Role of interband scattering in neutron irradiated MgB2_2 thin films by Scanning Tunneling Spectroscopy measurements

A series of MgB$_2$ thin films systematically disordered by neutron irradiation have been studied by Scanning Tunneling Spectroscopy. The c-axis orientation of the films allowed a reliable determination of local density of state of the $\pi$ band. With increasing disorder, the conductance peak moves towards higher voltages and becomes lower and broader, indicating a monotonic increase of the $\pi$ gap and of the broadening parameter. These results are discussed in the frame of two-band superconductivity.Comment: The text will be submitted in Latex format, and the corresponding pdf file should take 6 pages. There are 5 figures (eps files submitted) and 1 tabl

High quality MgB2 thin films in-situ grown by dc magnetron sputtering

Thin films of the recently discovered magnesium diboride (MgB2) intermetalic superconducting compound have been grown using a magnetron sputtering deposition technique followed by in-situ annealing at 830 C. High quality films were obtained on both sapphire and MgO substrates. The best films showed maximum Tc = 35 K (onset), a transition width of 0.5 K, a residual resistivity ratio up to 1.6, a low temperature critical current density Jc > 1 MA/cm2 and anisotropic critical field with gamma = 2.5 close to the values obtained for single crystals. The preparation technique can be easily scaled to produce large area in-situ films.Comment: 7 pages, 4 figure

Revised seismic classification of the ITACA stations, according to the EC8 and the Italian norms site classes

The activities carried out within Task 2 aim to collect, organize and synthesize geological, geomorphological, geotechnical and geophysical data for the location site of the Accelerometric National Network (RAN) stations in Italy, managed by the Department of Civil Protection, to improve the knowledge about the subsoil (see Delverable D05) and to permit a subsoil and topographic site classification based on EC8 categories. At the end of the project the subsoil of 695 stations have been classified using an hybrid approch, based on surface geology, spectral classification and Vs profils from different recording tecniques (DH, CH, MASW, ESAC). These activities have been useful to link the ITACA database with the software REXEL to select natural accelerograms, compatible with Norme Tecniche per le Costruzioni (NTC2008) and EUROCODE 8 (EC8) spectra, which may also reflect characteristics of the source in terms of magnitude and epicentral distance. For 688 station sites have been provided also a topographic classification using a GIS based semiautomatic method with “by-hand” corrections using topographic maps and/or Google Earth software. A Microsoft Excel Database which also allows to track all changes that have been made since the beginning of the project related to the site classification has been developed

A new generation photodetector for astroparticle physics: the VSiPMT

The VSiPMT (Vacuum Silicon PhotoMultiplier Tube) is an innovative design we proposed for a revolutionary photon detector. The main idea is to replace the classical dynode chain of a PMT with a SiPM (G-APD), the latter acting as an electron detector and amplifier. The aim is to match the large sensitive area of a photocathode with the performance of the SiPM technology. The VSiPMT has many attractive features. In particular, a low power consumption and an excellent photon counting capability. To prove the feasibility of the idea we first tested the performance of a special non-windowed SiPM by Hamamatsu (MPPC) as electron detector and current amplifier. Thanks to this result Hamamatsu realized two VSiPMT industrial prototypes. In this work, we present the results of a full characterization of the VSiPMT prototype

Scanning Tunneling Spectroscopy study of paramagnetic superconducting β’’-ET4[(H3O)Fe(C2O4)3]•C6H5Br crystals

Scanning tunnelling spectroscopy (STS) and microscopy (STM) were performed on the paramagnetic molecular superconductor beta''-ET4[(H3O)Fe(C2O4)(3)]C6H5Br. Under ambient pressure, this compound is located near the boundary separating superconducting and insulating phases of the phase diagram. In spite of a strongly reduced critical temperature T-c (T-c = 4.0 K at the onset, zero resistance at T-c = 0.5 K), the low temperature STS spectra taken in the superconducting regions show strong similarities with the higher T-c ET kappa-derivatives series. We exploited different models for the density of states (DOS), with conventional and unconventional order parameters to take into account the role played by possible magnetic and non-magnetic disorder in the superconducting order parameter. The values of the superconducting order parameter obtained by the fitting procedure are close to the ones obtained on more metallic and higher T-c organic crystals and far above the BCS values, suggesting an intrinsic role of disorder in the superconductivity of organic superconductors and a further confirmation of the non-conventional superconductivity in such compounds

New piperazine and morpholine derivatives: Mass spectrometry characterization and evaluation of their antimicrobial activity

: Recently, pharmaceutical research has been focused on the design of new antibacterial drugs with higher selectivity towards several strains. Major issues concern the possibility to obtain compounds with fewer side effects, at the same time effectively overcoming the problem of antimicrobial resistance. Several solutions include the synthesis of new pharmacophores starting from piperazine or morpholine core units. Mass spectrometry-based techniques offer important support for the structural characterization of newly synthesized compounds to design safer and more effective drugs for various medical conditions. Here, two new piperazine derivatives and four new morpholine derivatives were synthesized and structurally characterized through a combined approach of Fourier transform-ion cyclotron resonance (FT-ICR) and Linear Trap Quadrupole (LTQ) mass spectrometry. The support of both high-resolution and low-resolution mass spectrometric data namely accurate mass measurements, isotopic distribution and MSn spectra, was crucial to confirm the success of the synthesis. These compounds were further evaluated for inhibitory activity against a total of twenty-nine Gram-positive and Gram-negative bacteria to determine the action spectrum and the antimicrobial effectiveness. Results demonstrated compounds' antimicrobial activity against many tested bacterial species, providing an inhibitory effect linked to different chemical structure and suggesting that the new-synthesized derivatives could be considered as promising antimicrobial agents

Symmetry breaking at the (111) interfaces of SrTiO3{_3} hosting a 2D-electron system

We used x-ray absorption spectroscopy to study the orbital symmetry and the energy band splitting of (111) LaAlO${_3}$/SrTiO${_3}$ and LaAlO${_3}$/EuTiO${_3}$/SrTiO${_3}$ heterostructures, hosting a quasi two-dimensional electron system (q2DES), and of a Ti-terminated (111) SrTiO${_3}$ single crystal, also known to form a q2DES at its surface. We demonstrate that the bulk tetragonal Ti-3d D${_4}$${_h}$ crystal field is turned into trigonal D${_3}$${_d}$ crystal field in all cases. The symmetry adapted a${_1}$${_g}$ and e${^\pi_g}$ orbitals are non-degenerate in energy and their splitting, \Delta, is positive at the bare STO surface but negative in the heterostructures, where the a${_1}$${_g}$ orbital is lowest in energy. These results demonstrate that the interfacial symmetry breaking induced by epitaxial engineering of oxide interfaces has a dramatic effect on their electronic properties, and it can be used to manipulate the ground state of the q2DES.Comment: 6 pages article, plus 5 pages supplementary informatio

The VSiPMT project

Photon detection is a key factor to study many physical processes in several areas of fundamental physics research. Focusing the attention on photodetectors for particle astrophysics, the future experiments aimed at the study of very high-energy or extremely rare phenomena (e.g. dark matter, proton decay, neutrinos from astrophysical sources) will require additional improvements in linearity, gain, quantum efficiency and single photon counting capability. To meet the requirements of this class of experiments, we propose a new design for a modern hybrid photodetector: the VSiPMT (Vacuum Silicon PhotoMultiplier Tube). The idea is to replace the classical dynode chain of a PMT with a SiPM, which therefore acts as an electron detector and amplifier. The aim is to match the large sensitive area of a photocathode with the performances of the SiPM technology. We now present the preliminary study we are performing to realize a 3-inches VSiPMT prototype

Nanoscale modulation of the density of states at the conducting interface between LaAlO3 and SrTiO3 band insulators

The appearance of high-mobility electrons at the LaAlO3/SrTiO3 interface has raised strong interest in the material science community and a lively debate on the origin of the phenomenon. A possible explanation is an electronic reconstruction, realizing a transfer of electrons to SrTiO3 at the interface, thereby avoiding the build-up of excessive Coulomb energy as described by the "polarization catastrophe" associated with the alternating polar layers of the LaAlO3 film. Theoretical models predict that electrons are transferred into titanium 3d(xy) interface states and, in the presence of strong correlations, generate a charge and orbital order. Here we provide experimental evidence that at room temperature the local density of states of the LaAlO3/SrTiO3 conducting interface is modulated at the nanoscale in a short-range quasiperiodic pattern, which is consistent with the appearance of an orbital (short-range) order. This result, together with the splitting of the 3d states, confirms that an electronic reconstruction drives the functional properties of the LaAlO3/SrTiO3 oxide interface. The short-range superstructure does not fully agree with the theoretical predictions. Thus, further experimental and theoretical investigations are required to understand the electronic properties of the 2D electron system realised at the LaAlO3/SrTiO3 interface

Observation of a two-dimensional electron gas at the surface of annealed SrTiO3 single crystals by scanning tunneling spectroscopy

Scanning tunneling spectroscopy suggests the formation of a two dimensional electron gas (2DEG) on the TiO2 terminated surface of undoped SrTiO3 single crystals annealed at temperature lower than 400 {\deg}C in ultra high vacuum conditions. Low energy electron diffraction indicates that the 2D metallic SrTiO3 surface is not structurally reconstructed, suggesting that non-ordered oxygen vacancies created in the annealing process introduce carriers leading to an electronic reconstruction. The experimental results are interpreted in a frame of competition between oxygen diffusion from the bulk to the surface and oxygen loss from the surface itself.Comment: 9 pages, 3 figures, submitted to Physical Review