10 research outputs found
Macroporous MnO2 electrodes obtained by template assisted electrodeposition for electrochemical capacitors
Macroporous MnO2 electrodes prepared by template-assisted electrodeposition using spherical polystyrene colloidal particles are studied. The wettability of such electrodes by a LiClO4 aqueous electrolyte is measured by the contact angle technique. Cyclic voltammetry experiments are performed in order to evaluate the use of these electrodes for electrochemical capacitor applications. The specific capacity obtained is about 60% higher than that obtained for flat MnO2 surfaces showing that, in spite of the wettability being lower, some penetration of the electrolyte into the pores must occur, increasing the electroactive area with respect to the flat electrode. Furthermore, the macroporous electrode showed excellent electrochemical stability, with neither a capacitance decrease nor a loss of morphology, after 1000 cycles
Ellipsometric, Electrogravimetric, and Spectroelectrochemical Studies of the Redox Process of Sulfonated Polyaniline
Influence of Thermal Treatment on Doped Polyaniline Studied by Resonance Raman Spectroscopy
Comparison of Secondary Doping and Thermal Treatment in Poly(diphenylamine) and Polyaniline Monitored by Resonance Raman Spectroscopy
Kinetic and Thermodynamic Studies on the Adsorption of Reactive Red 239 by Carra Sawdust Treated with Formaldehyde
Platinum nanoparticle-modified electrodes, morphologic, and electrochemical studies concerning electroactive materials deposition
The present work describes the synthesis of platinum nanoparticles followed by their electrophoretic deposition onto transparent fluorine-doped tin oxide electrodes. The nano-Pt-modified electrodes were characterized by voltammetric studies in acidic solutions showing a great electrocatalytic behavior towards H+ reduction being very interesting for fuel cell applications. Morphological characterization was performed by atomic force microscopy on different modified electrodes showing a very rough surface which can be tuned by means of time of deposition. Also, nickel hydroxide thin films were galvanostatically grown onto these electrodes showing an interesting electrochemical behavior as sharper peaks, indicating a faster ionic exchange from the electrolyte to the film