Humidity resistant solar cell contacts

Gold-platinum solar cell contact is developed which does not exhibit chemical reactivity of titanium or porosity of silver. This contact offers excellent ohmic characteristics and stability in humid air

Anisotropic Sliding Dynamics, Peak Effect, and Metastability in Stripe Systems

A variety of soft and hard condensed matter systems are known to form stripe patterns. Here we use numerical simulations to analyze how such stripe states depin and slide when interacting with a random substrate and with driving in different directions with respect to the orientation of the stripes. Depending on the strength and density of the substrate disorder, we find that there can be pronounced anisotropy in the transport produced by different dynamical flow phases. We also find a disorder-induced "peak effect" similar to that observed for superconducting vortex systems, which is marked by a transition from elastic depinning to a state where the stripe structure fragments or partially disorders at depinning. Under the sudden application of a driving force, we observe pronounced metastability effects similar to those found near the order-disorder transition associated with the peak effect regime for three-dimensional superconducting vortices. The characteristic transient time required for the system to reach a steady state diverges in the region where the flow changes from elastic to disordered. We also find that anisotropy of the flow persists in the presence of thermal disorder when thermally-induced particle hopping along the stripes dominates. The thermal effects can wash out the effects of the quenched disorder, leading to a thermally-induced stripe state. We map out the dynamical phase diagram for this system, and discuss how our results could be explored in electron liquid crystal systems, type-1.5 superconductors, and pattern-forming colloidal assemblies.Comment: 18 pages, 22 postscript figure

High-Order Coupled Cluster Method Calculations for the Ground- and Excited-State Properties of the Spin-Half XXZ Model

In this article, we present new results of high-order coupled cluster method (CCM) calculations, based on a N\'eel model state with spins aligned in the $z$-direction, for both the ground- and excited-state properties of the spin-half {\it XXZ} model on the linear chain, the square lattice, and the simple cubic lattice. In particular, the high-order CCM formalism is extended to treat the excited states of lattice quantum spin systems for the first time. Completely new results for the excitation energy gap of the spin-half {\it XXZ} model for these lattices are thus determined. These high-order calculations are based on a localised approximation scheme called the LSUB$m$ scheme in which we retain all $k$-body correlations defined on all possible locales of $m$ adjacent lattice sites ($k \le m$). The ``raw'' CCM LSUB$m$ results are seen to provide very good results for the ground-state energy, sublattice magnetisation, and the value of the lowest-lying excitation energy for each of these systems. However, in order to obtain even better results, two types of extrapolation scheme of the LSUB$m$ results to the limit $m \to \infty$ (i.e., the exact solution in the thermodynamic limit) are presented. The extrapolated results provide extremely accurate results for the ground- and excited-state properties of these systems across a wide range of values of the anisotropy parameter.Comment: 31 Pages, 5 Figure

Structural Transitions, Melting, and Intermediate Phases for Stripe and Clump Forming Systems

We numerically examine the properties of a two-dimensional system of particles which have competing long range repulsive and short range attractive interactions as a function of density and temperature. For increasing density, there are well defined transitions between a low density clump phase, an intermediate stripe phase, an anticlump phase, and a high density uniform phase. To characterize the transitions between these phases we propose several measures which take into account the different length scales in the system. For increasing temperature, we find an intermediate phase that is liquid-like on the short length scale of interparticle spacing but solid-like on the larger length scale of the clump, stripe, or anticlump pattern. This intermediate phase persists over the widest temperature range in the stripe state when the local particle lattice within an individual stripe melts well below the temperature at which the entire stripe structure breaks down, and is characterized by intra-stripe diffusion of particles without inter-stripe diffusion. This is followed at higher temperatures by the onset of inter-stripe diffusion in an anisotropic diffusion phase, and then by breakup of the stripe structure. We identify the transitions between these regimes through diffusion, specific heat, and energy fluctuation measurements, and find that within the intra-stripe liquid regime, the excess entropy goes into disordering the particle arrangements within the stripe rather than affecting the stripe structure itself. The clump and anticlump phases also show multiple temperature-induced diffusive regimes which are not as pronounced as those of the stripe phase.Comment: 13 pages, 17 postscript figure

SENSITIVITY TO SCOPE: EVIDENCE FROM A CVM STUDY OF WETLANDS

Wetlands valuation is a situation in which CVM studies might be expected to fail scope tests. This paper reports results from a split-sample CVM study of Wisconsin wetlands. The survey employed a multiple-bounded, polychotomous-choice format, and compared WTP distributions using the method of convolutions. The survey demonstrated sensitivity to scope.Resource /Energy Economics and Policy,

Resonances, Unstable Systems and Irreversibility: Matter Meets Mind

The fundamental time-reversal invariance of dynamical systems can be broken in various ways. One way is based on the presence of resonances and their interactions giving rise to unstable dynamical systems, leading to well-defined time arrows. Associated with these time arrows are semigroups bearing time orientations. Usually, when time symmetry is broken, two time-oriented semigroups result, one directed toward the future and one directed toward the past. If time-reversed states and evolutions are excluded due to resonances, then the status of these states and their associated backwards-in-time oriented semigroups is open to question. One possible role for these latter states and semigroups is as an abstract representation of mental systems as opposed to material systems. The beginnings of this interpretation will be sketched.Comment: 9 pages. Presented at the CFIF Workshop on TimeAsymmetric Quantum Theory: The Theory of Resonances, 23-26 July 2003, Instituto Superior Tecnico, Lisbon, Portugal; and at the Quantum Structures Association Meeting, 7-22 July 2004, University of Denver. Accepted for publication in the Internation Journal of Theoretical Physic

A new method for the determination of thin film porosity

Internal reflection spectroscopy may be used to determine presence of water in thin film pores. Presence of water in such pores is function of relative humidity and pore size. Thus, one can determine pore size by controlling humidity. Fluids with surface tension different from that of water can be used to detect pores

Phase Transitions in the Spin-Half J_1--J_2 Model

The coupled cluster method (CCM) is a well-known method of quantum many-body theory, and here we present an application of the CCM to the spin-half J_1--J_2 quantum spin model with nearest- and next-nearest-neighbour interactions on the linear chain and the square lattice. We present new results for ground-state expectation values of such quantities as the energy and the sublattice magnetisation. The presence of critical points in the solution of the CCM equations, which are associated with phase transitions in the real system, is investigated. Completely distinct from the investigation of the critical points, we also make a link between the expansion coefficients of the ground-state wave function in terms of an Ising basis and the CCM ket-state correlation coefficients. We are thus able to present evidence of the breakdown, at a given value of J_2/J_1, of the Marshall-Peierls sign rule which is known to be satisfied at the pure Heisenberg point (J_2 = 0) on any bipartite lattice. For the square lattice, our best estimates of the points at which the sign rule breaks down and at which the phase transition from the antiferromagnetic phase to the frustrated phase occurs are, respectively, given (to two decimal places) by J_2/J_1 = 0.26 and J_2/J_1 = 0.61.Comment: 28 pages, Latex, 2 postscript figure