Data interpretation in forensic sediment and soil geochemistry

Automated geochemical techniques enable reproducible elemental assays of small quantity samples and have been used in recent years in many forensic criminal investigations in England and Wales. Two case studies are presented that highlight the problems of testing the presence of pre-, syn-, or post-crime event sample mixing. The number of elements or compounds analyzed can have a bearing on statistical discriminant techniques that may provide false-positive or false-negative associations or exclusions. Chemical analyses of soils and sediments using both atomic absorption spectrometry and Dionex (DX500 Sunnyvale, CA, USA), and inductively coupled plasma mass spectrometry enabled the identification and classification of discrete groups by hierarchical cluster analysis and canonical discriminant function analysis. These groupings, however, prove fragile to small variations within samples of even the most common minerals. Copyright © Taylor & Francis Group, LLC

The philosophy, nature and practice of forensic sediment analysis

The rapidly expanding field of forensic geoscience derives its roots from nineteenth-and early twentieth-century scientists who both influence and are influenced by literature and fictional writing. Forensic geoscience borrows much, but not all, of its precepts from geological and geomorphological analytical techniques. Fundamental differences exist between forensic geoscience and its sister disciplines, fundamental enough to make the unwary geoscientist succumb to philosophical and practical pitfalls which will not only endanger the outline of their report, but may well indeed provide false-negative or false-positive results leading to contrary or inaccurate conclusions. In the law, such outcomes have devastating and untenable consequences. Forensic geoscience requires techniques of exclusion rather than inclusion and an acknowledgement that analytical techniques may be diagnostic only in very specific situations. Whether analysis of the ubiquitous or the exotic component is chosen, acknowledgement of the need for samples to be representative is required. The presentation of false-positive results or the lack of identification of sample 'mixing' is prerequisite to the application of statistical tests which must be applied in the most careful manner. The realization of the limitations of the technique requires, wherever possible, conjunctive analysis by other truly independent techniques. While personal opinion derives from experience, there is no place for assumption. Research papers in forensic geoscience are not submitted to be speculative or challenging as may be the case in many fields of geomorphology and geology. There is no place for conjecture in forensic geoscience. © 2007 SAGE Publications

The use of grain size distribution analysis of sediments and soils in forensic enquiry

The use of grain size distribution analysis in forensic enquiry was investigated with reference to four forensic case studies which contained the type of sample restraints and limitations often encountered in criminal case work. The problems of the comparison of trace and bulk samples are outlined and the need for multiple sample analysis is highlighted. It was found that the problems of soil analysis, particularly when the soil was recovered from anthropogenic sources, focused on the lack of identification of pre-, syn- and post-forensic event mixing of materials, thus obscuring the recognition of false-negative or false-positive exclusions between samples. It was found that grain size distribution analysis was a useful descriptive tool but it was concluded that if it were to be used in any other manner the derived results should be treated with great caution. The statistical analyses of these data did not improve the quality of the interpretation of the results

The forensic analysis of soils and sediment taken from the cast of a footprint

The routine production of a cast of a shoe-print taken in soil provides information other than shoe size and gait. Material adhering to the surface of the cast represents the preservation of the moment of footprint impression. The analysis of the interface between the cast and soil is therefore a potentially lucrative source of information for forensic reconstruction. These principles are demonstrated with reference to a murder case which took place in the English Midlands. The cast of a footprint provided evidence of a two-way transfer of material between the sole of a boot and the soil of a recently ploughed field. Lumps of soil, which had dried on a boot, were deposited on the field as the footprints were made. Pollen analysis of these lumps of soil indicated that the perpetrator of the imprint had been standing recently in a nearby stream. Fibre analysis together with physical and chemical characteristics of the soil suggested a provenance for contamination of this mud prior to deposition of the footprint. Carbon/nitrogen ratios of the water taken from the cast showed that distilled water had been used thus excluding the possibility of contamination of the boot–soil interface. It was possible to reconstruct three phases of previous activity of the wearer of the boot prior to leaving the footprint in the field after the murder had taken place. This analysis shows the power of integrating different independent techniques in the analysis of hitherto unrecognised forensic materials

The role of forensic geoscience in wildlife crime detection

The increase in both automation and precision in the analysis of geological materials has had significant impact upon forensic investigations in the last 10 years. There is however, a fundamental philosophical difference between forensic and geological enquiry. This paper presents the results of forensic geoscientific investigations of three cases of wildlife crime. Two cases involve the analysis of soils recovered after incidents of illegal badger baiting in the United Kingdom. The third case involves the illegal importation of Eleonora's Falcon (Falco eleonorae) into the United Kingdom from the Mediterranean. All three cases utilise the analysis of soils by a variety of physical, chemical and biological techniques. These involve mineral and grain size analyses, cation and anion compositions, pH, organic content and pollen analysis.The independent analysis undertaken by specialists in each of these three main fields conclude firstly, that there is a significant similarity between sediments taken at the crime site at both badger setts and with sediments recovered from various spades, shovels and clothing belonging to suspects and secondly, that the soils analysed associated with the removal of the falcon eggs in the Mediterranean contained characteristics similar in many respects to the soils of the breeding areas of E eleonorae on the cliffs of Mallorca. The use of these independent techniques in wildlife crime detection has great potential given the ubiquitous nature of soils and sediments found in association with wildlife sites. (c) 2006 Elsevier Ireland Ltd. All rights reserved

A forensic geoscience framework and practice

Appropriate and correct collection, analysis, interpretation, and presentation of geoforensic evidence are contingent upon understanding the specific context of the particular forensic investigation undertaken. To achieve this, the role of experimental studies in forensic geoscience must not be underestimated. In this article, we present two experimental studies that assess the spatial distribution of pollen in a living room and the nature of subsequent transfer of pollen onto clothing. The presence of cut flowers in a living room are shown to lead to a distribution of pollen grains onto all types of surface in that room that exhibits a distance–decay pattern with the greatest numbers of grains found in close proximity to the flowers. Once the transfer of pollen grains from a source location onto clothing has taken place, our second study demonstrates the nature of the persistence of that evidence for dry and damp clothing under active and inactive conditions. The level of activity after transfer is shown to have far more influence upon the persistence of this form of geoforensic evidence in comparison to the damp or dry conditions of the garment. We argue that these findings have implications for all stages of the forensic investigation–from sampling protocols to the interpretation of the presence/absence of geoforensic evidence. Whilst every contact does indeed leave a trace, it is imperative that there is an appreciation of the context of each forensic investigation, meaningful science take place and accurate and helpful crime reconstructions to be achieved

The preservation of quartz grain surface textures following vehicle fire and their use in forensic enquiry

During a terrorist trial, dispute arose as to whether the temperature produced in a car fire was sufficient to destroy quartz grain surface textures. A series of seven sequential experiments showed that the temperature for quartz surface texture modification/destruction and the production of vugs, vesicles and glassy precipitation ('snowdrifting') occurred at 1200 degrees C under normal atmospheric conditions. By adding a number of man-made and natural substances, it was found that only the presence of salts depressed this modification temperature (to 900 degrees C). Experiments to determine the temperature of fire in a car indicated that the maximum temperature produced under natural conditions (810 degrees C) was insufficient to affect the quartz grain Surface textures. These results confirm the use of surface texture analysis of quartz grains recovered from the remains of cars Subjected to fire and their use as a forensic indicator. (C) 2008 Forensic Science Society. Published by Elsevier Ireland Ltd. All rights reserved

High Performance Liquid Chromatography as a valuable tool for geoforensic soil analysis

A key issue for geoforensic analysis is the ability to discriminate between geographical locations of close proximity, often with similar underlying geology. This paper addresses the lack of empirical research into the non-mineral components of sediment samples and presents the development of a method of sediment sample characterisation by High Performance Liquid Chromatography (HPLC) utilising the organic components of the sample. A sample preparation method and set of instrument parameters were developed such that the cost of the analysis could be reduced, efficiency increased and the sample amount required for analysis reduced fourfold. The re-developed method allows samples collected from different locations within the same forensically relevant site to be accurately discriminated in this study by both visual examination of the chromatography and the use of multivariate statistics. The results of the HPLC analysis were compared with those obtained by quartz grain surface texture analysis, and HPLC was found to offer better discrimination between the samples in this instance. The results of this study suggest that HPLC has the potential to offer an accurate and practical method of comparing soil samples based on characteristics that are independent of, and therefore complementary to, traditional mineralogical-based geoforensic analyses