Reply to comment by J.-P. Renaud et al. on “An assessment of the tracer-based approach to quantifying groundwater contributions to streamflow”

This is the published version. Copyright Wiley [Commercial Publisher

Hydrologic response of catchments to precipitation: Quantification of mechanical carriers and origins of water

This is the published version. Copyright American Geophysical Union[1] Precipitation-induced overland and groundwater flow and mixing processes are quantified to analyze the temporal (event and pre-event water) and spatial (groundwater discharge and overland runoff) origins of water entering a stream. Using a distributed-parameter control volume finite-element simulator that can simultaneously solve the fully coupled partial differential equations describing 2-D Manning and 3-D Darcian flow and advective-dispersive transport, mechanical flow (driven by hydraulic potential) and tracer-based hydrograph separation (driven by dispersive mixing as well as mechanical flow) are simulated in response to precipitation events in two cross sections oriented parallel and perpendicular to a stream. The results indicate that as precipitation becomes more intense, the subsurface mechanical flow contributions tend to become less significant relative to the total pre-event stream discharge. Hydrodynamic mixing can play an important role in enhancing pre-event tracer signals in the stream. This implies that temporally tagged chemical signals introduced into surface-subsurface flow systems from precipitation may not be strong enough to detect the changes in the subsurface flow system. It is concluded that diffusive/dispersive mixing, capillary fringe groundwater ridging, and macropore flow can influence the temporal sources of water in the stream, but any sole mechanism may not fully explain the strong pre-event water discharge. Further investigations of the influence of heterogeneity, residence time, geomorphology, and root zone processes are required to confirm the conclusions of this study

An assessment of the tracer-based approach to quantifying groundwater contributions to streamflow

This is the published version. Copyright American Geophysical Union[1] The use of conservative geochemical and isotopic tracers along with mass balance equations to determine the pre-event groundwater contributions to streamflow during a rainfall event is widely used for hydrograph separation; however, aspects related to the influence of surface and subsurface mixing processes on the estimates of the pre-event contribution remain poorly understood. Moreover, the lack of a precise definition of “pre-event” versus “event” contributions on the one hand and “old” versus “new” water components on the other hand has seemingly led to confusion within the hydrologic community about the role of Darcian-based groundwater flow during a storm event. In this work, a fully integrated surface and subsurface flow and solute transport model is used to analyze flow system dynamics during a storm event, concomitantly with advective-dispersive tracer transport, and to investigate the role of hydrodynamic mixing processes on the estimates of the pre-event component. A number of numerical experiments are presented, including an analysis of a controlled rainfall-runoff experiment, that compare the computed Darcian-based groundwater fluxes contributing to streamflow during a rainfall event with estimates of these contributions based on a tracer-based separation. It is shown that hydrodynamic mixing processes can dramatically influence estimates of the pre-event water contribution estimated by a tracer-based separation. Specifically, it is demonstrated that the actual amount of bulk flowing groundwater contributing to streamflow may be much smaller than the quantity indirectly estimated from a separation based on tracer mass balances, even if the mixing processes are weak

Transforming practice, transforming practitioners:reflections on the TQFE in Scotland

This study offers reflections on the TQFE in Scotland as an example of the transformative professional learning model as identified by various authors. The focus of this study is the professional learning of lecturers in Scotland’s colleges. Informed by wider considerations of teacher education more broadly, it will be of particular interest to those supporting a transformative model of professional learning in a variety of educational contexts. The research was undertaken as a collaborative initiative between each of the three universities which offer the TQFE in Scotland. Qualitative data are drawn from former TQFE participants and college mentors, and thematic analysis used to gain further insight from participant interviews. Findings highlight the transformative nature of the TQFE with an impact that is beyond the currency of the TQFE programme duration. The provision of transformative professional learning opportunities is now imperative given various pressures and tensions around the development of educators more generally and within contemporary Scottish Further Education in particular. Such pressures and tensions include: the varied demands within the Professional Standards for Lecturers in Scotland’s Colleges, and the need for professional learning for college lecturers to go beyond a competency or tool-kit based approach and to be sustainable

Five-Spin Supramolecule for Simulating Quantum Decoherence of Bell States

We report a supramolecule that contains five spins of two different types and with, crucially, two different and predictable interaction energies between the spins. The supramolecule is characterized, and the interaction energies are demonstrated by electron paramagnetic resonance (EPR) spectroscopy. Based on the measured parameters, we propose experiments that would allow this designed supramolecule to be used to simulate quantum decoherence in maximally entangled Bell states that could be used in quantum teleportation

Modelling Conformational Flexibility in a Spectrally Addressable Molecular Multi-Qubit Model System

Dipolar coupled multi-spin systems have the potential to be used as molecular qubits. Herein we report the synthesis of a molecular multi-qubit model system with three individually addressable, weakly interacting, spin (Formula presented.) centres of differing g-values. We use pulsed Electron Paramagnetic Resonance (EPR) techniques to characterise and separately address the individual electron spin qubits; CuII, Cr7Ni ring and a nitroxide, to determine the strength of the inter-qubit dipolar interaction. Orientation selective Relaxation-Induced Dipolar Modulation Enhancement (os-RIDME) detecting across the CuII spectrum revealed a strongly correlated CuII-Cr7Ni ring relationship; detecting on the nitroxide resonance measured both the nitroxide and CuII or nitroxide and Cr7Ni ring correlations, with switchability of the interaction based on differing relaxation dynamics, indicating a handle for implementing EPR-based quantum information processing (QIP) algorithms

Primordial Neutrinos, Cosmological Perturbations in Interacting Dark-Energy Model: CMB and LSS

We present cosmological perturbation theory in neutrinos probe interacting dark-energy models, and calculate cosmic microwave background anisotropies and matter power spectrum. In these models, the evolution of the mass of neutrinos is determined by the quintessence scalar field, which is responsible for the cosmic acceleration today. We consider several types of scalar field potentials and put constraints on the coupling parameter between neutrinos and dark energy. Assuming the flatness of the universe, the constraint we can derive from the current observation is $\sum m_{\nu} < 0.87 eV$ at the 95 % confidence level for the sum over three species of neutrinos. We also discuss on the stability issue of the our model and on the impact of the scattering term in Boltzmann equation from the mass-varying neutrinos.Comment: 26 pages Revtex, 11 figures, Add new contents and reference

The Adiabatic Instability on Cosmology's Dark Side

We consider theories with a nontrivial coupling between the matter and dark energy sectors. We describe a small scale instability that can occur in such models when the coupling is strong compared to gravity, generalizing and correcting earlier treatments. The instability is characterized by a negative sound speed squared of an effective coupled dark matter/dark energy fluid. Our results are general, and applicable to a wide class of coupled models and provide a powerful, redshift-dependent tool, complementary to other constraints, with which to rule many of them out. A detailed analysis and applications to a range of models are presented in a longer companion paper.Comment: 4 pages, 1 figur

A kapwa-infused paradigm in teaching Catholic theology/catechesis in a multireligious classroom in the Philippines

The increasing religious diversity in educational space has raised a legitimate question on how Catholic theology/ catechesis must be taught in Philippine Catholic universities given the institutional mandate to educate students “into the faith of the Church through teaching of Christian doctrine in an organic and systematic way” (Wuerl, 2013, 1). On this note, the paper makes reference to “centered plural- ism” (CP), a positional posture espoused by Georgetown University in dealing with this predicament. In an attempt to (re) appropriate CP into local context, there is a need to explore the Filipino conception of self/others as enveloped within the indigenous concept of kapwa. Hereon, the paper finds that CP is not just feasibly suitable in local context but with kapwa's more inclusive description of the relationship of self and others, a CP‐based teaching paradigm in theology/ catechesis is a promising project in the educational scene of the Philippines