5 research outputs found
Recovery of RNA adsorbed onto sorbents following storage at 4°C.
<p>Data is presented as the ratio of the RNA recovered on a given day to that recovered for the same sorbent on day one of the experiment. Recovery of RNA from NS (black), NS-G (blue) NS-T (green), and NS-B (red) sorbents. An RNA control in water under identical storage conditions was also monitored over this time period (gray).</p
Schematic representations of synthesis and functionalization of nanospherical silicate particles.
<p>Schematic representations of synthesis and functionalization of nanospherical silicate particles.</p
Characterization of nanospherical silicate particles by nitrogen adsorption and SEM imaging: NS (black), NS-G (blue), NS-T (green), and NS-B (red).
<p><b>A.</b> Nitrogen adsorption/desorption isotherms. <b>B.</b> Pore size distributions. <b>C.</b> SEM image. <b>D.</b> Particle diameter distribution determined from SEM images.</p
Platinum-Paper Micromotors: An Urchin-like Nanohybrid Catalyst for Green Monopropellant Bubble-Thrusters
Platinum
nanourchins supported on microfibrilated cellulose films (MFC) were
fabricated and evaluated as hydrogen peroxide catalysts for small-scale,
autonomous underwater vehicle (AUV) propulsion systems. The catalytic
substrate was synthesized through the reduction of chloroplatinic
acid to create a thick film of Pt coral-like microstructures coated
with Pt urchin-like nanowires that are arrayed in three dimensions
on a two-dimensional MFC film. This organic/inorganic nanohybrid displays
high catalytic ability (reduced activation energy of 50–63%
over conventional materials and 13–19% for similar Pt nanoparticle-based
structures) during hydrogen peroxide (H<sub>2</sub>O<sub>2</sub>)
decomposition as well as sufficient propulsive thrust (>0.5 N)
from reagent grade H<sub>2</sub>O<sub>2</sub> (30% w/w) fuel within
a small underwater reaction vessel. The results demonstrate that these
layered nanohybrid sheets are robust and catalytically effective for
green, H<sub>2</sub>O<sub>2</sub>-based micro-AUV propulsion where
the storage and handling of highly explosive, toxic fuels are prohibitive
due to size-requirements, cost limitations, and close person-to-machine
contact
High Aspect Ratio Carbon Nanotube Membranes Decorated with Pt Nanoparticle Urchins for Micro Underwater Vehicle Propulsion <i>via</i> H<sub>2</sub>O<sub>2</sub> Decomposition
The utility of unmanned micro underwater vehicles (MUVs) is paramount for exploring confined spaces, but their spatial agility is often impaired when maneuvers require burst-propulsion. Herein we develop high-aspect ratio (150:1), multiwalled carbon nanotube microarray membranes (CNT-MMs) for propulsive, MUV thrust generation by the decomposition of hydrogen peroxide (H<sub>2</sub>O<sub>2</sub>). The CNT-MMs are grown <i>via</i> chemical vapor deposition with diamond shaped pores (nominal diagonal dimensions of 4.5 × 9.0 μm) and subsequently decorated with urchin-like, platinum (Pt) nanoparticles <i>via</i> a facile, electroless, chemical deposition process. The Pt-CNT-MMs display robust, high catalytic ability with an effective activation energy of 26.96 kJ mol<sup>–1</sup> capable of producing a thrust of 0.209 ± 0.049 N from 50% [w/w] H<sub>2</sub>O<sub>2</sub> decomposition within a compact reaction chamber of eight Pt-CNT-MMs in series