Design and optimization of electrochemical microreactors for continuous electrosynthesis

The study focuses on the design and construction, as well as the theoretical and experimental optimization of electrochemical filter press microreactors for the electrosynthesis of molecules with a high added value. The main characteristics of these devices are firstly a high-specific electrochemical area to increase conversion and selectivity, and secondly the shape and size of themicrochannels designed for a uniform residence time distribution of the fluid. A heat exchanger is integrated into the microstructured electrode to rapidly remove (or supply) the heat required in exo- or endothermic reactions. The microreactors designed are used to perform-specific electrosynthesis reactions such as thermodynamically unfavorable reactions (continuous NADH regeneration), or reactions with high enthalpy changes

Primordial Black Hole Formation during First-Order Phase Transitions

Primordial black holes (PBHs) may form in the early universe when pre-existing adiabatic density fluctuations enter into the cosmological horizon and recollapse. It has been suggested that PBH formation may be facilitated when fluctuations enter into the horizon during a strongly first-order phase transition which proceeds in approximate equilibrium. We employ general-relativistic hydrodynamics numerical simulations in order to follow the collapse of density fluctuations during first-order phase transitions. We find that during late stages of the collapse fluctuations separate into two regimes, an inner part existing exclusively in the high-energy density phase with energy density $\epsilon_{\rm h}$, surrounded by an outer part which exists exclusively in the low-energy density phase with energy density $\epsilon_{\rm h}-L$, where $L$ is the latent heat of the transition. We confirm that the fluctuation density threshold $\delta\epsilon /\epsilon$ required for the formation of PBHs during first-order transitions decreases with increasing $L$ and falls below that for PBH formation during ordinary radiation dominated epochs. Our results imply that, in case PBHs form at all in the early universe, their mass spectrum is likely dominated by the approximate horizon masses during epochs when the universe undergoes phase transitions.Comment: 8 pages, 4 figures, revtex style, submitted to PR

First Astronomical Use of Multiplexed Transition Edge Bolometers

We present performance results based on the first astronomical use of multiplexed superconducting bolometers. The Fabry-Perot Interferometer Bolometer Research Experiment (FIBRE) is a broadband submillimeter spectrometer that achieved first light in June 2001 at the Caltech Submillimeter Observatory (CSO). FIBRE'S detectors are superconducting transition edge sensor (TES) bolometers read out by a SQUID multiplexer. The Fabry-Perot uses a low resolution grating to order sort the incoming light. A linear bolometer array consisting of 16 elements detects this dispersed light, capturing 5 orders simultaneously from one position on the sky. With tuning of the Fabry-Perot over one free spectral range, a spectrum covering Δλ/λ= 1/7 at a resolution of δλ/λ ≈ 1/1200 can be acquired. This spectral resolution is sufficient to resolve Doppler-broadened line emission from external galaxies. FIBRE operates in the 350 µm and 450 µm bands. These bands cover line emission from the important star formation tracers neutral carbon [Cl] and carbon monoxide (CO). We have verified that the multiplexed bolometers are photon noise limited even with the low power present in moderate resolution spectrometry

Wind-Current Feedback Is an Energy Sink For Oceanic Internal Waves

Internal waves contain a large amount of energy in the ocean and are an important source of turbulent mixing. Ocean mixing is relevant for climate because it drives vertical transport of water, heat, carbon and other tracers. Understanding the life cycle of internal waves, from generation to dissipation, is therefore important for improving the representation of ocean mixing in climate models. Here, we provide evidence from a regional realistic numerical simulation in the northeastern Pacific that the wind can play an important role in damping internal waves through current feedback. This results in a reduction of 67% of wind power input at near-inertial frequencies in the region of study. Wind-current feedback also provides a net energy sink for internal tides, removing energy at a rate of 0.2 mW/m2 on average, corresponding to 8% of the local internal tide generation at the Mendocino ridge. The temporal variability and modal distribution of this energy sink are also investigated

Remote Internal Wave Forcing of Regional Ocean Simulations Near the U.S. West Coast

Low mode internal waves are able to propagate across ocean basins and modulate ocean dynamics thousands of kilometers away from their generation sites. In this study, the impact of remotely generated internal waves on the internal wave energetics near the U.S. West Coast is investigated with realistically forced regional ocean simulations. At the open boundaries, we impose high-frequency oceanic state variables obtained from a global ocean simulation with realistic atmospheric and astronomical tidal forcing. We use the Discrete Fourier Transform (DFT) technique in separating ingoing and outgoing internal tide energy fluxes at the open boundaries in order to quantify internal tide reflections. Although internal tide reflections are reduced with increasing sponge viscosity and/or sponge layer width, reflection coefficients (λ) can be as high as 73%. In the presence of remote internal waves, the model variance and spatial correlations become more in agreement with both mooring and altimetry datasets. The results confirm that an improved internal wave continuum can be achieved in regional models with remote internal wave forcing at the open boundaries. However, care should be taken to avoid excessive reflections of internal waves from the interior at these boundaries

Discovery and Characterization of a Caustic Crossing Microlensing Event in the SMC

We present photometric observations and analysis of the second microlensing event detected towards the Small Magellanic Cloud (SMC), MACHO Alert 98-SMC-1. This event was detected early enough to allow intensive observation of the lightcurve. These observations revealed 98-SMC-1 to be the first caustic crossing, binary microlensing event towards the Magellanic Clouds to be discovered in progress. Frequent coverage of the evolving lightcurve allowed an accurate prediction for the date of the source crossing out of the lens caustic structure. The caustic crossing temporal width, along with the angular size of the source star, measures the proper motion of the lens with respect to the source, and thus allows an estimate of the location of the lens. Lenses located in the Galactic halo would have a velocity projected to the SMC of v^hat ~1500 km/s, while an SMC lens would typically have v^hat ~60 km/s. We have performed a joint fit to the MACHO/GMAN data presented here, including recent EROS data of this event. These joint data are sufficient to constrain the time for the lens to move an angle equal to the source angular radius; 0.116 +/- 0.010 days. We estimate a radius for the lensed source of 1.4 +/- 0.1 R_sun. This yields a projected velocity of v^hat = 84 +/- 9 km/s. Only 0.15% of halo lenses would be expected to have a v^hat value at least as small as this, while 31% of SMC lenses would be expected to have v^hat as large as this. This implies that the lensing system is more likely to reside in the SMC than in the Galactic halo.Comment: 16 pages, including 3 tables and 3 figures; submitted to The Astrophysical Journa

The MACHO Project: Microlensing Results from 5.7 Years of LMC Observations

We report on our search for microlensing towards the Large Magellanic Cloud (LMC). Analysis of 5.7 years of photometry on 11.9 million stars in the LMC reveals 13 - 17 microlensing events. This is significantly more than the $\sim$ 2 to 4 events expected from lensing by known stellar populations. The timescales (\that) of the events range from 34 to 230 days. We estimate the microlensing optical depth towards the LMC from events with 2 < \that < 400 days to be 1.2 ^{+0.4}_ {-0.3} \ten{-7}$, with an additional 20systematic error. The spatial distribution of events is mildly inconsistent with LMC/LMC disk self-lensing, but is consistent with an extended lens distribution such as a Milky Way or LMC halo. Interpreted in the context of a Galactic dark matter halo, consisting partially of compact objects, a maximum likelihood analysis gives a MACHO halo fraction of 20with a 95the 95Galactic halo population, the most likely MACHO mass is between$ 0.15 \msun$and$ 0.9 \msun$, depending on the halo model, and the total mass in MACHOs out to 50 kpc is found to be 9+4-3 10^{10} msun, independent of the halo model. These results are marginally consistent with our previous results, but are lower by about a factor of two. Besides a larger data set, this work also includes an improved efficiency determination, improved likelihood analysis, and more thorough testing of systematic errors, especially with respect to the treatment of potential backgrounds to microlensing, such as supernovae in galaxies behind the LMC. [Abridged]Comment: 53 pages, Latex with 12 postscript figures, submitted to Ap

Probing Red Giant Atmospheres with Gravitational Microlensing

Gravitational microlensing provides a new technique for studying the surfaces of distant stars. Microlensing events are detected in real time and can be followed up with precision photometry and spectroscopy. This method is particularly adequate for studying red giants in the Galactic bulge. Recently we developed an efficient method capable of computing the lensing effect for thousands of frequencies in a high-resolution stellar spectrum. Here we demonstrate the effects of microlensing on synthesized optical spectra of red giant model atmospheres. We show that different properties of the stellar surface can be recovered from time-dependent photometry and spectroscopy of a point-mass microlensing event with a small impact parameter. In this study we concentrate on center-to-limb variation of spectral features. Measuring such variations can reveal the depth structure of the atmosphere of the source star.Comment: 23 pages with 11 Postscript figures, submitted to ApJ; Section 2 expanded, references added, text revise

Very High Energy Gamma-ray spectral properties of Mrk 501 from CAT Cerenkov telescope observations in 1997

The BL Lac object Mrk 501 went into a very high state of activity during 1997, both in VHE gamma-rays and X-rays. We present here results from observations at energies above 250 GeV carried out between March and October 1997 with the CAT Cerenkov imaging Telescope. The average differential spectrum between 30 GeV and 13 TeV shows significant curvature and is well represented by phi_0 * E_TeV^{-(alpha + beta*log10(E_TeV))}, with: phi_0 = 5.19 +/- 0.13 {stat} +/- 0.12 {sys-MC} +1.66/-1.04 {sys-atm} * 10^-11 /cm^2/s/TeV alpha = 2.24 +/- 0.04 {stat} +/- 0.05 {sys} beta = 0.50 +/- 0.07 {stat} (negligible systematics). The TeV spectral energy distribution of Mrk 501 clearly peaks in the range 500 GeV-1 TeV. Investigation of spectral variations shows a significant hardness-intensity correlation with no measurable effect on the curvature. This can be described as an increase of the peak TeV emission energy with intensity. Simultaneous and quasi-simultaneous CAT VHE gamma-ray and BeppoSAX hard X-ray detections for the highest recorded flare on 16th April and for lower-activity states of the same period show correlated variability with a higher luminosity in X-rays than in gamma-rays. The observed spectral energy distribution and the correlated variability between X-rays and gamma-rays, both in amplitude and in hardening of spectra, favour a two-component emission scheme where the low and high energy components are attributed to synchrotron and inverse Compton (IC) radiation, respectively.Comment: Submitted to Astronomy and Astrophysics, 8 pages including 6 figures. Published with minor change