Remediation of chromium(VI) at polypyrrole-coated titanium

The application of conducting polypyrrole (PPy) and polyaniline (PAni) coated substrates in remediation of chromium, Cr(VI), is an area of considerable interest. Here, we discuss the implementation of PPy-coated titanium as a new material for the reduction of Cr(VI) to the less toxic trivalent state, Cr(III). An alkaline-peroxide based etching process was used to ensure the adhesion of the PPy coatings to the underlying titanium. The PPy films showed excellent resistance to acidic Cr(VI) solutions and remained adherent after continuous exposure to the solutions. In order to optimise the remediation process a number of experimental parameters were investigated, including the thickness of the PPy coating, the reduction potential used in pre-treatment of the PPy and the degree of solution agitation. The durability of the materials on exposure to the Cr(VI) test solutions made them suitable for repeated remediation experiments. Following several test-runs, the cleanup efficiency of the material was found to decrease slightly, however, increasing the exposure/experiment time resulted in significantly improved cleanup ability

The Flux Variability of Markarian 501 in Very High Energy Gamma Rays

The BL Lacertae object Markarian 501 was identified as a source of gamma-ray emission at the Whipple Observatory in March 1995. Here we present a flux variability analysis on several times-scales of the 233 hour data set accumulated over 213 nights (from March 1995 to July 1998) with the Whipple Observatory 10 m atmospheric Cherenkov imaging telescope. In 1995, with the exception of a single night, the flux from Markarian 501 was constant on daily and monthly time-scales and had an average flux of only 10% that of the Crab Nebula, making it the weakest VHE source detected to date. In 1996, the average flux was approximately twice the 1995 flux and showed significant month-to-month variability. No significant day-scale variations were detected. The average gamma-ray flux above ~350 GeV in the 1997 observing season rose to 1.4 times that of the Crab Nebula -- 14 times the 1995 discovery level -- allowing a search for variability on time-scales shorter than one day. Significant hour-scale variability was present in the 1997 data, with the shortest, observed on MJD 50607, having a doubling time of ~2 hours. In 1998 the average emission level decreased considerably from that of 1997 (to ~20% of the Crab Nebula flux) but two significant flaring events were observed. Thus, the emission from Markarian 501 shows large amplitude and rapid flux variability at very high energies as does Markarian 421. It also shows large mean flux level variations on year-to-year time-scales, behaviour which has not been seen from Markarian 421 so far.Comment: 19 pages, 3 figures, to appear in ApJ, June 20, 1999, Vol. 518 #

Continuous Quantum Measurement and the Emergence of Classical Chaos

We formulate the conditions under which the dynamics of a continuously measured quantum system becomes indistinguishable from that of the corresponding classical system. In particular, we demonstrate that even in a classically chaotic system the quantum state vector conditioned by the measurement remains localized and, under these conditions, follows a trajectory characterized by the classical Lyapunov exponent.Comment: 5 pages, multicol revte

Quantum Revivals in Periodically Driven Systems close to nonlinear resonance

We calculate the quantum revival time for a wave-packet initially well localized in a one-dimensional potential in the presence of an external periodic modulating field. The dependence of the revival time on various parameters of the driven system is shown analytically. As an example of application of our approach, we compare the analytically obtained values of the revival time for various modulation strengths with the numerically computed ones in the case of a driven gravitational cavity. We show that they are in very good agreement.Comment: 14 pages, 1 figur

Limits to Quantum Gravity Effects from Observations of TeV Flares in Active Galaxies

We have used data from the TeV gamma-ray flare associated with the active galaxy Markarian 421 observed on 15 May 1996 to place bounds on the possible energy-dependence of the speed of light in the context of an effective quantum gravitational energy scale. The possibility of an observable time dispersion in high energy radiation has recently received attention in the literature, with some suggestions that the relevant energy scale could be less than the Planck mass and perhaps as low as 10^16 GeV. The limits derived here indicate this energy scale to be in excess of 4x10^16 GeV at the 95% confidence level. To the best of our knowledge, this constitutes the first convincing limit on such phenomena in this energy regime.Comment: 6 pages, including 2 figure

TeV Observations of the Variability and Spectrum of Markarian 501

Markarian 501 is only the second extragalactic source to be detected with high statistical certainty at TeV energies; it is similar in many ways to Markarian 421. The Whipple Observatory gamma-ray telescope has been used to observe the AGN Markarian 501 in 1996 and 1997, the years subsequent to its initial detection. The apparent variability on the one-day time-scale observed in TeV gamma rays in 1995 is confirmed and compared with the variability in Markarian 421. Observations at X-ray and optical wavelengths from 1997 are also presented.Comment: 4 pages, 2 figures, to appear in proceedings of 25th ICRC (Durban

Tev Observations of the Variability and Spectrum of Markarian 421

Markarian 421 was the first extragalactic source to be detected with high statistical certainty at TeV energies. The Whipple Observatory gamma-ray telescope has been used to observe the Active Galactic Nucleus, Markarian 421 in 1996 and 1997. The rapid variability observed in TeV gamma rays in previous years is confirmed. Doubling times as short as 15 minutes are reported with flux levels reaching 15 photons per minute. The TeV energy spectrum is derived using two independent methods. The implications for the intergalactic infra-red medium of an observed unbroken power law spectrum up to energies of 5 TeV is discussed.Comment: 4 pages, 4 figures, to appear in proceedings of 25 ICRC (Durban