The random phase approximation applied to ice

Standard density functionals without van der Waals interactions yield an unsatisfactory description of ice phases, specifically, high density phases occurring under pressure are too unstable compared to the common low density phase I$_h$ observed at ambient conditions. Although the description is improved by using functionals that include van der Waals interactions, the errors in relative volumes remain sizable. Here we assess the random phase approximation (RPA) for the correlation energy and compare our results to experimental data as well as diffusion Monte Carlo data for ice. The RPA yields a very balanced description for all considered phases, approaching the accuracy of diffusion Monte Carlo in relative energies and volumes. This opens a route towards a concise description of molecular water phases on surfaces and in cavities

Limit curve theorems in Lorentzian geometry

The subject of limit curve theorems in Lorentzian geometry is reviewed. A general limit curve theorem is formulated which includes the case of converging curves with endpoints and the case in which the limit points assigned since the beginning are one, two or at most denumerable. Some applications are considered. It is proved that in chronological spacetimes, strong causality is either everywhere verified or everywhere violated on maximizing lightlike segments with open domain. As a consequence, if in a chronological spacetime two distinct lightlike lines intersect each other then strong causality holds at their points. Finally, it is proved that two distinct components of the chronology violating set have disjoint closures or there is a lightlike line passing through each point of the intersection of the corresponding boundaries.Comment: 25 pages, 1 figure. v2: Misprints fixed, matches published versio

The Geometry of Warped Product Singularities

In this article the degenerate warped products of singular semi-Riemannian manifolds are studied. They were used recently by the author to handle singularities occurring in General Relativity, in black holes and at the big-bang. One main result presented here is that a degenerate warped product of semi-regular semi-Riemannian manifolds with the warping function satisfying a certain condition is a semi-regular semi-Riemannian manifold. The connection and the Riemann curvature of the warped product are expressed in terms of those of the factor manifolds. Examples of singular semi-Riemannian manifolds which are semi-regular are constructed as warped products. Applications include cosmological models and black holes solutions with semi-regular singularities. Such singularities are compatible with a certain reformulation of the Einstein equation, which in addition holds at semi-regular singularities too.Comment: 14 page

Effects of Corner Geometry and Adiabatic Extensions on Heat Transfer through a Differentially Heated Square Cavity

This study is concerned with heat transfer by natural convection in a differentially heated square cavity. The purpose is to explore numerically the effects of the corner geometry and adiabatic extensions on heat transfer through the sidewalls. Two sets of simulations have been carried out in this study. The first set is concerned with steady-state calculations with different corner shapes, and the second set considers both steady-state and transient heat transfer with adiabatic extensions of various dimensions. The numerical results are presented in this paper

Spinorial Characterizations of Surfaces into 3-dimensional pseudo-Riemannian Space Forms

We give a spinorial characterization of isometrically immersed surfaces of arbitrary signature into 3-dimensional pseudo-Riemannian space forms. For Lorentzian surfaces, this generalizes a recent work of the first author in $\mathbb{R}^{2,1}$ to other Lorentzian space forms. We also characterize immersions of Riemannian surfaces in these spaces. From this we can deduce analogous results for timelike immersions of Lorentzian surfaces in space forms of corresponding signature, as well as for spacelike and timelike immersions of surfaces of signature (0,2), hence achieving a complete spinorial description for this class of pseudo-Riemannian immersions.Comment: 9 page

Painleve-Gullstrand Coordinates for the Kerr Solution

We construct a coordinate system for the Kerr solution, based on the zero angular momentum observers dropped from infinity, which generalizes the Painleve-Gullstrand coordinate system for the Schwarzschild solution. The Kerr metric can then be interpreted as describing space flowing on a (curved) Riemannian 3-manifold. The stationary limit arises as the set of points on this manifold where the speed of the flow equals the speed of light, and the horizons as the set of points where the radial speed equals the speed of light. A deeper analysis of what is meant by the flow of space reveals that the acceleration of free-falling objects is generally not in the direction of this flow. Finally, we compare the new coordinate system with the closely related Doran coordinate system.Comment: 6 pages; v2: new section, matches final published version; v3: sign error in the expression of the function delta correcte

Synchrotron radiation study of the relation between structure and strain in polyurethane elastomers

This paper describes a system for the study of the relation between structure and applied strain in thermoplastic polyurethane elastomers using the Australian National Beamline Facility at the Photon Factory, KEK, Tsukuba, Japan. The system uses the sagittal focusing monochromator at beamline 20B to provide a high-intensity focused beam which then falls on the specimen mounted in a miniature tensometer mounted in the unique vacuum diffractometer (BIGDIFF). Imaging plates were used to record simultaneously SAXS and WAXS patterns from the specimen at a particular strain. The change in SAXS and WAXS patterns with loading and unloading was recorded using a ten-plate imaging-plate changer