativeimpacts are weighed against other ecosystem services, which may be stimulated