394 research outputs found
Temperature crossover of decoherence rates in chaotic and regular bath dynamics
The effect of chaotic bath dynamics on the decoherence of a quantum system is
examined for the vibrational degrees of freedom of a diatomic molecule in a
realistic, constant temperature collisional bath. As an example, the specific
case of I in liquid xenon is examined as a function of temperature, and the
results compared with an integrable xenon bath. A crossover in behavior is
found: the integrable bath induces more decoherence at low bath temperatures
than does the chaotic bath, whereas the opposite is the case at the higher bath
temperatures. These results, verifying a conjecture due to Wilkie, shed light
on the differing views of the effect of chaotic dynamics on system decoherence.Comment: 7 pages, 3 figure
Engineering an all-optical route to ultracold molecules in their vibronic ground state
We propose an improved photoassociation scheme to produce ultracold molecules
in their vibronic ground state for the generic case where non-adiabatic effects
facilitating transfer to deeply bound levels are absent. Formation of molecules
is achieved by short laser pulses in a Raman-like pump-dump process where an
additional near-infrared laser field couples the excited state to an auxiliary
state. The coupling due to the additional field effectively changes the shape
of the excited state potential and allows for efficient population transfer to
low-lying vibrational levels of the electronic ground state. Repetition of many
pump-dump sequences together with collisional relaxation allows for
accumulation of molecules in v=0.Comment: Phys. Rev. A, in pres
Mode-selective vibrational excitation induced by nonequilibrium transport processes in single-molecule junctions
In a nanoscale molecular junction at finite bias voltage,the intra-molecular
distribution of vibrational energy can strongly deviate from the thermal
equilibrium distribution and specific vibrational modes can be selectively
excited in a controllable way,regardless of the corresponding mode frequency.
This is demonstrated for generic models of asymmetric molecular junctions with
localized electronic states, employing a master equation as well as a
nonequilibrium Green's function approach. It is shown that the applied bias
voltage controls the excitation of specific vibrational modes coupled to these
states, by tuning their electronic population,which influences the efficiency
of vibrational cooling processes due to energy exchange with the leads.Comment: 12 pages, 4 figures, and Support Informatio
Advances in decoherence control
I address the current status of dynamical decoupling techniques in terms of
required control resources and feasibility. Based on recent advances in both
improving the theoretical design and assessing the control performance for
specific noise models, I argue that significant progress may still be possible
on the road of implementing decoupling under realistic constraints.Comment: 14 pages, 3 encapsulated eps figures. To appear in Journal of Modern
Optics, Special Proceedings Volume of the XXXIV Winter Colloquium on the
Physics of Quantum Electronics, Snowbird, Jan 200
Statistical mechanics of Floquet systems with regular and chaotic states
We investigate the asymptotic state of time-periodic quantum systems with
regular and chaotic Floquet states weakly coupled to a heat bath. The
asymptotic occupation probabilities of these two types of states follow
fundamentally different distributions. Among regular states the probability
decreases from the state in the center of a regular island to the outermost
state by orders of magnitude, while chaotic states have almost equal
probabilities. We derive an analytical expression for the occupations of
regular states of kicked systems, which depends on the winding numbers of the
regular tori and the parameters temperature and driving frequency. For a
constant winding number within a regular island it simplifies to Boltzmann-like
weights \exp(-\betaeff \Ereg_m), similar to time-independent systems. For
this we introduce the regular energies \Ereg_m of the quantizing tori and an
effective winding-number-dependent temperature 1/\betaeff, different from the
actual bath temperature. Furthermore, the occupations of other typical Floquet
states in a mixed phase space are studied, i.e. regular states on nonlinear
resonances, beach states, and hierarchical states, giving rise to distinct
features in the occupation distribution. Avoided crossings involving a regular
state lead to drastic consequences for the entire set of occupations. We
introduce a simplified rate model whose analytical solutions describe the
occupations quite accurately.Comment: 18 pages, 11 figure
Coherent Control of Quantum Chaotic Diffusion
Extensive coherent control over quantum chaotic diffusion using the kicked
rotor model is demonstrated and its origin in deviations from random matrix
theory is identified. Further, the extent of control in the presence of
external decoherence is established. The results are relevant to both areas of
quantum chaos and coherent control.Comment: 4 pages, 4 figures, to appear in Phys. Rev. Let
A Selective Advantage for Conservative Viruses
In this letter we study the full semi-conservative treatment of a model for
the co-evolution of a virus and an adaptive immune system. Regions of viability
are calculated for both conservatively and semi-conservatively replicating
viruses interacting with a realistic semi-conservatively replicating immune
system. The conservative virus is found to have a selective advantage in the
form of an ability to survive in regions with a wider range of mutation rates
than its semi-conservative counterpart. This may help explain the existence of
a rich range of viruses with conservatively replicating genomes, a trait which
is found nowhere else in nature.Comment: 4 pages, 2 figure
Overlapping resonances in the control of intramolecular vibrational redistribution
Coherent control of bound state processes via the interfering overlapping
resonances scenario [Christopher et al., J. Chem. Phys. 123, 064313 (2006)] is
developed to control intramolecular vibrational redistribution (IVR). The
approach is applied to the flow of population between bonds in a model of
chaotic OCS vibrational dynamics, showing the ability to significantly alter
the extent and rate of IVR by varying quantum interference contributions.Comment: 10 pages, 7 figure
Aspects of quantum coherence in the optical Bloch equations
Aspects of coherence and decoherence are analyzed within the optical Bloch
equations. By rewriting the analytic solution in an alternate form, we are able
to emphasize a number of unusual features: (a) despite the Markovian nature of
the bath, coherence at long times can be retained; (b) the long-time asymptotic
degree of coherence in the system is intertwined with the asymptotic difference
in level populations; (c) the traditional population-relaxation and decoherence
times, and , lose their meaning when the system is in the presence
of an external field, and are replaced by more general overall timescales; (d)
increasing the field strength, quantified by the Rabi frequency, ,
increases the rate of decoherence rather than reducing it, as one might expect;
and (e) maximum asymptotic coherence is reached when the system parameters
satisfy .Comment: 18 pages, 6 figures; to appear in J Chem Phy
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