328 research outputs found
Fabrication and Characterisation of an Adaptable Plasmonic Nanorod Array for Solar Energy Conversion
The surface plasmonic modes of a side-by-side aligned gold nanorod array supported on a gold substrate has been characterised by electron energy loss spectroscopy (EELS). Plasmonic coupling within the array splits the nanorods' longitudinal mode into a bright mode (symmetrically aligned dipoles) and a dark mode (anti-symmetrically aligned dipoles). We support this observation by means of finite element modelling (FEM)
Application of automated electron microscopy imaging and machine learning to characterise and quantify nanoparticle dispersion in aqueous media
For many nanoparticle applications it is important to understand dispersion in liquids. For nanomedicinal and nanotoxicological research this is complicated by the often complex nature of the biological dispersant and ultimately this leads to severe limitations in the analysis of the nanoparticle dispersion by light scattering techniques. Here we present an alternative analysis and associated workflow which utilises electron microscopy. The need to collect large, statistically relevant datasets by imaging vacuum dried, plunge frozen aliquots of suspension was accomplished by developing an automated STEM imaging protocol implemented in an SEM fitted with a transmission detector. Automated analysis of images of agglomerates was achieved by machine learning using two free openâsource software tools: CellProfiler and ilastik. The specific results and overall workflow described enable accurate nanoparticle agglomerate analysis of particles suspended in aqueous media containing other potential confounding components such as salts, vitamins and proteins
Transmission electron microscopy of a model crystalline organic, theophylline
We report on the use of transmission electron microscopy (TEM) to analyse the diffraction patterns of the model crystalline organic theophylline to investigate beam damage in relation to changing accelerating voltage, sample temperature and TEM grid support films. We find that samples deposited on graphene film grids have the longest lifetimes when also held at -190 °C and imaged at 200 kV accelerating voltage. Finally, atomic lattice images are obtained in bright field STEM by working close to the estimated critical electron dose for theophylline
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Bilayer graphene formed by passage of current through graphite: evidence for a three-dimensional structure
The passage of an electric current through graphite or few-layer graphene can result in a striking structural transformation, but there is disagreement about the precise nature of this process. Some workers have interpreted the phenomenon in terms of the sublimation and edge reconstruction of essentially flat graphitic structures. An alternative explanation is that the transformation actually involves a change from a flat to a three-dimensional structure. Here we describe detailed studies of carbon produced by the passage of a current through graphite which provide strong evidence that the transformed carbon is indeed three-dimensional. The evidence comes primarily from images obtained in the scanning transmission electron microscope using the technique of high-angle annular dark-field imaging, and from a detailed analysis of electron energy loss spectra. We discuss the possible mechanism of the transformation, and consider potential applications of âthree-dimensional bilayer grapheneâ
Single-atom spectroscopy of phosphorus dopants implanted into graphene
One of the keys behind the success of modern semiconductor technology has been the ion implantation of silicon, which allows its electronic properties to be tailored. For similar purposes, heteroatoms have been introduced into carbon nanomaterials both during growth and using post-growth methods. However, due to the nature of the samples, it has been challenging to determine whether the heteroatoms have been incorporated into the lattice as intended. Direct observations have so far been limited to N and B dopants, and incidental Si impurities. Furthermore, ion implantation of these materials is challenging due to the requirement of very low ion energies and atomically clean surfaces. Here, we provide the first atomic-resolution imaging and electron energy loss spectroscopy (EELS) evidence of phosphorus atoms in the graphene lattice, implanted by low-energy ion irradiation. The measured P L âââ-edge shows excellent agreement with an ab initio spectrum simulation, conclusively identifying the P in a buckled substitutional configuration. While advancing the use of EELS for single-atom spectroscopy, our results demonstrate the viability of phosphorus as a lattice dopant in sp ÂČ-bonded carbon structures and provide its unmistakable fingerprint for further studies
The Sigma 13 (10-14) twin in alpha-Al2O3: A model for a general grain boundary
The atomistic structure and energetics of the Sigma 13 (10-14)[1-210]
symmetrical tilt grain boundary in alpha-Al2O3 are studied by first-principles
calculations based on the local-density-functional theory with a mixed-basis
pseudopotential method. Three configurations, stable with respect to
intergranular cleavage, are identified: one Al-terminated glide-mirror twin
boundary, and two O-terminated twin boundaries, with glide-mirror and two-fold
screw-rotation symmetries, respectively. Their relative energetics as a
function of axial grain separation are described, and the local electronic
structure and bonding are analysed. The Al-terminated variant is predicted to
be the most stable one, confirming previous empirical calculations, but in
contrast with high-resolution transmission electron microscopy observations on
high-purity diffusion-bonded bicrystals, which resulted in an O-terminated
structure.
An explanation of this discrepancy is proposed, based on the different
relative energetics of the internal interfaces with respect to the free
surfaces
The prismatic Sigma 3 (10-10) twin bounday in alpha-Al2O3 investigated by density functional theory and transmission electron microscopy
The microscopic structure of a prismatic twin
boundary in \aal2o3 is characterized theoretically by ab-initio
local-density-functional theory, and experimentally by spatial-resolution
electron energy-loss spectroscopy in a scanning transmission electron
microscope (STEM), measuring energy-loss near-edge structures (ELNES) of the
oxygen -ionization edge. Theoretically, two distinct microscopic variants
for this twin interface with low interface energies are derived and analysed.
Experimentally, it is demonstrated that the spatial and energetical resolutions
of present high-performance STEM instruments are insufficient to discriminate
the subtle differences of the two proposed interface variants. It is predicted
that for the currently developed next generation of analytical electron
microscopes the prismatic twin interface will provide a promising benchmark
case to demonstrate the achievement of ELNES with spatial resolution of
individual atom columns
Structure and dielectric properties of yttrium-doped Ca0.28Ba0.72Nb2O6 ceramics
An unfilled tungsten bronze-structured ferroelectric ceramic, Ca0.28Ba0.72Nb2O6 (CBN28), has been doped with Y3+ to produce ceramics with a nominal composition, (Ca0.28Ba0.72)1â3w/2YwNb2O6 [0 †w †0.05]. The substitution of Y3+ for Ca2+/Ba2+, and consequent additional vacancy formation, is assumed to occur on the A1/A2 sites. This resulted in a minor reduction of the c lattice parameter, and unit cell volume. For undoped CBN28, there was a slightly diffuse relative permittivity-temperature (Δr-T) peak at 268 â°C. The peak became much broader for sample compositions w = 0.04 and 0.05 and the peak temperature showed a level of frequency dependence consistent with weak relaxor behaviour. The polarisation-electric field loops became narrower for samples w = 0.04 and 0.05, corresponding to a reduction in remnant polarisation value, from 2.4 to 0.8 ”C cmâ2 (30 kV cmâ1). The Y doped ceramics exhibited stable relative permittivity over a wide temperature range, the variation being within± 15% of the median value from 36 â°C to 218 â°C for w = 0.05, when measured at 1 kHz. Consequently, we suggest that A site donor-doping and aliovalent B site doping of CBN holds potential for industry standard, temperature stable, high temperature dielectrics (Ér â„ 500 ± 15% from - 55â250 + â°C)
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